Carbon-Coated Nanopowder as Sintering Aid for Water-Atomized Iron Powder

The influence of carbon coating on the nanopowder when used as a sintering aid for water-atomized iron powder is explored. Iron nanopowder without such a coating was used as a reference sintering aid to isolate and depict the influence of the carbon coating. Both nanopowder variants were characterized using XPS and HRTEM, and the results showed a core-shell structure for both nanopowder variants. Iron nanopowder is covered by a 3-4 nm thick iron oxide layer, while the carbon-coated nanopowder is encapsulated with a number of nanometric carbon layers. Thermogravimetry carried out in a pure hydrogen environment shows a multipeak behaviour for carbon-coated nanopowder, while a single peak behaviour is observed for the iron nanopowder. This difference was correlated with chemical analysis. Two types of micro/nanobimodal powders were obtained by mixing the nanopowder with water-atomized iron powder. An improved linear shrinkage was observed when carbon-coated iron nanopowder was added. This can be explained by the reduced surface diffusion in the nanopowder due to the carbon coating, which allows the nanopowder to sinter at higher temperatures and improves densification.

Synthesis of the Current Knowledge Concerning the Construction of French Traditional Cob Building for Giving Recommendations

The museum of the “Bourrine du bois Juquaud” is a tourist site located in the town of Saint Hilaire de Riez in France. It presents the daily life of the inhabitants of the marsh in the early twentieth century and their traditional earthen houses called Bourrine. The Bourrine is a cob construction with reed roof. The earth used for walls is soil from marshlands added with dune sand and straw fibres but some part are without fibres like coating applied on walls. By now, the knowledge acquired on the implementation of these mixtures for the lifting of the walls are oral knowledge and it is necessary to ensure the preservation of this traditional heritage. Currently the done reparations present cracks due to shrinkage. This study aims at well defining the mixtures by a scientific approach. The earth and dune sand were analyzed by taking cores from different existing bourrines and also by extracting soil on site. Different mixtures were produced by varying the proportion of earth sand and water. The linear shrinkage were measured. Corrections were done to get the best mixture for manufacturing and repairing the Bourrines.

Waste to Wealth Strategy: Preparation and Properties of Lightweight Al2O3-SiO2-Rich Castables Using Aluminum Dross Waste

Aluminum dross is a well-known industrial waste generated in the aluminium industry, and its recycling and reuse is still a worldwide issue. Herein, aluminum dross waste (ADW) was recycled to progressively replace the aggregate fraction of clay at 70, 75, 80, 85, and 90 wt% for the fabrication of Al2O3-SiO2-rich porous castable refractories. Their physical properties and mechanical behavior were assessed by the measurement of linear shrinkage rate, bulk density, apparent porosity, cold crushing strength, and thermal conductivity. The microstructure and phase evolutions were analyzed via scanning electron microscopy (SEM) and X-ray diffraction (XRD). The incorporation of 85 wt% of ADW allowed the development of a waste-containing conventional refractory castable with improved properties as compared to those of the other samples. The sustainable refractory castable exhibited decent thermal conductivity and physical and mechanical characteristics, and is suitable for application as reheating furnace lining. It is a “green” practice to partially replace the traditional raw materials with industrial waste in the manufacture of conventional refractory castables and provides environmental and economic benefits.

Geotechnical Characteristics of Benin Formation, Owerri Imo State, Nigeria

A good road network consists of a constant stretch of asphalt laid down for a smooth ride. The spot in the smooth ride on the pavement is commonly referred to as "pavement failure." Soil type, load bearing capacity of materials, zone of vulnerability, resistance to permeation, compressibility, shrinkage limit, and other details are frequently required in order to construct a very good and solid foundation for the planned bridge site. In Nigeria, numerous factors contribute to the failure of road construction projects. They are primarily insufficient research on subgrade and other pavement materials (sub-base and base courses) prior to the start of road projects; flawed engineering, including a poor drainage system and supervision throughout road construction; and shoddy workmanship that was superimposed with asphaltic concrete to improve strength. Within the Niger Delta basin, the study area is located between latitude 5.485°N and longitude 7.035°E. The Benin Formation underpins the study area. It is composed primarily of friable sands, conglomerates, very coarse sandstone, and isolated gravel units, as well as intercalation of Pliocene to Miocene shale/clay lenses. Natural Moisture Content (NMC), Linear Shrinkage (LS), Particle Size Distribution, and California Bearing Ratio were among the laboratory tests performed on samples collected at failed and stable sections of some selected road segments (CBR). When compared to the stable sections, the NMC along the failed sections was on the high side (ranging from 13.11 percent to 26.89 percent) (ranging from 11.11 percent to 16.40 percent). The majority of the tested soils passed the 0.075mm sieve with a percentage greater than the Federal Ministry of Works and Housing's maximum of 35% for subgrade materials. The maximum dry density (MDD) for the samples at failed and stable sections was 1550 kg/m3 to 1860 kg/m3; 1650 kg/m3 to 1980 kg/m3; and the Optimum Moisture Content (OMC) was 8.30% to 20.30%. The soaked CBR values ranged from 2 to 17 percent, while the unsoaked values ranged from 4 to 25 percent.

New Clayey Deposit and Their Potential as Raw Material for Red or Structured Ceramics: Technological Characterization

Mineralogical and technological characterization of ceramic raw materials from a new deposit located at Caxias city, Maranhão State—Brazil, was accomplished to determine their potential as raw materials for the ceramics industry in northeastern Brazil. The ceramic raw materials were collected from three different locations on the site and characterized by X-ray fluorescence (XRF), X-ray diffraction (XRD), differential thermal analysis (DTA), and thermogravimetry (TG). The XRF analysis of the fraction < 2 μm revealed that most samples had SiO2 (35–51 wt%), Al2O3 (19–29 wt%), Fe2O3 (2–21 wt%), MgO (0.7 to 4.5 wt%) and K2O (0.9 to 5 wt%) as components. Quartz, kaolinite, illite, hematite and montmorillonite were the main mineral phases identified. DTA and TG analysis confirmed the mineral identification. The technological potential of the ceramic raw materials was investigated by: cation exchange capacity (CEC), plastic behavior (Atterberg Limits), linear shrinkage at 950 °C (LSF), flexural strength (FS), apparent porosity (AP), water absorption (WA) and bulk density (BD). The main experimental results—WA (9–17%), AP (19–31%), FS (2.0–23 MPa), and the Atterberg limits—indicated that the ceramic raw materials investigated have high potential to be used to develop mass for red or structured ceramics, such as bricks and roof tiles.

Vat Photopolymerization of Cemented Carbide Specimen

Numerous studies show that vat photopolymerization enables near-net-shape printing of ceramics and plastics with complex geometries. In this study, vat photopolymerization was investigated for cemented carbide specimens. Custom-developed photosensitive WC-12 Co (wt%) slurries were used for printing green bodies. The samples were examined for defects using quantitative microstructure analysis. A thermogravimetric analysis was performed to develop a debinding program for the green bodies. After sintering, the microstructure and surface roughness were evaluated. As mechanical parameters, Vickers hardness and Palmqvist fracture toughness were considered. A linear shrinkage of 26–27% was determined. The remaining porosity fraction was 9.0%. No free graphite formation, and almost no η-phase formation occurred. WC grain growth was observed. 76% of the WC grains measured were in the suitable size range for metal cutting tool applications. A hardness of 1157 HV10 and a Palmqvist fracture toughness of 12 MPam was achieved. The achieved microstructure exhibits a high porosity fraction and local cracks. As a result, vat photopolymerization can become an alternative forming method for cemented carbide components if the amount of residual porosity and defects can be reduced.

Silicon dioxide dispersed effects on some physical and mechanical properties of Al2Si2O5(OH)4

Kaolin and silica of 50 μm grain size were used in different weight percentage. Four combinations have been selected as green compacted bodies. Different sintering temperatures ranging from (1000 – 1400) °C were used to sintered all the combinations under static air. The sintered density, thermal conductivity compression strength and linear shrinkage were tested after sintering. The common behavior indicated that the improvement with its optimum results was found at the combination (Kaolin 20-SiO2 80) Wt. %, sintered at 1400 °C, for 3 hours under static air.

Physical characterization of biopolymers with starch from potato and cassava organic wastes polymerized in water

During the last decades, the use of plastic has become indispensable for the daily life of people; the global production of these materials reaches approximately more than 200 million tons per year. For this reason, research has been carried out to manufacture substitute materials that have similar physical properties, such as starch-based biopolymers; in this research we initially characterized the physical properties of a biopolymer based on starch polymerized in water, without plasticizers, and also to find an optimal proportion between starch and water; in this way an experimental design is generated where the proportion of these two varies, in which starch extracted from potato and cassava wastes was used. These biopolymers were characterized for linear shrinkage, density, and hardness properties. The results of the characterizations showed that the proportions lower than 1:5 starch-water present difficulty to process and deficiency in the homogeneity of the mixture, while the proportions higher than 1:5 presented a linear shrinkage higher than 82. 69% and a loss in weight higher than 74.45%; on the other hand, the hardness analysis showed an average of 79 points on the shore A scale and density with an average of 1.055 g/cm3, the results determined that the most adequate proportion is 1:6.5 starch-water.

Characteristics of Thermal Parameters and Some Physical Properties of Mineral Eutectic Type: Petalite–Alkali Feldspars

The aim of the research was to check whether the system of three fluxes based on lithium aluminium silicate and alkali feldspars has a eutectic point, i.e., with the lowest melting temperature. Lithium was introduced into the mixtures in the form of petalite, which occurs naturally in nature (Bikita Zimbabwe deposit). Using naturally occurring raw materials such as petalite, sodium feldspar, and potassium feldspar, an attempt was made to obtain eutectics with the lowest melting point to facilitate thermal processing of the mineral materials. In addition, the high-temperature viscosity of the mineral alloys and physical parameters such as density, linear shrinkage, and open porosity were studied. The study showed that in these systems, there is one three-component eutectic at 1345 °C, with the lowest viscosity of 1·105 Pas and the highest density of 2.34g/cm3, with a weight content of petalite 20%, sodium feldspar 20%, and potassium feldspar 20%.

Role of Fly Ash on Strength Properties of Rejuvenated Soil Cement for Pavement Materials

Stabilization with cement is the most commonly used technique for the improvement of soil physical, mechanical, and engineering properties. This research reported on the properties of the rejuvenation for recycled soil cement with incorporation of fly ash (FA). The study showed that the specific gravity of Rejuvenated Soil Cement (RSC) decreased with increasing FA. The free swell ratio and linear shrinkage of RSC were significantly decreased with the increase in FA. The maximum dry unit weight of RSC increased with increasing FA up to the optimum FA content of 20 – 25 %. The optimum water content in compaction was relatively constant with the increase in FA. Particularly, the strength improvement in active zone of FA-RSC was influenced by several factors viz., compaction, packing, rehydration, and pozzolanic reaction. As a result, the unconfined compressive strength (UCS) of RSC increased with increase in FA and curing time. This research clearly showed that the rejuvenation of soil-cement with FA as additive was successful. It was also shown that the normalized UCSs of RSC at various curing times could be used to predict the UCSs at 7 and 28 days.