scholarly journals Synergistic Effect in Solvent Extraction—Effect of the Chelating Ligands on the Stability of Lutetium Mixed Chelates with β-Diketones and Their Adducts with TOPO—

1970 ◽  
Vol 43 (3) ◽  
pp. 796-800 ◽  
Author(s):  
Tsunenobu Shigematsu ◽  
Takaharu Honjyo
2015 ◽  
Vol 2015 ◽  
pp. 1-8 ◽  
Author(s):  
Andery Lim ◽  
Noramaliyana Haji Manaf ◽  
Kushan Tennakoon ◽  
R. L. N. Chandrakanthi ◽  
Linda Biaw Leng Lim ◽  
...  

Chlorophyll and xanthophyll dyes extracted from a single source of filamentous freshwater green algae (Cladophora sp.) were used to sensitize dye sensitized solar cells and their performances were investigated. A more positive interaction is expected as the derived dyes come from a single natural source because they work mutually in nature. Cell sensitized with mixed chlorophyll and xanthophyll showed synergistic activity with improved cell performance of 1.5- to 2-fold higher than that sensitized with any individual dye. The effect of temperature and the stability of these dyes were also investigated. Xanthophyll dye was found to be more stable compared to chlorophyll that is attributed in the ability of xanthophyll to dissipate extra energy via reversible structural changes. Mixing the dyes resulted to an increase in effective electron life time and reduced the process of electron recombination during solar cell operation, hence exhibiting a synergistic effect.


Processes ◽  
2019 ◽  
Vol 7 (12) ◽  
pp. 954 ◽  
Author(s):  
Daria Bożejewicz ◽  
Katarzyna Witt ◽  
Małgorzata A. Kaczorowska ◽  
Borys Ośmiałowski

A new compound 2,6-bis(4-methoxybenzoyl)-diaminopyridine (L) was used as an extractant for copper(II) ion recovery in a solvent extraction conducted at a temperature of 25 °C. The best results (99% recovery of copper(II) ions) were obtained when the aqueous phase contained 0.001 mol/dm3 Cu(II) and 0.2 mol/dm3 NH3 (pH~5.8), while the organic phase was a 0.001 mol/dm3 chloroform solution of 2,6-bis(4-methoxybenzoyl)-diaminopyridine. Spectrophotometry studies were used to determine the dissociation constant of the tested compound and determine the stability constant of the complex of subjected compound with copper(II) ions. The high-resolution mass spectrometry (HRMS) and higher energy collisional dissociation tandem mass spectrometry (HCD MS/MS) methods have been applied for the confirmation of the structure of 2,6-bis(4-methoxybenzoyl)-diaminopyridine and to determine its complexation with Cu(II) in solution.


2017 ◽  
Vol 2 ◽  
pp. 80-80 ◽  
Author(s):  
Jiangfeng Lu ◽  
Yanru Wang ◽  
Yingzhen Niu ◽  
Weixia Bai ◽  
Shurong Liang ◽  
...  

2010 ◽  
Vol 57 (3) ◽  
pp. 109-113 ◽  
Author(s):  
Mitsuhiro OKADA ◽  
Satoshi KIMURA ◽  
Norihiro MURAYAMA ◽  
Junji SHIBATA ◽  
Katsumi OTANI

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