Antiferromagnetic Transition in a Novel Star-shaped High-spin Fe(III) Tetranuclear Cluster from a Mononuclear Coordination Anion Featuring π-Extended Schiff Base Ligands

2015 ◽  
Vol 44 (6) ◽  
pp. 840-842 ◽  
Author(s):  
Kazuyuki Takahashi ◽  
Kiko Kawamukai ◽  
Tomoyuki Mochida ◽  
Takahiro Sakurai ◽  
Hitoshi Ohta ◽  
...  
Keyword(s):  
Schiff Base ◽  
High Spin ◽  
Antiferromagnetic Transition ◽  
Schiff Base Ligands ◽  
Tetranuclear Cluster

Series of high spin mononuclear iron(iii) complexes with Schiff base ligands derived from 2-hydroxybenzophenones

2017 ◽  
Vol 41 (13) ◽  
pp. 5904-5915 ◽  
Author(s):  
Lukáš Pogány ◽  
Ján Moncol ◽  
Ján Pavlik ◽  
Ivan Šalitroš
Keyword(s):  
Schiff Base ◽  
High Spin ◽  
Coupled Systems ◽  
Schiff Base Complexes ◽  
Schiff Base Ligands ◽  
Mononuclear Iron ◽  
P Utilization

Utilization of 2-hydroxybenzophenone derivatives for the preparation of iron(iii) Schiff base complexes resulted in a series of high-spin, mostly antiferromagnetically coupled systems.

High‐Spin Mononuclear Iron(III) Complexes with Pentadentate Schiff Base Ligands: Structural Analysis and Magnetic Properties

ChemPlusChem ◽  
2019 ◽  
Vol 84 (4) ◽  
pp. 358-367 ◽  
Author(s):  
Lukáš Pogány ◽  
Ján Moncol ◽  
Ján Pavlik ◽  
Milan Mazúr ◽  
Ivan Šalitroš
Keyword(s):  
Magnetic Properties ◽  
Schiff Base ◽  
Structural Analysis ◽  
High Spin ◽  
Schiff Base Ligands ◽  
Mononuclear Iron

Tuning the nuclearity of iron(iii) polynuclear clusters by using tetradentate Schiff-base ligands

2014 ◽  
Vol 38 (5) ◽  
pp. 2105-2113 ◽  
Author(s):  
Alexandre Abhervé ◽  
Juan Modesto Clemente-Juan ◽  
Miguel Clemente-León ◽  
Eugenio Coronado ◽  
Jaursup Boonmak ◽  
...  
Keyword(s):  
Schiff Base ◽  
High Spin ◽  
Schiff Base Ligands ◽  
Tetradentate Schiff Base ◽  
Polynuclear Clusters ◽  
Tetranuclear Complexes

Three novel octanuclear, hexanuclear and tetranuclear complexes of high-spin Fe(iii) ions were obtained by the reaction of the N,N′-bis-(1R-imidazol-4-ylmethylene)-ethane-1,2-diamine ligand (R = H, CH3) and its derivatives with Fe(ClO4)3·6H2O and KSCN.

Conductivity Studies of Schiff Base Ligands Derived from O-Phenylenediamine and Their Co(II) and Zn(II) Complexes

2015 ◽  
Vol 12 (2) ◽  
pp. 13
Author(s):  
Muhamad Faridz Osman ◽  
Karimah Kassim
Keyword(s):  
Nuclear Magnetic Resonance ◽  
Fourier Transform ◽  
Schiff Base ◽  
Nmr Spectroscopy ◽  
Magnetic Resonance ◽  
Impedance Spectroscopy ◽  
Ftir Spectroscopy ◽  
Coordination Complexes ◽  
Frequency Range ◽  
Schiff Base Ligands

The coordination complexes of Co(II) and Zn(II) with Schiff bases derived from o-phenylenediamine and substituted 2-hydroxybenzaldehyde were prepared All compounds were characterized by Fourier transform infrared (FTIR) spectroscopy and Nuclear magnetic resonance (NMR) spectroscopy elemental analyzers. They were analyzed using impedance spectroscopy in the frequency range of 100Hz-1 MHz. LI and L2 showed higher conductivity compared to their metal complexes, which had values of 1.3 7 x 10-7 and 6.13 x 10-8 S/cm respectively. 

Tetranuclear Copper and Mononuclear Nickel Complex of the Schiff Base of (3Z)-3-Hydrazonobutan-2-One Oxime with Different Aromatic Carbonyl Compounds: Synthesis, Single Crystal X-Ray Structure, Catecholase Activity, Phenoxazinone Synthase Activity, Catalytic Study for the Homocoupling of Benzyl Amines

2019 ◽  
Author(s):  
Swaraj Sengupta ◽  
Sahanwaj Khan ◽  
Shyamal K. Chattopadhyay ◽  
Indrani Banerjee ◽  
Tarun K. Panda ◽  
...  
Keyword(s):  
Schiff Base ◽  
Single Crystal ◽  
Copper Complex ◽  
Carbonyl Compounds ◽  
Nickel Complex ◽  
Schiff Base Ligands ◽  
X Ray ◽  
Phenoxazinone Synthase ◽  
Catecholase Activity ◽  
Aromatic Carbonyl Compounds

Synthesis and characterisation of one trinuclear copper complex, ([Cu<sub>3</sub>L<sub>3</sub>O]ClO<sub>4</sub>) (<b>1</b>) and one nickel complex ([Ni(L'H)<sub>2</sub>(dmso)<sub>2</sub>](ClO<sub>4</sub>)<sub>2</sub>) (<b>2</b>) with Schiff base ligands: (3Z)-3-((Z)-(1-(thiophen-2-yl)ethylidene)hydrazono)butan-2-one oxime (LH) and 1-(pyridin-2-yl)ethylidene)hydrazono)butan-2-one oxime (L<sup>'</sup>H). <b>1</b> shows high catecholase activity and has also been tested as a catalyst for the synthesis of benzylimine. <b>2 </b> shows phenoxazinone synthase activity.

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