scholarly journals Transient Circular Dichroism Measurement of the Excited Triplet State of Pristine Hexahelicene in Solution at Room Temperature

2019 ◽  
Vol 48 (4) ◽  
pp. 357-360 ◽  
Author(s):  
Makoto Kuronuma ◽  
Takehito Sato ◽  
Yasuyuki Araki ◽  
Tadashi Mori ◽  
Seiji Sakamoto ◽  
...  

1983 ◽  
Vol 3 (1-6) ◽  
pp. 321-332 ◽  
Author(s):  
G. H. Atkinson ◽  
J. B. Pallix

The time-resolved resonance Raman (TR3) spectra of excited triplet state all-trans-retinal (ATR (T1)) are analyzed with respect to (1) time-resolved excitation profiles (TREP), (2) T1 → S0 intersystem crossing rates, and (3) O2 quenching kinetics. These TR3 data are used to comment on the electronic characteristics and kinetic decay of the excited triplet state of a specific retinal isomer in room temperature solutions.



2000 ◽  
Vol 113 (24) ◽  
pp. 11194-11201 ◽  
Author(s):  
Tran-Chin Yang ◽  
David J. Sloop ◽  
S. I. Weissman ◽  
Tien-Sung Lin


1987 ◽  
Vol 52 (5) ◽  
pp. 1356-1361
Author(s):  
S. Abdel Rahman ◽  
M. Elsafty ◽  
A. Hattaba

The conformation of elastin-like peptides Boc-Ala-Pro-Gly-Val-APEGM, Boc-Ala-Pro-Gly-Val-Gly-Val-APEGM, Boc-Ala-Pro-Gly-Val-Ala-Pro-Gly-Val-Gly-Val-APEGM, Boc-Ala-Pro-Gly-Val-Gly-Val-Ala-Pro-Gly-Val-Gly-Val-APEGM were examined in solution using circular dichroism at 30 °C, 50 °C, and 70 °C and in solid state by IR at room temperature. The studies show that the β-turn is a significant conformational feature for peptides under investigation in solution at 30 °C and 50 °C, but at 70 °C the tetra, hexa, and decapeptides show the CD feature characteristic of the β-structure while the dodecapeptide spectra show the presence of β-turn which indicates the stability of the β-turn at this chain length. The IR spectra show that in the solid state at room temperature all investigated peptides assume essentially a β-turn except the tetrapeptide which present evidence of antiparallel β-structure. The β-turn contribution in the IR spectra increases with the increase of the chain length of the peptide.





2016 ◽  
Vol 128 (22) ◽  
pp. 6597-6601 ◽  
Author(s):  
Juwon Oh ◽  
Young Mo Sung ◽  
Woojae Kim ◽  
Shigeki Mori ◽  
Atsuhiro Osuka ◽  
...  




1984 ◽  
Vol 13 (4) ◽  
pp. 549-550 ◽  
Author(s):  
Hiro-o Hamaguchi ◽  
Hiromi Okamoto ◽  
Mitsuo Tasumi


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