Dehydrocoupling Reactions of Secondary and Primary Amine–Borane Adducts Catalyzed by Half-sandwich Carbonyl Complexes, [CpMn(CO)3], [(η6-C6H6)Cr(CO)3], and [CpV(CO)4]

2011 ◽  
Vol 40 (2) ◽  
pp. 171-173 ◽  
Author(s):  
Taeko Kakizawa ◽  
Yasuro Kawano ◽  
Kohsuke Naganeyama ◽  
Mamoru Shimoi
Keyword(s):  
Primary Amine ◽  
Carbonyl Complexes ◽  
Half Sandwich

Photoinduced Carbon Monoxide Release from Half-Sandwich Iron(II) Carbonyl Complexes by Visible Irradiation: Kinetic Analysis and Mechanistic Investigation

2015 ◽  
Vol 21 (37) ◽  
pp. 13065-13072 ◽  
Author(s):  
Xiujuan Jiang ◽  
Limei Chen ◽  
Xiu Wang ◽  
Li Long ◽  
Zhiyin Xiao ◽  
...  
Keyword(s):  
Carbon Monoxide ◽  
Kinetic Analysis ◽  
Carbonyl Complexes ◽  
Mechanistic Investigation ◽  
Visible Irradiation ◽  
Half Sandwich

Chlorination of half-sandwich carbonyl complexes: The square-pyramidal cation [(η6-C6Et6)Mo(CO)3Cl]+

Polyhedron ◽  
1988 ◽  
Vol 7 (19-20) ◽  
pp. 2027-2030 ◽  
Author(s):  
W.A. Herrmann ◽  
W.R. Thiel ◽  
E. Herdtweck
Keyword(s):  
Carbonyl Complexes ◽  
Half Sandwich

Hemilability of the primary amine–metal bond in polyamine-(Group 6) metal carbonyl complexes

2002 ◽  
Vol 664 (1-2) ◽  
pp. 214-222 ◽  
Author(s):  
Anne-Cécile Hervé ◽  
Jean-Jacques Yaouanc ◽  
Jean-Claude Clément ◽  
Hervé des Abbayes ◽  
Loı̈c Toupet
Keyword(s):  
Primary Amine ◽  
Metal Carbonyl ◽  
Carbonyl Complexes ◽  
Metal Bond ◽  
Metal Carbonyl Complexes ◽  
Group 6

Probing the electron transfer mechanism of the half-sandwich iron(II)-carbonyl complexes and their catalysis on proton reduction

2018 ◽  
Vol 283 ◽  
pp. 27-35 ◽  
Author(s):  
Bingying Rong ◽  
Wei Zhong ◽  
Erxing Gu ◽  
Li Long ◽  
Lijuan Song ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Transfer Mechanism ◽  
Carbonyl Complexes ◽  
Proton Reduction ◽  
Electron Transfer Mechanism ◽  
Half Sandwich

Half-Sandwich Metal Carbonyl Complexes as Precursors to Functional Materials: From a Near-Infrared-Absorbing Dye to a Single-Molecule Magnet

2017 ◽  
Vol 139 (34) ◽  
pp. 12069-12075 ◽  
Author(s):  
Wenqing Wang ◽  
Jing Li ◽  
Lei Yin ◽  
Yue Zhao ◽  
Zhongwen Ouyang ◽  
...  
Keyword(s):  
Single Molecule ◽  
Near Infrared ◽  
Metal Carbonyl ◽  
Functional Materials ◽  
Carbonyl Complexes ◽  
Single Molecule Magnet ◽  
Metal Carbonyl Complexes ◽  
Half Sandwich

Dehydrocoupling Reactions of Borane−Secondary and −Primary Amine Adducts Catalyzed by Group-6 Carbonyl Complexes: Formation of Aminoboranes and Borazines

2009 ◽  
Vol 131 (41) ◽  
pp. 14946-14957 ◽  
Author(s):  
Yasuro Kawano ◽  
Mikio Uruichi ◽  
Mamoru Shimoi ◽  
Seitaro Taki ◽  
Takayuki Kawaguchi ◽  
...  
Keyword(s):  
Primary Amine ◽  
Carbonyl Complexes ◽  
Group 6 ◽  
Amine Adducts

Half-Sandwich Ruthenium Catalyst Bearing an Enantiopure Primary Amine Tethered to an N-Heterocyclic Carbene for Ketone Hydrogenation

ACS Catalysis ◽  
2017 ◽  
Vol 7 (10) ◽  
pp. 6827-6842 ◽  
Author(s):  
Kai Y. Wan ◽  
Molly M. H. Sung ◽  
Alan J. Lough ◽  
Robert H. Morris
Keyword(s):  
Primary Amine ◽  
Ruthenium Catalyst ◽  
Ketone Hydrogenation ◽  
Half Sandwich

MULTIPLE SCATTERING EFFECTS IN THE COBALT K-EDGE EXAFS OF METAL CARBONYL COMPLEXES

1986 ◽  
Vol 47 (C8) ◽  
pp. C8-589-C8-592
Author(s):  
N. BINSTED ◽  
S. L. COOK ◽  
J. EVANS ◽  
R. J. PRICE ◽  
G. N. GREAVES
Keyword(s):  
Multiple Scattering ◽  
Metal Carbonyl ◽  
Carbonyl Complexes ◽  
Metal Carbonyl Complexes ◽  
Scattering Effects ◽  
Multiple Scattering Effects

Regio-, Stereo- and Enantioselective α-Addition of Carbonyl Nucleo-philes to Allenamides Catalyzed by a Synergistic Copper/Enamine System

2020 ◽  
Author(s):  
Rémi Blieck ◽  
Sebastien Lemouzy ◽  
Marc Taillefer ◽  
Florian Monnier
Keyword(s):  
Catalytic System ◽  
Secondary Amine ◽  
Primary Amine ◽  
Synergistic Catalysis ◽  
Enantioselective Addition ◽  
Amine Catalysts

A dual copper/enamine catalytic system is found to enable an intermolecular enantioselective α-addition of various carbonyl nucleophiles to allenamides. Secondary amine catalysts allowed the highly enantioselective addition of aldehydes, while using primary amine catalysts led to the enantioselective addition of ketoester nucleophiles. The process was found to be highly regio-, stereo- and enantio-selective and represented the first allene hydrofunctionalization using an synergistic catalysis involving copper

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