scholarly journals Kinetics of the Esterification Reaction of the Aliphatic and the Aromatic Carboxylic Acids

1967 ◽  
Vol 70 (4) ◽  
pp. 470-475 ◽  
Author(s):  
Kei MATSUZAKI ◽  
Kazuo MITANI
2013 ◽  
Vol 2013 ◽  
pp. 1-12 ◽  
Author(s):  
K. Ramesh ◽  
S. Shylaja ◽  
K. C. Rajanna ◽  
P. Giridhar Reddy ◽  
P. K. Saiprakash

Polyethylene glycols (PEGs) were found to be efficient media for decarboxylative nitration of α,β-unsaturated aromatic carboxylic acids by ceric ammonium nitrate (CAN) in acetonitrile to give β-nitrostyrene derivatives. Kinetics of the reaction exhibited second order kinetics with a first order dependence on [CAN] and [substrate]. Reactions were too sluggish to be studied in the absence of PEG; therefore detailed kinetics were not taken up. Reaction times were reduced from 24 hrs to few hours. The catalytic activity was found to be in the increasing order PEG-300 > PEG-400 > PEG-600 > PEG-200. Mechanism of PEG-mediated reactions was explained by Menger-Portnoy's scheme as applied in micellar kinetics.


2003 ◽  
Vol 248 (1-2) ◽  
pp. 161-167 ◽  
Author(s):  
Sharath R. Kirumakki ◽  
N. Nagaraju ◽  
Komandur V.R. Chary ◽  
Sankarasubbier Narayanan

2011 ◽  
Vol 81 (7) ◽  
pp. 1539-1542
Author(s):  
A. V. Protopopov ◽  
V. V. Kon’shin ◽  
N. A. Chemeris ◽  
M. M. Chemeris

2021 ◽  
pp. 116443
Author(s):  
N. Bensid ◽  
R. Zerdoum ◽  
Z. Hattab ◽  
Y. Boutaleb ◽  
M. Bououdina

2021 ◽  
pp. 117605
Author(s):  
Amanda de Sousa e Silva ◽  
Tasso Jorge Tavares Ferreira ◽  
Naassom Wagner Sales Morais ◽  
Erlon Lopes Pereira ◽  
André Bezerra dos Santos

ChemInform ◽  
2012 ◽  
Vol 43 (35) ◽  
pp. no-no
Author(s):  
Chao-Jun Hu ◽  
Xiao-Hong Zhang ◽  
Qiu-Ping Ding ◽  
Ting Lv ◽  
Shao-Peng Ge ◽  
...  

2015 ◽  
Vol 31 (1) ◽  
pp. 37-44
Author(s):  
Junichi ODO ◽  
Masahiko INOGUCHI ◽  
Hiroyuki AOKI ◽  
Yuto SOGAWA ◽  
Masahiro NISHIMURA

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