S/X ratio impacts the profile and kinetics of carboxylic acids production from the acidogenic fermentation of dairy wastewater

2021 ◽  
pp. 117605
Author(s):  
Amanda de Sousa e Silva ◽  
Tasso Jorge Tavares Ferreira ◽  
Naassom Wagner Sales Morais ◽  
Erlon Lopes Pereira ◽  
André Bezerra dos Santos
Keyword(s):  
Carboxylic Acids ◽  
Dairy Wastewater ◽  
Acidogenic Fermentation ◽  
Kinetics Of

THE TRANSMISSION OF POLAR EFFECTS: IV. THE KINETICS OF ESTERIFICATION WITH DIAZODIPHENYLMETHANE OF SUBSTITUTED HETEROCYCLIC CARBOXYLIC ACIDS

1966 ◽  
Vol 44 (13) ◽  
pp. 1493-1499 ◽  
Author(s):  
Keith Bowden ◽  
D. C. Parkin
Keyword(s):  
Carboxylic Acid ◽  
Carboxylic Acids ◽  
Rate Coefficients ◽  
Relative Ability ◽  
Indole Carboxylic Acid ◽  
Kinetics Of ◽  
Electron Effects

The rate coefficients for the reaction with diazodiphenylmethane, in ethanol at 30.0°, of a number of substituted indole-2-carboxylic acids, indole-3-carboxylic acids, coumarin-3-carboxylic acids, coumarilic acids, and N-phenylglycines have been determined. The effect of substitution is assessed by use of adapted Hammett and Dewar–Grisdale relations. The relations give good correlations for oxygen-ring heterocyclic systems, and the relative ability of the systems to transmit π-electron effects has been determined. An anomalous perturbing effect appears to operate in the indole-carboxylic acid systems.

Reaction Kinetics for the Hydrolysis of Titanium Isopropoxide Carboxylate Complexes

1992 ◽  
Vol 271 ◽  
Author(s):  
Charles D. Gagliardi ◽  
Dilum Dunuwila ◽  
Beatrice A. Van Vlierberge-Torgerson ◽  
Kris A. Berglund
Keyword(s):  
Carboxylic Acids ◽  
Ceramic Materials ◽  
Titanium Isopropoxide ◽  
General Interest ◽  
Chemical Transformations ◽  
Molecular Precursors ◽  
Novel Applications ◽  
Kinetics Of ◽  
Hydrolysis Of

ABSTRACTTitanium alkoxides modified by carboxylic acids have been widely studied as the molecular precursors to ceramic materials. These alkoxide complexes have also been very useful in the formation of stable, porous, optically clear films having many novel applications such as chemical sensors, catalytic supports, and ion-exchange media. To improve the processing of these materials, it is essential to better understand the kinetics of the chemical transformations which occur.The kinetics of the hydrolysis reaction are studied for selected carboxylic acids using Raman spectroscopy to probe the chemistry of the process. The study has a special emphasis on the titanium isopropoxide-valeric acid system due to the superior quality of these films over other carboxylates. Greater knowledge of the hydrolysis kinetics allows increased control over the quality of the film materials and should be of general interest to those working with modified metal alkoxides.

Photoluminescence and its damping kinetics of nanoporous alumina membranes formed in solutions of various carboxylic acids

2021 ◽  
Author(s):  
I. A. Vrublevsky ◽  
K. V. Chernyakova ◽  
E. N. Muratova ◽  
Yu. M. Spivak ◽  
V. A. Moshnikov
Keyword(s):  
Carboxylic Acids ◽  
Nanoporous Alumina ◽  
Alumina Membranes ◽  
Kinetics Of

Enhancement of carboxylic acid degradation with sulfate radical generated by persulfate activation

2010 ◽  
Vol 61 (5) ◽  
pp. 1221-1226 ◽  
Author(s):  
J. Criquet ◽  
P. Nebout ◽  
N. Karpel Vel Leitner
Keyword(s):  
Aqueous Solution ◽  
Citric Acid ◽  
Carboxylic Acids ◽  
Sulfate Radical ◽  
Acid Degradation ◽  
Competitive Reactions ◽  
Radical Production ◽  
Persulfate Activation ◽  
Kinetics Of

The aim of this work was to investigate the generation of sulfate radical for the removal of two carboxylic acids in aqueous solution: acetic and citric acids. From photochemical and radiolytic processes, kinetics of the degradation of these two carboxylic acids was studied as a function of the pH of the solution. It was shown that the maximum of acetic acid degradation occurred at pH 5. Above this pH, competitive reactions with the carbon mineralized inhibit the reaction of with the solute. In the case of citric acid, pH has only a little effect on the kinetic of citric acid degradation. The determination of mineralization yields shows several differences depending on carboxylic acids and pH. The degradation of both carboxylic acids was also studied in the radiolysis process whether with or without persulfate addition. A comparison of the processes of sulfate radical production is presented.

Solvolysis kinetics of trimethylsilyl esters of aromatic N-carboxylic acids

1995 ◽  
Vol 493 (1-2) ◽  
pp. 267-270 ◽  
Author(s):  
R. Szalay ◽  
D. Knausz ◽  
L. Szakács ◽  
K. Újszászy ◽  
B. Csákvári ◽  
...  
Keyword(s):  
Carboxylic Acids ◽  
Kinetics Of
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