micellar effect
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Author(s):  
Mitu Saha ◽  
Nilima Biswas ◽  
S.A. Hussain ◽  
D. Bhattacharjee


Several approaches quantitatively describe the effect of surfactant micellar solution on the reaction rate. The most used among them are Piszkiewicz’s, Berezin’s, and Pseudophase Ion-Exchange (PIE) models. The last-named was developed by Bunton and Romsted. Piszkiewicz’s model is based on representations of the micellization according to the mass action law with the formation of a catalytic micelle, which consists of some surfactant molecules and a substrate. In our previously paper, this model was used to explain the kinetic micellar effect on the reaction of cationic triphenylmethine dyes with water once again showed the main disadvantages of this approach. Berezin’s model is based on another model of micelle formation viz. the pseudophase model, and the binding of reagents by micelles is considered as the distribution of a substance between two phases. In this work, we aim to consider the applicability of Berezin’s approach for the interaction of malachite green and brilliant green cations with water molecule as a nucleophile in aqueous systems of nonionic, anionic, cationic, and zwitterionic surfactants. On the whole, Berezin's model performed well when applied to the description of the micellar effect on the reaction of similar dye with the hydroxide ion. However, it was revealed that this model does not take into account the change in the local concentration of the HO– ions due to a compression of the double electric layer upon addition of reacting ions to the system, as well as the constant of association of the HO– ions with cationic head groups of surfactant. In this case, when water is used as a nucleophile, the question of the degree of nucleophile binding can be solved differently. The PIE model is also based on a pseudophase model of micellization, but a substrate binding by micelles is considered as an association in a stoichiometric ratio of 1:1, and a nucleophile concentration is expressed in a local concentration based on the neutralization degree of micelles. Given the latter, its approach cannot be applied to the kinetic micellar influence on the reaction of cationic triphenylmethine dyes with water.



Proceedings ◽  
2019 ◽  
Vol 41 (1) ◽  
pp. 72
Author(s):  
Jesica B. Soffietti ◽  
Claudia G. Adam ◽  
Claudia D. Della Rosa

In the present work, our objective is to take advantage of the property presented by Ionic Liquids (ILs) based on 1-alkyl-3-methylimidazolium cations by having amphiphilic character when the alkyl group is a long hydrocarbon chain. These ILs can act as surfactants forming micelles in aqueous solution. In this sense, the micellar effect on a Diels-Alder reaction (DA) was analyzed taken as a reference. The reactive system studied consists of maleic anhydride and isoprene, variables such as diene:dienophile ratio and reaction temperatura among the most important were optimized. N,N-dodecylmethylimidazolium bromide was used at the critical micellar concentration (CMC) of 1 × 10−2 M. These “new systems” microheterogeneous would allow, in addition to better solubilization of non-polar substrates, to adopt milder reaction conditions.



Author(s):  
Chandan Debnath ◽  
Mitu Saha ◽  
S.A. Hussain ◽  
D. Bhattacharjee


Quantitative treatment of the kinetic data of the reaction between phenolphthalein dianion and hydroxide ion in aqueous solutions containing variable concentration of various surfactants is presented. Following surfactants are used: Brij-35 (nonionic), sodium n-dodecyl sulfate (anionic), cetyltrimethylammonium bromide (cationic) and 3-(dimethyl-n-dodecylammonio)-propansulfonate (zwitterionic). The quantitative treatment is carried out basing of Piszkiewicz’s, Berezin’s, and Pseudophase Ion-Exchange (PIE) models. It is revealed that the Berezin’s model is a more applicable one for describing the effect of nonionic, anionic, and zwitterionic micellar systems. The values of the corresponding kinetic parameters are discussed. The effect of cetyltrimethylammonium hydroxide on the reaction is also examined and quantitatively described by the PIE model. The research of systems based on a cationic surfactant shows previously unknown effect called by us as “diverting influence”.



2017 ◽  
Vol 539 ◽  
pp. 13-18 ◽  
Author(s):  
J. Nowicki ◽  
J. Woch ◽  
M. Mościpan ◽  
E. Nowakowska-Bogdan


2017 ◽  
Vol 225 ◽  
pp. 207-216 ◽  
Author(s):  
Susanta Malik ◽  
Debabrata Saha ◽  
Monohar Hossain Mondal ◽  
Pintu Sar ◽  
Aniruddha Ghosh ◽  
...  


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