A New Correlation and Prediction Method for the Solubility of Metal Complexes in Supercritical Carbon Dioxide Using Regular Solution Theory with the COSMO-RS Method

2009 ◽  
Vol 42 (5) ◽  
pp. 309-318 ◽  
Author(s):  
Masashi Haruki ◽  
Kazuya Kishimoto ◽  
Fumiya Kobayashi ◽  
Shin-ichi Kihara ◽  
Shigeki Takishima
Keyword(s):  
Carbon Dioxide ◽  
Supercritical Carbon Dioxide ◽  
Metal Complexes ◽  
Regular Solution ◽  
Prediction Method ◽  
Regular Solution Theory ◽  
Solution Theory ◽  
New Correlation ◽  
Supercritical Carbon

Synthesis of novel promising materials via impregnation of crosslinked polymeric networks with metal complexes in supercritical carbon dioxide

2016 ◽  
Vol 10 (7) ◽  
pp. 1163-1165 ◽  
Author(s):  
I. O. Rybakova ◽  
A. E. Lazhko ◽  
A. V. Zolotuchina ◽  
P. S. Timashev ◽  
V. N. Bagratashvili ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Supercritical Carbon Dioxide ◽  
Metal Complexes ◽  
Polymeric Networks ◽  
Supercritical Carbon

Study of Metal Complexes’ Solubility in Supercritical Carbon Dioxide

2011 ◽  
Vol 236-238 ◽  
pp. 411-416 ◽  
Author(s):  
Yi Gang Ding ◽  
Hai Tao Huang ◽  
Yao Ding ◽  
Chang Yan Yang ◽  
Jun Ji ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Mathematical Model ◽  
Supercritical Carbon Dioxide ◽  
Metal Complexes ◽  
Solubility Data ◽  
Experiment Data ◽  
Extraction Device ◽  
Supercritical Temperature ◽  
Good Agreement ◽  
Supercritical Carbon

The solubility of 8-hydroxyquinoline lead, lead diethyldithiocarbamate, 8-hydroxyquinoline mercury and mercury diethyldithiocarbamate in supercritical carbon dioxide under different supercritical conditions was investigated by using supercritical extraction device. It was measured ranged from 308.15K to 328.15K for supercritical temperature, and 10 MPa to 30MPa for pressure. The solubility data of metal complexes were correlated and a mathematical model was put forward from a viewpoint of solvent association theory compared to Chrastil’s model. The results showed that SA model gives fairly good agreement with the experiment data.

Heck reactions using water-soluble metal complexes in supercritical carbon dioxide

1999 ◽  
Vol 40 (35) ◽  
pp. 6427-6430 ◽  
Author(s):  
Bhalchandra M. Bhanage ◽  
Yutaka Ikushima ◽  
Masayuki Shirai ◽  
Masahiko Arai
Keyword(s):  
Carbon Dioxide ◽  
Supercritical Carbon Dioxide ◽  
Metal Complexes ◽  
Water Soluble ◽  
Heck Reactions ◽  
Supercritical Carbon

Carbosilane Dendrons as Solubilizers of Metal Complexes in Supercritical Carbon Dioxide#

2006 ◽  
Vol 25 (17) ◽  
pp. 4138-4143 ◽  
Author(s):  
Francisco Montilla ◽  
Agustín Galindo ◽  
Román Andrés ◽  
Marta Córdoba ◽  
Ernesto de Jesús ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Supercritical Carbon Dioxide ◽  
Metal Complexes ◽  
Supercritical Carbon

Trimethylsilyl-substituted ligands as solubilizers of metal complexes in supercritical carbon dioxide

2003 ◽  
pp. 2170-2176 ◽  
Author(s):  
Francisco Montilla ◽  
Vitor Rosa ◽  
Chris Prevett ◽  
Teresa Avilés ◽  
Manuel Nunes da Ponte ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Supercritical Carbon Dioxide ◽  
Metal Complexes ◽  
Supercritical Carbon
Sign in / Sign up

Export Citation Format

Share Document