scholarly journals Reactions Induced in DNA by Oxyl Radicals-Detection and Identification of Precursor Radicals of DNA Damage by the Spin-Trapping Method.

1997 ◽  
Vol 35 (2) ◽  
pp. 91-98
Author(s):  
Mikinori KUWABARA
Polymers ◽  
2021 ◽  
Vol 13 (13) ◽  
pp. 2123
Author(s):  
Maria Râpă ◽  
Maria Stefan ◽  
Paula Popa ◽  
Dana Toloman ◽  
Cristian Leostean ◽  
...  

The electrospun nanosystems containing poly(3-hydroxybutyrate-co-3-hydroxyvalerate) (PHBV) and 1 wt% Fe doped ZnO nanoparticles (NPs) (with the content of dopant in the range of 0–1 wt% Fe) deposited onto polylactic acid (PLA) film were prepared for food packaging application. They were investigated by scanning electron microscopy (SEM), energy dispersive X-ray (EDX), Fourier transform infrared spectroscopy (FT-IR), X-ray diffraction (XRD), antimicrobial analysis, and X-ray photoelectron spectrometry (XPS) techniques. Migration studies conducted in acetic acid 3% (wt/wt) and ethanol 10% (v/v) food simulants as well as by the use of treated ashes with 3% HNO3 solution reveal that the migration of Zn and Fe falls into the specific limits imposed by the legislation in force. Results indicated that the PLA/PHBV/ZnO:Fex electrospun nanosystems exhibit excellent antibacterial activity against the Pseudomonas aeruginosa (ATCC-27853) due to the generation of a larger amount of perhydroxyl (˙OOH) radicals as assessed using electron paramagnetic resonance (EPR) spectroscopy coupled with a spin trapping method.


2003 ◽  
Vol 68 (11) ◽  
pp. 2219-2230 ◽  
Author(s):  
Gabriel Čík ◽  
Milada Hubinová ◽  
František Šeršeň ◽  
Jozef Krištín ◽  
Monika Antošová

Degradation of 4-chlorophenol by reactive oxygen species was studied, the latter being generated by photo-assisted reactions of thiophene oligomers, synthesized in channels of the Na-ZSM-5 zeolite. The photoreaction was carried out in an aqueous suspension of photocatalyst, irradiated with visible light (λ > 400 nm). The spin-trapping method was used to detect the generated •OH radicals. The main products of the photodecomposition of 4-chlorophenol were found to be phenol, hydroquinone and maleic acid.


Nephron ◽  
1995 ◽  
Vol 70 (3) ◽  
pp. 382-384 ◽  
Author(s):  
Takako Yokozawa ◽  
Naoki Fujitsuka ◽  
Hikokichi Oura ◽  
Akitane Mori ◽  
Hiroshi Kashiwagi

1978 ◽  
Vol 47 (3) ◽  
pp. 281-296 ◽  
Author(s):  
R Kh Freidlina ◽  
I I Kandror ◽  
Rashid G Gasanov

1974 ◽  
Vol 52 (21) ◽  
pp. 3645-3650 ◽  
Author(s):  
Frederick Peter Sargent ◽  
Edward Michael Gardy

The radicals produced during γ radiolysis of methanol, ethanol, 1-propanol, 2-propanol, and t-butanol have been trapped by reaction with 2-nitroso-2-methylpropane (t-nitrosobutane) to give nitroxides which are detected by e.s.r.[Formula: see text]All the alcohols gave alkoxy radicals and, with the exception of t-butanol, radicals derived by the loss of an H atom from the carbon atom adjacent to the OH group. Methyl radicals were detected in t-butanol.


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