scholarly journals Detection of mercury by a new sensor based CPE modified with extract of takaout plant

2016 ◽  
Vol 5 (4) ◽  
pp. 514-520
Author(s):  
Abdelaziz Ait sidi mou ◽  
Aicha Ouarzane ◽  
Mama El Rhazi

A new carbon paste electrode (CPE) modified with extract takaout was developed for the determination of mercury using square wave voltammetry (SWV).  Compared with carbon paste electrode, the anodic peak current had a significant increase at the modified electrode. Under the optimized conditions (amount of modifier 3%, 0.1 M acetate buffer pH 2, accumulation potential -0.6 V, accumulation time 300 s, resting time 10 s, frequency 25 Hz, pulse amplitude 0.050 V, step height 2 mV), a linear response was obtained in the concentration range from 3.1 to 11 µM Hg(II) and the detection limit was 0.42 µM. The results indicate that this electrode is sensitive and effective for determination of Hg2+ in the tap water sample.

2011 ◽  
Vol 76 (8) ◽  
pp. 1033-1041
Author(s):  
Jiří Zima ◽  
Veronika Tinková ◽  
Joseph Wang ◽  
Jiří Barek

Direct current (DC) voltammetry and differential pulse (DP) voltammetry using a carbon paste electrode (CPE) have been used for the determination of trace amounts of ecotoxic 1,2-diaminoanthraquinone (DAAQ). The limit of determination (LD) of DAAQ for DC voltammetry was 2 × 10–6 mol l–1, and for DP voltammetry 2 × 10–7 mol l–1 under the optimized conditions in a mixed Britton–Robinson buffer pH 12 and methanol (1:9) medium. Adsorptive accummulation of the analyte on the surface of CPE decreased the limit of determination to 2 × 10–8 mol l–1 for DP voltammetry. Practical applicability of these newly developed methods was verified on model samples of river water.


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