Sensitivity Enhancement in Near-Field Photothermal-Lens Detection in Capillary Electrophoresis Using Laser-Induced Online Precipitation

2011 ◽  
Vol 65 (11) ◽  
pp. 1275-1280 ◽  
Author(s):  
Dmitry A. Nedosekin ◽  
Werner Faubel ◽  
Mikhail A. Proskurnin ◽  
Ute Pyell
1993 ◽  
Vol 65 (10) ◽  
pp. 489A-497A ◽  
Author(s):  
Michael Albin ◽  
Paul D. Grossman ◽  
Stephen E. Moring

2019 ◽  
Vol 33 (05) ◽  
pp. 1950032
Author(s):  
Qi Rong ◽  
Fangrong Hu ◽  
Yuanyuan Li ◽  
Shan Yin ◽  
Mingzhu Jiang ◽  
...  

A symmetry broken hexagram metamaterial (SBHM) is presented to enhance the polarization sensitivity, and thus realize mechanically controlling the transmissions of tri-band in terahertz (THz) region. This SBHM has different electromagnetic response for rotating clockwise and anticlockwise, respectively. When incident THz wave is polarized in the direction of [Formula: see text], the SBHM has three stopbands with central frequencies at 0.36 THz, 0.52 THz and 0.75 THz, respectively. When the SBHM rotates clockwise [Formula: see text], the transmission of 0.52 THz increases from 0.17 to 0.85, and its modulation depth reaches 68%. On the contrary, when it rotates anticlockwise [Formula: see text], the transmissions of the other two bands can be modulated simultaneously, and their modulation depth are 78% and 40%, respectively. The physical mechanism for the tunability is investigated using finite-integration time-domain (FITD) method. The results indicated that the tri-band tunability in the SBHM is due to the mode transfer and polarization sensitivity enhancement which is induced by near field coupling. This novel design proves a new way for modulation, selection and switching of the THz wave at multiband.


2005 ◽  
Vol 59 (12) ◽  
pp. 1470-1479 ◽  
Author(s):  
Mikhail A. Proskurnin ◽  
Svetlana N. Bendrysheva ◽  
Nataliya Ragozina ◽  
Stefan Heissler ◽  
Werner Faubel ◽  
...  

The optical scheme of a near-field dual-beam mode-mismatched thermal-lens detector for capillary electrophoresis with a crossed-beam configuration employing a multimode HeCd laser (325 nm) as an excitation source was optimized. It is shown that a multimode laser can be successfully used as an excitation source in thermal lensing with minimal deviations in thermal responses from Gaussian excitation sources. An equation for diffraction thermal-lens theory for near-field measurements is deduced, and the experimental results agree with the deduced equation. The temperature rise in the capillary was estimated, and the exponential decrease of the signal with time for static conditions and low flow velocities was explained. The optimum configuration of the detector from the viewpoint of the maximum sensitivity and beam sizes was found. The detector provides a significant improvement in the detection limits for model compounds absorbing at 325 nm (nitrophenols) compared to the results obtained with a commercial absorbance detector operating at the same wavelength.


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