scholarly journals A Novel Three-Fold Interpenetrating Three-Dimensional Co(II) Coordination Polymer Based on Flexible Bistriazole Ligand: Synthesis, Structure and Magnetic Properties

2017 ◽  
Vol 29 (12) ◽  
pp. 2643-2646 ◽  
Author(s):  
J.L. Lu ◽  
Y.S. Xue ◽  
J. Wei ◽  
T. Zhou
2014 ◽  
Vol 43 (19) ◽  
pp. 7263-7268 ◽  
Author(s):  
Tiffany M. Smith ◽  
Michael Tichenor ◽  
Yuan-Zhu Zhang ◽  
Kim R. Dunbar ◽  
Jon Zubieta

The three-dimensional [Co3(OH)2(H2O)2(aptet)4] exhibits magnetic properties consistent with a ferrimagnetic chain with the non-compensating resultant moment of one Co(ii) per trinuclear Co(ii) subunit and ac magnetic susceptibility indicative of glassy-like magnetic behavior.


2020 ◽  
Vol 5 (43) ◽  
pp. 13732-13737
Author(s):  
Saima Kamaal ◽  
Mayak Gupta ◽  
Rupali Mishra ◽  
Arif Ali ◽  
Abdullah Alarifi ◽  
...  

2011 ◽  
Vol 66 (10) ◽  
pp. 1029-1034 ◽  
Author(s):  
Jun-Xia Li ◽  
Zhong-Xiang Du ◽  
Wei-Ping Huang

A new 3d-4 f heteronuclear coordination polymer containing cobalt and neodymium, [Nd2Co3(oda)6(H2O)6]·3H2O}n (1) (H2oda = oxydiacetic acid), has been synthesized and structurally characterized. In 1, the oxydiacetate dianions (oda2−) act as pentadentate ligands, and each of them chelates one Nd3+ ion and bridges two Co2+ ions. The infinite connection of metal ions and ligands results in a highly ordered 3D hexagonal channel framework. The photoluminescent, EPR and magnetic properties of the complex were also investigated.


2014 ◽  
Vol 70 (11) ◽  
pp. 1029-1032 ◽  
Author(s):  
Xiao-Juan Xu

A metal coordination polymer, {[Mn2Mo(CN)8(C12H8N6)(CH3CN)2(H2O)2]·2H2O}n, has been synthesized by the reaction of Mn(ClO4)2·6H2O with 3,6-bis(pyridin-2-yl)-1,2,4,5-tetrazine (bptz) and (Bu3N)3[Mo(CN)8] at room temperature. The polymer was characterized by IR spectroscopy, elemental analysis and X-ray diffraction, and the magnetic properties were also investigated. The X-ray diffraction analysis reveals that the compound is a new three-dimensional coordination polymer with a PtS-type network. Magnetic investigation shows antiferromagnetic coupling between adjacent Mn2+cations.


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