Effect of Catalyst (de)activation on Reagent Diffusion in ZSM-5/alumina Extruded Pellet for the Methanol-to-hydrocarbons Conversion

A pelletized ZSM-5/alumina catalyst was prepared by the extrusion technique. The catalyst was activated by ion-exchange with NH4NO3 aqueous solution. The activated catalyst was trained in the methanol-to-hydrocarbons reaction which caused the catalyst deactivation due to coke deposition (6.5 % wt.). Coke deposition resulted in a two-time decrease in the micropore volume. The methane, benzene, and methanol transport through ZSM-5/alumina pellet were consequently studied prior to activation, after activation, and after catalyst deactivation. A slight decrease in the diffusion rate after catalyst activation is observed. After deactivation, the diffusion rate increases insignificantly. The diffusion regime remains unchanged with respect to either activation or deactivation procedure. Contrary, for the methanol, the diffusion rate through a deactivated catalyst pellet remarkably increases due to micropore blockage by coke deposition. The obtained results reveal that the micropores blockage during the catalyst deactivation enhances the methanol mass transfer.