scholarly journals Mineral carbonation of metallurgical slags

Mineralogia ◽  
2015 ◽  
Vol 45 (1-2) ◽  
pp. 27-45 ◽  
Author(s):  
Monika Kasina ◽  
Piotr R. Kowalski ◽  
Marek Michalik

Abstract Due to increasing emissions of greenhouse gases into the atmosphere number of methods are being proposed to mitigate the risk of climate change. One of them is mineral carbonation. Blast furnace and steel making slags are co-products of metallurgical processes composed of minerals which represent appropriate source of cations required for mineral carbonation. Experimental studies were performed to determine the potential use of slags in this process. Obtained results indicate that steel making slag can be a useful material in CO2 capture procedures. Slag components dissolved in water are bonded as stable carbonates in the reaction with CO2 from ambient air. In case of blast furnace slag, the reaction is very slow and minerals are resistant to chemical changes. More time is needed for minerals dissolution and release of cations essential for carbonate crystallisation and thus makes blast furnace slags less favourable in comparison with steel making slag.

2001 ◽  
Vol 13 (2) ◽  
pp. 271-283
Author(s):  
Abdel-Alim H. El-Sayed ◽  
Musaed N. Al-Awad ◽  
Emad S. Al-Homadhi ◽  
Mohammed A. Al-Saddiqui

Author(s):  
Volodymyr Bondarenko ◽  
◽  
Oleksandr Filonenko ◽  
Mykhailo Petlovanyi ◽  
Vladyslav Ruskykh ◽  
...  

Purpose. Experimental studies of the interaction of blast-furnace and steel-making slags with open pit waters during their direct contact and assessment of the volume of filling of the formed man-made cavities during mining of mineral deposits. Methods. Based on the analysis, the current low level of metallurgical slag and the lack of real and effective directions of their large-scale utilization were determined. The laboratory studies of the interaction of metallurgical slags with open pit water at a certain time of interaction, generally accepted methods for studying the chemical composition and concentration of substances in water, computer-aided design software packages and drawings to determine the volumes of the open pit mined-out area were used. Results. The dynamics of changes in the products of interactions of steel-smelting slags with open-pit waters at a certain ratio and period of interaction was investigated. It was found that the concentration of pollutants upon contact of water with steel-making slag changes according to polynomial dependences on the time of their interaction, decreasing by the 30th day, which eliminates the danger for the aquifer. The safest type of metallurgical slag was recommended for the formation of the bottom layer of the backfill massif. The volumes of the mined-out area of the open pit were determined in detail to assess the volumes of placement of the backfill material based on metallurgical slags. Scientific novelty. The safety of the contact of backfill materials based on steelmaking slags with open pit water was scientifically proven, which is confirmed by the established polynomial patterns of changes in concentrations and pollutants from the ratio and time of interaction. Practical significance. The formation of the backfill massif on the basis of blast-furnace dump and steel-smelting slags will allow achieving an environmental effect, such as their safe disposal as a reclamation of technologically disturbed lands by mining and restoration of the economic value of the land plot, as well as preventing the formation of new dumps.


2019 ◽  
Vol 774 ◽  
pp. 1151-1159 ◽  
Author(s):  
Weizao Liu ◽  
Shu Yin ◽  
Dongmei Luo ◽  
Guoquan Zhang ◽  
Hairong Yue ◽  
...  

1977 ◽  
Vol 41 (320) ◽  
pp. 493-499 ◽  
Author(s):  
B. C. M. Butler

SummaryFassaitic diopside containing 22–23 wt% Al2O3 (approximately 41–43% calcium Tschermak's molecule, CaAl2SiO6) and melilite containing 69–43% gehlenite crystallized from a blast-furnace slag at atmospheric pressure between about 1450°C and 1250°C. The occurrence is of petrological interest because the association of pyroxene with gehlenite-rich melilite has not been recorded from experimental studies in the system CaO-MgO-Al2O3-SiO2, and because of the similarity of the compositions of both minerals to pyroxene and melilite in the Ca-Al-rich inclusions of the Allende meteorite.


2020 ◽  
Vol 28 (9) ◽  
pp. 2256-2266 ◽  
Author(s):  
Yingjie Xiong ◽  
Tahani Aldahri ◽  
Weizao Liu ◽  
Guanrun Chu ◽  
Guoquan Zhang ◽  
...  

2015 ◽  
Vol 1105 ◽  
pp. 26-30
Author(s):  
Martina Kovalcikova ◽  
Adriana Eštoková ◽  
Alena Luptáková

The hydraulic properties of granulated blast-furnace slags have been studied for nearly 200 years, and use of slag in mortars and concretes dates back more than a hundred years. The use of ground blast furnace slag, added as a replacement for a portion of the portland cement, has gained increasing acceptance in recent years. The effects of sulphur-oxidizing bacteria Acidithiobacillusthiooxidans on concrete mixture with addition of ground granulated blast furnace slag compared to mixture without any additives were investigated in laboratory over a period of 91 days. A laboratory study was conducted to comparison the performance of concrete samples in terms of a concrete deterioration influenced by the leaching of calcium compounds from the cement matrix. The changes in the elemental concentrations of calcium ions in leachates were measured by using X – ray fluorescence method. Experimental studies confirmed: bacteria Acidithiobacillus thiooxidans caused much intensive calcium release from the concrete matrices into the solution; the higher resistance of concrete mixture with 65 % wt. slag addition was not confirmed.


2018 ◽  
Vol 26 (3) ◽  
pp. 583-592 ◽  
Author(s):  
Lin Wang ◽  
Weizao Liu ◽  
Jingpeng Hu ◽  
Qiang Liu ◽  
Hairong Yue ◽  
...  

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