Sorption of vanadium (V) and nickel (II) on amorphous silic

The sorption of vanadium (V) and nickel (II) from aqueous solutions on amorphous silica obtained from metallurgical slags of the Kola MMC is considered, and the optimal conditions for the metal sorption process are determined. It is established that the maximum sorption of metals is achieved at pH 2.0–4.0, at a temperature of 40 °C and a process time of 60 minutes for nickel and 90 minutes for vanadium.

A new technological approach to the granulation of slag melts of ferrous metallurgy: obtaining glassy fine-grained granules of improved quality

The technological factors required to improve the operational properties of granulated metallurgical slags demanded in the building industry have been analyzed. In order to satisfy these factors, a new technology for hydro-vacuum granulation of slag melts (HVG) has been developed. It is shown that the main advantage of the proposed HVG process is the provision of forced high-speed vortex convection of water, with the effect of vertical suction, crushing, and degassing of the three-phase (water–slag granules–water vapor) heterogeneous medium formed during the overcooling and solidification of slag. It is proved that the high-speed volumetric disintegration and overcooling with the degassing effect sharply reduces a degree of aggressive gas/vapor impact on the being cooled particles of slag, which, in turn, leads to the reduction of the perforation degree of the granules. The obtained granules are distinguished by stable fractionation and improved, well-defined dense amorphous glassy structure, the water-holding capacity of which has reduced from 45–50% to 25–13%, the actual moisture content from 24–20% to 6–4%, while the hydraulic activity in terms of CaO-uptake increased from the conventional 320–360 mg/g to 610–650 mg/g. Pilot scale research demonstrated that the designed equipment for the HVG technology allows sustainable control of the quality of granules, and it has the potential for further development and implementation.

Research on the Recovery of Copper from Metallurgical Slag

Metallurgical slag is one of the most common industrial wastes. Many of these wastes are not stable over time, by reacting with water and air, continuously generating emissions of heavy metals. Metallurgical slag processing is necessary for at least two reasons: reducing pollutant emissions and broadening the raw material base. The recovery of these slags is very difficult because they are the result of metallurgical processes that aimed to fix metals considered impurities in chemical matrices as stable as possible. This paper presents the initial research on the behavior of metallurgical slags against different leaching technologies.

Effect of Basicity and Boron Oxide in Slags of the AOD Process on the Equilibrium Interphase Distribution of Sulfur and Boron

The use of fluorspar in modern metallurgical slags, incl. slags of the argon-oxygen decarburization (AOD) process, as a fluxing agent, is associated with many disadvantages. Those disadvantages can be solved by using boron oxide as an alternative, which also provides conditions for direct microalloying of steel with boron. The paper presents the results of thermodynamic modeling of the effect of basicity and boron oxide content in slags of the CaO–SiO2–B2O3–Cr2O3–Al2O3–MgO system on the equilibrium interphase distribution of sulfur and boron, and their equilibrium content in the metal. Modeling was carried out using the HSC 8.03 Chemistry software package (Outokumpu). Slag from the desulfurization period of the AOD-process was used as the oxide phase. As a result, it was shown that, in the range of basicities 2.0-2.5 and a content of 2-4% B2O3, it is possible to carry out desulfurization of the metal, providing a sulfur content of 0.001-0.007%, and simultaneous microalloying of steel with boron in an amount of up to 0.0103%.