Unique 3D framework formed by adding MIIO4 groups into high Sb/P ratio phosphatoantimonates
2019 ◽
Vol 234
(5)
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pp. 301-306
Keyword(s):
Abstract Explorations on a mixed metal phosphatoantimonate system led to the discovery of two new anhydrous phosphatoantimonates, namely, Cs4MSb6P4O28 (M=Mg, Zn), which represent the first examples of quinary AI – MII –SbV – PV– O systems. Single-crystal structure analysis reveals that the two title compounds crystallize in the tetragonal space group I41/a (No. 88). Their structures feature complicated 3D frameworks with interesting tunnel structures comprised of corner sharing MO4 tetrahedra, SbO6 octahedra and PO4 tetrahedra, with the Cs+ cations sitting in the tunnels to balance the valence. Optical reflectance spectrum measurements show that these two compounds are insulators with band gaps of about 4.5 eV.
2020 ◽
Vol 76
(5)
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pp. 507-512
2016 ◽
Vol 55
(22)
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pp. 6390-6395
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2011 ◽
Vol 13
(4)
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pp. 684-690
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1998 ◽
Vol 52
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pp. 702-708
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1970 ◽
Vol 3
(2)
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pp. 97-98
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