Surface Energy for Nematic Liquid Crystals: A New Point of View

1992 ◽  
Vol 47 (12) ◽  
pp. 1235-1240 ◽  
Author(s):  
A. L. Alexe-Ionescu ◽  
R. Barberi ◽  
G. Barbero ◽  
T. Beica ◽  
R. Moldovan

The surface energy of nematic liquid crystals is deduced from a phenomenological point of view. The idea of an easy surface tensor order parameter is proposed. An expression similar to a Landau expansion for the free energy of a system characterized by two order parameters is deduced and analysed. An interpretation similar to the one usually accepted for magnetic materials is given. The possibility of surface transitions induced by temperature is discussed.

2020 ◽  
Vol 47 (9) ◽  
pp. 1338-1344
Author(s):  
Olha Melnyk ◽  
Yuriy Garbovskiy ◽  
Anatoliy Glushchenko

1990 ◽  
Vol 45 (1) ◽  
pp. 29-32
Author(s):  
S. Sreehari Sastry ◽  
V. Venkata Rao ◽  
P. Narayana Murty ◽  
G. Satyanandam ◽  
T. F. Sundar Raj

AbstractBy EPR, two nematic liquid crystals (MBCA and EPAPU) were investigated using a steroidal nitroxide spin probe. In both liquid crystals the isotropic-nematic phase transition is of first order. The observed variation of the order parameter with temperature is compared with predictions from the Maier-Saupe and Humphries-James-Luckhurst models and with results obtained by several other experimental techniques.


1994 ◽  
Vol 33 (Part 2, No. 8B) ◽  
pp. L1174-L1177 ◽  
Author(s):  
Dae-Shik Seo ◽  
Norihiro Yoshida ◽  
Shunsuke Kobayashi ◽  
Michinori Nishikawa ◽  
Yoshikazu Yabe

Author(s):  
Cécile Zakri ◽  
Christophe Blanc ◽  
Eric Grelet ◽  
Camilo Zamora-Ledezma ◽  
Nicolas Puech ◽  
...  

Liquid crystal ordering is an opportunity to develop novel materials and applications with spontaneously aligned nanotubes or graphene particles. Nevertheless, achieving high orientational order parameter and large monodomains remains a challenge. In addition, our restricted knowledge of the structure of the currently available materials is a limitation for fundamental studies and future applications. This paper presents recent methodologies that have been developed to achieve large monodomains of nematic liquid crystals. These allow quantification and increase of their order parameters. Nematic ordering provides an efficient way to prepare conductive films that exhibit anisotropic properties. In particular, it is shown how the electrical conductivity anisotropy increases with the order parameter of the nematic liquid crystal. The order parameter can be tuned by controlling the length and entanglement of the nanotubes. In the second part of the paper, recent results on graphene liquid crystals are reported. The possibility to obtain water-based liquid crystals stabilized by surfactant molecules is demonstrated. Structural and thermodynamic characterizations provide indirect but statistical information on the dimensions of the graphene flakes. From a general point of view, this work presents experimental approaches to optimize the use of nanocarbons as liquid crystals and provides new methodologies for the still challenging characterization of such materials.


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