Die Struktur von Bis(cyclopentadienyldicarhonylmangan)-1.2-diphenyldiphosphan, [C5H5(CO)2Mn]2PhP(H)—(H)PPh.
1976 ◽
Vol 31
(9)
◽
pp. 1166-1169
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The title compound 1 contains complex stabilized 1,2-diphenyldiphosphane. It crystallizes in space group P21/c with a = 1095(1), b = 1145(1), c = 1186(1) pm, β= 124.73(5)°, Z = 2. The structure has been solved by coventional methods; full matrix refinement converged at R1= 0.045.1 shows crystallographic inversion symmetry and thus contains a meso-1,2-diphenyldiphosphane ligand. The P–P-distance is 225.8 pm, the Mn–P bonds are rather short (221.6 pm).
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1976 ◽
Vol 31
(11)
◽
pp. 1441-1446
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