Oxidation of 4-Lithium-diazasilacyclopentene with Transition Metal Halides / Oxidation of 4-Lithium-diazasilacyclopentene with Transition Metal Halides

1983 ◽  
Vol 38 (8) ◽  
pp. 953-954 ◽  
Author(s):  
Michael Hesse ◽  
Uwe Klingebiel
Keyword(s):  
Reaction Mechanism ◽  
Transition Metal ◽  
Metal Halides ◽  
Tert Butyl ◽  
Oxidation Potentials

4-Lithium-3,3,5-trimethyl-2-tert-butyl-1,2-diaza-3-sila-5-cyclopentene is oxidized in the reaction with transition metal halides and subsequently dimerizes. Oxidation potentials are given and a reaction mechanism is proposed.

Synthesis of TaNbHfZrW-Based Nanopowders by Thermolysis of Transition Metal Halides in the Form of Dry Mixtures and Gels

2021 ◽  
Vol 24 (6) ◽  
pp. 684-691
Author(s):  
S. Vorotylo ◽  
A. S. Sedegov ◽  
K. V. Vorotylo ◽  
D. O. Moskovskikh
Keyword(s):  
Transition Metal ◽  
Metal Halides

Relativistic DFT Study on the Reaction Mechanism of Second-Row Transition Metal Ru with CO2

2006 ◽  
Vol 110 (10) ◽  
pp. 3552-3558 ◽  
Author(s):  
Xian-Yang Chen ◽  
Yi-Xin Zhao ◽  
Shu-Guang Wang
Keyword(s):  
Reaction Mechanism ◽  
Transition Metal ◽  
Dft Study ◽  
Relativistic Dft

SOME EQUILIBRIUM CONSTANTS OF TRANSITION METAL HALIDES

1960 ◽  
Vol 38 (10) ◽  
pp. 1827-1836 ◽  
Author(s):  
M. W. Lister ◽  
P. Rosenblum
Keyword(s):  
Ionic Strength ◽  
Transition Metal ◽  
Equilibrium Constant ◽  
Spectrophotometric Method ◽  
Equilibrium Constants ◽  
Cell Voltage ◽  
Metal Halides ◽  
Complex Ions ◽  
Anomalous Variation ◽  
A Cell

Measurements are reported on the formation of complex ions in solutions containing cupric and chloride or bromide ions, and solutions of nickel or cobalt with chloride. In each case the halide was present in very low amount. With copper a spectrophotometric method was used, and a cell voltage method with nickel and cobalt. The ionic strength was kept constant, but the temperature was varied. The data show difficulties of interpretation if it is assumed that only MX+ ions (M is the metal, X is the halogen) are formed, the difficulties arising from the anomalous variation of the equilibrium constant with temperature, and from the general drift of the calculated constants from the e.m.f. measurements. Various explanations are considered and it is shown that postulation of M2X+3 ions is at least a possible explanation.

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