Hydrolyse von Per(fluorchlor)methylsulfenylchloriden: Isolierung und Charakterisierung stabiler Zwischenstufen / Hydrolysis of Per(fluorochloro)methylsulfenylchlorides: Isolation and Characterization of Stable Intermediates
Hydrolysis of CF3-nClnSCl with water yields the thiosulfinates CF3-nClnSS(O)CF3-nCln and thiosulfonates CF3-nClnSSO2CF3-nCln as stable intermediates. They were synthesized on a preparative scale by special reactions and characterized. A new mechanism, based upon additional reactions of the isolated products, is discussed and extended to the reaction of chlorine with water
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2010 ◽
Vol 46
(6)
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pp. 444-449
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2014 ◽
Vol 62
(50)
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pp. 12178-12185
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1989 ◽
Vol 67
(10)
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pp. 1657-1665
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