Neue Bis(phosphan)-nickel(0)-alkin-Komplexe /New Bis(phosphane)-nickel(0)-alkyne Complexes

1985 ◽  
Vol 40 (2) ◽  
pp. 199-209 ◽  
Author(s):  
Klaus R. Pörschke ◽  
Richard Mynott ◽  
Klaus Angermund ◽  
Carl Krüger
Keyword(s):  
Molecular Structure ◽  
Crystal And Molecular Structure ◽  
X Ray ◽  
X Ray Crystallography ◽  
Nmr Data ◽  
Alkyne Complexes

Abstract (Me3P)2Ni(C2H4) (5) and (dmpe) 2Ni2(C2H4)3 (6) react with various alkynes including ethyne (acetylene) and 1-alkynes to form the crystalline compounds (Me3P)2Ni(C2RR′), (dmpe)Ni(C2RR′), and (dmpe)2Ni2(C2R2)2 (R.R′ = H, Me, Ph). Structural assignments were made on the basis of 1H, 13C, and 31P NMR data. The crystal and molecular structure of (dmpe)Ni(C2Ph2) (17) has been determined by X-ray crystallography.

scholarly journals Tris(phosphan)-Nickel(0)-Ethen-Komplexe (dmpe)(PR3)Ni(C2H4). Molekülstruktur des (dmpe)(PØ3 )Ni(C2H4)/ Tris(phosphane)-nickel(0)-ethene Complexes (dmpe)(PR3)Ni(C2H4). Molecular Structure of (dmpe)(PO3)Ni(C2H4)

1984 ◽  
Vol 39 (8) ◽  
pp. 1076-1081 ◽  
Author(s):  
Klaus R. Pörschke ◽  
Richard Mynott ◽  
Carl Krüger ◽  
M. J. Romão
Keyword(s):  
Molecular Structure ◽  
Ligand Exchange ◽  
Crystal And Molecular Structure ◽  
Exchange Reactions ◽  
Tetrahedral Geometry ◽  
X Ray ◽  
X Ray Crystallography ◽  
Nmr Data

AbstractSynthesis and properties of tris(phosphane)(ethene)nickel(0) complexes (dmpe)(PR3)Ni(C2H4) (R = CH3(4), c-C6H11(5), and C6H5 (6)) are reported. In solution. 4-6 are thermolabile and undergo ligand exchange reactions affording tetrakis(phosphane)nickel(0 ) and bis(phosphane)- (ethene)nickel(0) complexes. 1H, 13C, and 31P NMR data of 4-6 confirm the tetrahedral geometry around nickel. For 6 , the crystal and molecular structure has been determined by X-ray crystallography.

scholarly journals Structural Characterization of Heterodinuclear ZnII-LnIII Complexes (Ln = Pr, Nd) with a Ring-Contracted H2valdien-Derived Schiff Base Ligand

2021 ◽  
Author(s):  
Shabana Noor ◽  
Richard Goddard ◽  
Fehmeeda Khatoon ◽  
Sarvendra Kumar ◽  
Rüdiger W. Seidel
Keyword(s):  
Molecular Structure ◽  
Schiff Base ◽  
Structural Characterization ◽  
Schiff Base Ligand ◽  
Crystal And Molecular Structure ◽  
X Ray ◽  
X Ray Crystallography ◽  
Imidazoline Ring

AbstractSynthesis and structural characterization of two heterodinuclear ZnII-LnIII complexes with the formula [ZnLn(HL)(µ-OAc)(NO3)2(H2O)x(MeOH)1-x]NO3 · n H2O · n MeOH [Ln = Pr (1), Nd (2)] and the crystal and molecular structure of [ZnNd(HL)(µ-OAc)(NO3)2(H2O)] [ZnNd(HL)(OAc)(NO3)2(H2O)](NO3)2 · n H2O · n MeOH (3) are reported. The asymmetrical compartmental ligand (E)-2-(1-(2-((2-hydroxy-3-methoxybenzylidene)amino)-ethyl)imidazolidin-2-yl)-6-methoxyphenol (H2L) is formed from N1,N3-bis(3-methoxysalicylidene)diethylenetriamine (H2valdien) through intramolecular aminal formation, resulting in a peripheral imidazoline ring. The structures of 1–3 were revealed by X-ray crystallography. The smaller ZnII ion occupies the inner N2O2 compartment of the ligand, whereas the larger and more oxophilic LnIII ions are found in the outer O2O2’ site. Graphic Abstract Synthesis and structural characterization of two heterodinuclear ZnII-LnIII complexes (Ln = Pr, Nd) bearing an asymmetrical compartmental ligand formed in situ from N1,N3-bis(3-methoxysalicylidene)diethylenetriamine (H2valdien) through intramolecular aminal formation are reported.

Crystal and molecular structure of trans-[RhCl(CO)(PtBu2Ph)2]

2018 ◽  
Vol 73 (12) ◽  
pp. 1029-1032
Author(s):  
Peter Mayer ◽  
Hans-Christian Böttcher
Keyword(s):  
Molecular Structure ◽  
Ir Spectroscopy ◽  
Crystal And Molecular Structure ◽  
Title Complex ◽  
High Yield ◽  
X Ray ◽  
Carbonyl Ligands ◽  
Pale Yellow ◽  
X Ray Crystallography ◽  
Type Complex

AbstractTreatment of THF solutions containing the rhodium(II) complex trans-[RhCl2(PtBu2Ph)2] (1) with [Fe2(CO)9] in the same solvent resulted in the formation of the Vaska-type complex trans-[RhCl(CO)(PtBu2Ph)2] (2) in high yield. The title complex 2 was obtained as pale yellow crystals, characterized by NMR and IR spectroscopy, as well as by microanalyses. Additionally, the molecular structure of 2 has been established by X-ray crystallography. As often reported for similar constituted compounds, the chlorido and carbonyl ligands in crystals of 2 are strongly disordered.

Synthesis and molecular structure of tetraphenylarsonium Tetrakis(benzenethiolato)-oxorhenate(V)-Acetonitrile (1/1)

1983 ◽  
Vol 36 (2) ◽  
pp. 253 ◽  
Author(s):  
AC McDonell ◽  
TW Hambley ◽  
MR Snow ◽  
AG Wedd
Keyword(s):  
Molecular Structure ◽  
Crystal And Molecular Structure ◽  
Crystal Data ◽  
Rhenium Atom ◽  
Space Group ◽  
X Ray ◽  
X Ray Crystallography

The salts Ph4As [ReO(SPh)4].MeCN and Ph4As [ReO(SePh)4] have been synthesized and characterized. The crystal and molecular structure of the thiolate compound has been determined by X-ray crystallography which reveals a square-pyramidal arrangement of ligand atoms around the central rhenium atom of the [ReO(SPh)4]- anion. Crystal data: a 9.756(4), b 18.171(3), c 25.684(4) �, space group P212121, Z 4.

The Crystal Structure of the Tetrameric Adduct of Antimony Trichloride and Phosphoryl Isothiocyanate, [SbCl3·OP(NCS)3]4

1994 ◽  
Vol 49 (4) ◽  
pp. 441-444 ◽  
Author(s):  
Alexander V. Sienkiewicz ◽  
Anatoliy A. Kapshuk
Keyword(s):  
Molecular Structure ◽  
Crystal Structure ◽  
Crystal And Molecular Structure ◽  
Antimony Trichloride ◽  
Cage Structure ◽  
Space Group ◽  
X Ray ◽  
X Ray Crystallography ◽  
Cubic System ◽  
Tetrameric Complex

The crystal and molecular structure of the tetrameric complex of the composition [SbCl3·OP(NCS)3]4 synthesized from SbCl3 and OP(NCS)3 in CCl4 waso determined by X-ray crystallography [143 m space group, cubic system with a = 13.927(4) Å]. The complex exhibits a tetranuclear "cage" structure with a [Sb4O4] core which consists of μ3-bridging oxygen and six coordinate antimony(III) atoms; the Sb-O distance, 3.060 Å, is exceptionally long.

Ligandensubstitution an cis-Mo(CO)2(PPh3)2(MeCN)(η2-SO2), Kristall- und Molekülstruktur von cis-Mo(CO)2(PMe3)3(η2-SO2) / Ligand Substitution at cis-Mo(CO)2(PPh3)2(MeCN)(η2-SO2), Crystal and Molecular Structure of cis-Mo(CO)2(PMe3)3(η2-SO2)

1986 ◽  
Vol 41 (10) ◽  
pp. 1211-1218 ◽  
Author(s):  
Franz-Erich Baumann ◽  
Christian Burschka ◽  
Wolfdieter A . Schenk
Keyword(s):  
Molecular Structure ◽  
Crystal And Molecular Structure ◽  
Ligand Substitution ◽  
X Ray ◽  
X Ray Crystallography ◽  
Donor And Acceptor ◽  
The Relationship ◽  
Bonding Mode

Abstract Mo(CO)2(PPh3)2(MeCN)(η2-SO2), reacts with a number of unidentate or tridentate phosphines with displacement of both MeCN and PPh3. Mixtures of up to three different isomers are obtained the structures of which are assigned by IR , 1H, 13C, and 31PNMR , and in one case by X-ray crystallography. The results support earlier observations concerning the relationship between the disposition of donor and acceptor ligands around the metal and the bonding mode of SO2 .

Structure and Conformation of Photosynthetic Pigments and Related Compounds, 8 [1]Molecular Structure of an Iron(III) Chlorophyll Derivative-Chloro(phytochlorinato methyl ester)iron(III)

1995 ◽  
Vol 50 (1) ◽  
pp. 139-146 ◽  
Author(s):  
Mathias O. Senge ◽  
Karin Ruhlandt-Senge ◽  
Kevin M. Smith
Keyword(s):  
Molecular Structure ◽  
Crystal And Molecular Structure ◽  
Axial Ligand ◽  
Monoclinic Space Group ◽  
X Ray ◽  
X Ray Crystallography ◽  
Chlorophyll Derivative ◽  
Cell Dimensions ◽  
Unit Cell Dimensions ◽  
Related Compounds

The crystal and molecular structure of chloro(methyl phytochlorinato)iron(III), 4, have been determined by single crystal X-ray crystallography to obtain further information on the conformation of metallochlorins related to chlorophyll. The compound crystallized with two independent molecules mainly distinguished by the orientation of the axial ligand. The macrocycles show significant deviations from planarity larger than those observed in corresponding magnesium(II) complexes. The overall type of distortion is similar to those found in chlorophyllides. Compound 4 crystallized in the monoclinic space group P21 (MoKa,λ = 0.71063 A) with unit cell dimensions a = 12.035(6) Å, b = 13.396(8) Å, c = 19.04(2), b = 97.51(2) Å, Z = 4, V = 3043(4) Å3. The structure was refined to an R-value of 0.075 on the basis of 3974 reflections with I > 3.0σ(Ι) (130 Κ).

Crystal and molecular structure of cis,anti,cis-N,N′-dibenzoyl-3,12-diazatricyclo[6.4.0.02,7]dodecan-6,12-dione and cis,anti,cis-N,N′-dibenzoyl-3,9-diazatricyclo[6.4.0.02,7]dodecan-6,9-dione. Photodimers of N-benzoylcyclohex-2-ene-4-one

1981 ◽  
Vol 59 (22) ◽  
pp. 3136-3140 ◽  
Author(s):  
T. Stanley Cameron ◽  
Ruth E. Cordes ◽  
B. Mario Pinto ◽  
Walter A. Szarek
Keyword(s):  
Molecular Structure ◽  
Crystal And Molecular Structure ◽  
Benzene Solution ◽  
X Ray ◽  
X Ray Crystallography

The products of photodimerization of N-benzoylazacyclohex-2-ene-4-one (1) have been investigated by X-ray crystallography. Irradiation of a benzene solution of compound 1 leads to a mixture of head-to-head and head-to-tail, cis,anti,cis adducts, namely, cis,anti,cis-N,N′-dibenzoyl-3,12-diazatricyclo[6.4.0.02,7]dodecan-6,12-dione and cis,anti,cis-N,N′-dibenzoyl-3,9-diazatricyclo[6.4.0.02,7]dodecan-6,9-dione, compounds 2 and 3 respectively.

[(Dimethylamino)methyl]ferrocene as an Amine Ligand: Study of the Bonding and X-Ray Crystal and Molecular Structure of the Pentacarbonyl{[(dimethylamino)methyl]ferrocene}tungsten Complex

2002 ◽  
Vol 67 (2) ◽  
pp. 228-234 ◽  
Author(s):  
Axel Fischer ◽  
Frank T. Edelmann ◽  
Klaus Jacob ◽  
Ivan Pavlík ◽  
Martin Pavlišta
Keyword(s):  
Molecular Structure ◽  
Single Crystal ◽  
Crystal And Molecular Structure ◽  
X Ray Diffraction ◽  
Amine Nitrogen ◽  
X Ray ◽  
Nmr Data ◽  
Amine Ligand ◽  
C Nmr

The heterodinuclear complex [W(CO)5(Me2NCH2Fc)] (Fc = ferrocenyl) (1) resulting from the reaction of [(dimethylamino)methyl]ferrocene (2) and [W(CO)6] was studied by single-crystal X-ray diffraction. Its molecular structure confirms the coordination of the amine nitrogen in 2 to tungsten (d(W-N) = 2.359(5) Å) and reveals its trans-influence in the W(CO)5 moiety. The structure is discussed in relation to several previously referred spectroscopic (IR, UV-VIS, 13C NMR) data.

Enantioselektive Gewinnung und Kristallstruktur des Ecstasy-Analogons N-Ethyl-3,4-methylendioxyamphetamin-HCl (MDE) und seiner beiden Hauptmetaboliten MDA und HME / Enantioselective Production and Crystal Structure of the Ecstasy Analogue N-Ethyl-3,4- methylenedioxyamphetamine-HCl (MDE) and its Major Metabolites MDA and HME

2000 ◽  
Vol 55 (12) ◽  
pp. 1124-1130 ◽  
Author(s):  
Jochen Büchler ◽  
Cacilia Maichle-Mössmer ◽  
Karl-Artur Kovar
Keyword(s):  
Molecular Structure ◽  
Crystal Structure ◽  
Hydrogen Bonding ◽  
Crystal Lattice ◽  
Crystal And Molecular Structure ◽  
Synthetic Route ◽  
X Ray ◽  
X Ray Crystallography

A synthetic route to the production of the pure enantiomers of the ecstasy-analogue N-Ethyl- 3,4-methylenedioxyamphetamine (MDE) and its major metabolites MDA and HME is presented. The crystal and molecular structure of these compounds has been determined by X-ray crystallography. The hydrogen bonding in the crystal lattice is examined and significant differences were found by comparing (R)- and (S)-MDA-HCl.

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