Excited State Properties of Myochrysin and Auranofin
1996 ◽
Vol 51
(8)
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pp. 1067-1071
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Keyword(s):
Myochrysin (sodium aurothiomalate hydrate) and auranofin [2,3,4,6-tetra-O-acetyl-1-thio-β-D-glucopyranosato-S)(triethylphospine)gold(I)] are luminescent in the solid state and in ethanol glasses at 77 K (myochrysin: λmax = 600 nm; auranofin: 618 nm). Aqueous myochrysin and auranofin in acetonitrile undergo a photodecomposition. It is assumed that the luminecence originates from a metal-centered ds excited state with partial ligand-to-metal charge transfer (LMCT) character while the photodecomposition is induced by LMCT excitation.
Keyword(s):
Keyword(s):
2019 ◽
Vol 58
(22)
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pp. 15320-15329
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Keyword(s):
1988 ◽
Vol 92
(21)
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pp. 5982-5986
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Keyword(s):
2019 ◽
Vol 141
(29)
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pp. 11572-11582
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Keyword(s):
2018 ◽
Vol 122
(34)
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pp. 20019-20026
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2014 ◽
Vol 615
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pp. 105-110
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