Syntheses and Spectroscopic Studies of Some New Diazaphospholes and Diazaphosphorinanes. Crystal Structure of 4
2005 ◽
Vol 60
(10)
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pp. 1021-1026
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Keyword(s):
X Ray
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New diazaphospholes and diazaphosphorinanes with formula were synthesized and characterized by 1H, 13C, 31P NMR and IR spectroscopy and elemental analysis. The structure of compound 1 has been determined by X-ray crystallography. A one-dimensional polymeric chain was observed in the crystalline lattice produced by intermolecular -P=O. . .H-N- and -C=O. . .H-N-hydrogen bonds. Compounds 1 and 2 contain five-membered rings and show high values for 2J(PNH) and 2J(P,C) coupling constants due to the ring strain. These constants are reduced seriously in compounds with six-membered rings. In compound 6 with CCl3C(O)NH moiety, all phosphorus-hydrogen couplings are zero.
2005 ◽
Vol 220
(1)
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Keyword(s):
2013 ◽
Vol 68
(2)
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pp. 161-167
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2003 ◽
Vol 17
(2-3)
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pp. 345-353
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2011 ◽
Vol 76
(4)
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pp. 529-537
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2015 ◽
Vol 48
(3)
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pp. 901-905
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1998 ◽
Vol 53
(7)
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pp. 699-703
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2014 ◽
Vol 70
(12)
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pp. 1169-1173
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