Synthesis and crystal structure of a homoleptic diruthenium complex containing tetra-2-pyridyl-1,4-pyrazine (tppz)
2017 ◽
Vol 72
(10)
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pp. 759-762
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Keyword(s):
X Ray
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AbstractTreatment of hydrated ruthenium(III) chloride with tetra-2-pyridyl-1,4-pyrazine (tppz) in refluxing ethoxyethanol afforded the homoleptic dinuclear complex [(tppz)Ru(μ-tppz)Ru(tppz)]4+ (1) besides small amounts of the species [Ru(tppz)2]2+. The title complex 1 was obtained as purple crystals and characterized as its hexafluoridophosphate salt by NMR spectroscopy, mass spectrometry and microanalyses. The molecular structure of 1(PF6)4 has been established by X-ray crystallography.
2010 ◽
Vol 65
(2)
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pp. 128-134
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2006 ◽
Vol 61
(11)
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pp. 1421-1425
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2012 ◽
Vol 18
(52)
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pp. 16665-16676
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2007 ◽
Vol 62
(9)
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pp. 1133-1138
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