Thiosugars, 17. Preparation and structure of a novel deoxythionucleoside
Abstract1-(3′,5′-Anhydro-2′-deoxy-3′-thio-D-lyxo-furanosyl)thymine is prepared from the corresponding methyl pentofuranoside by using the silyl Hilbert–Johnson reaction. The α- and β-anomers are separated by column chromatography and their configuration is elucidated by NMR spectroscopy and, in case of the α-anomer, by an X-ray structure determination.
2006 ◽
Vol 61
(5)
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pp. 577-582
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Keyword(s):
1993 ◽
Vol 26
(1)
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pp. 49-125
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