Synthesis, crystal structure, and magnetic properties of a multicage compound: [(Me)2EtNH][Mn(N3)3] with a perovskite-related structure
2019 ◽
Vol 74
(4)
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pp. 335-339
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Keyword(s):
X Ray
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AbstractA new multicage compound [(Me)2EtNH][Mn(N3)3] (Me = methyl, Et = ethyl) with a perovskite-related structure has been synthesized. The manganese(II) cations are bridged by end-to-end (EE) azide anions to form three-dimensional cages with the N,N-dimethylethylammonium cations residing in the cavities of the [Mn(N3)3]nn− cages. The compound has been characterized by single-crystal X-ray diffraction, IR spectroscopy, elemental analysis, second-harmonic generation, and magnetic measurements. The second-harmonic generation results support its noncentrosymmetric polar crystal structure. Magnetic susceptibility measurements show antiferromagnetic interactions among the MnII ions.
Keyword(s):
Keyword(s):
2010 ◽
Vol 43
(3)
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pp. 491-497
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1994 ◽
Vol 91
(9)
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pp. 757-759
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Keyword(s):
2007 ◽
Vol 80
(5)
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pp. 960-962
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