Impedance of the Hydrogen Polymer Fuel Cell Electrode. Theory and Experiments
2000 ◽
Vol 214
(7)
◽
Keyword(s):
We derive the impedance for the hydrogen electrode in the polymer membrane fuel cell from irreversible thermodynamics. The results predict a surface contribution to the cell impedance that can give two semi-circles in the Nyquist diagram. The equivalent circuit of the impedance is shown. The high-frequency contribution is connected to the oscillation of dipoles consisting of free charges in the surface, while the low-frequency contribution is connected to the electrochemical reaction. This can be explained by a slowly relaxing proton conducting polymer network at the reaction site.
Keyword(s):
2011 ◽
Vol 36
(22)
◽
pp. 14815-14822
◽
Keyword(s):
2009 ◽
Vol 191
(1)
◽
pp. 10-15
◽
2017 ◽
Vol 4
(6)
◽
pp. 1289-1304
◽
Keyword(s):
2014 ◽
Vol 39
(25)
◽
pp. 13694-13700
◽
Keyword(s):
2012 ◽
Vol 83
(5)
◽
pp. 053707
◽
2019 ◽
Vol 44
(24)
◽
pp. 12356-12364
◽