Effect of BaCu(B2O5) on the sintering temperature and microwave dielectric properties of Ba(Nd0.8Bi0.2)2Ti4O12 ceramics

2010 ◽  
Vol 25 (12) ◽  
pp. 2380-2383 ◽  
Author(s):  
Yi Zeng ◽  
Hong Wang ◽  
Huanfu Zhou

The effect of BaCu(B2O5) (BCB) on the sintering temperature and microwave dielectric properties of Ba(Nd0.8Bi0.2)2Ti4O12 (BNBT) ceramics was investigated. The sintering temperature of the BNBT ceramics was significantly reduced from 1300 to 900 °C. Due to adding BCB into Ba(Nd1–xBix)2Ti4O12, the temperature coefficient of resonant frequency can be adjusted to zero with BCB content increasing. Good microwave dielectric properties of quality factor (Q×f) = 2600 GHz, εr = 75, and τf = 5 ppm/°C were obtained for BNBT with 7 wt% BCB sintered at 925 °C for 2 h, which make it a potential candidate for low temperature cofired ceramics applications.

2007 ◽  
Vol 336-338 ◽  
pp. 279-282
Author(s):  
In Sun Cho ◽  
Sang Gu Kang ◽  
Dong Wan Kim ◽  
Kug Sun Hong

The effects of CuO and V2O5 addition on sintering behaviors and microwave dielectric properties of 0.7Ca2P2O7-0.3TiO2 ceramics were investigated. With CuO and V2O5 addition, the sintering temperature of 0.7Ca2P2O7-0.3TiO2 can be effectively reduced from 1150 to 950oC. The dielectric constant of the low fired 0.7Ca2P2O7-0.3TiO2 ceramics was not significantly changed while the quality factor was affected by additives. The temperature coefficient of resonant frequency value was increased in negative value with the additive contents. V2O5 and CuO additives effectively improved the densification and dielectric properties of 0.7Ca2P2O7-0.3TiO2 ceramics. The correlation between the phase constituents and the dielectric properties was investigated with additive contents.


1999 ◽  
Vol 14 (9) ◽  
pp. 3567-3570 ◽  
Author(s):  
Ji-Won Choi ◽  
Chong-Yun Kang ◽  
Seok-Jin Yoon ◽  
Hyun-Jai Kim ◽  
Hyung-Jin Jung ◽  
...  

The microwave dielectric properties of Ca[(Li1/3Nb2/3)1−xMx]O3−δ (M = Sn, Ti, 0 ≤ x ≤ 0.5) ceramics were investigated. In general, the ceramics prepared were multiphase materials. However, single-phase specimens having orthorhombic perovskite structure similar to CaTiO3 could be obtained in the vicinity of Sn = 0.2 to 0.3, and Ti = 0.2. As Sn concentration increased, the dielectric constant (εr) decreased and the quality factor (Q) significantly increased within the limited Sn concentration. As Ti concentration increased, the dielectric constant (εr) increased, the quality factor (Q) decreased, and the temperature coefficient of resonant frequency (τf) changed from a negative to positive value. The temperature coefficient of resonant frequency of 0 ppm/°C was realized at Ti = 0.2. The Q · fo value and εr for this composition were found to be 26100 GHz and 38.6, respectively.


2012 ◽  
Vol 535-537 ◽  
pp. 832-835
Author(s):  
Hui Xiong ◽  
Gang Xiong ◽  
Cui Hua She

The effects of B2O3 on the sinterability and microwave dielectric properties of Ca[(Li1/3Nb2/3)0.95Zr0.05]O3−δ−0.04TiO2 (CLNZ−0.04TiO2) ceramics were investigated . B2O3 doping can effectively reduce sintering temperatue by 150~200°C. The temperature coefficient of resonator frequency τf increased with an increase of B2O3 content and sintering temperatue. When B2O3 of 2wt% were added, the optimum microwave dielectric properties: εr =31.8,Qf =17240GHz and τf = − 5.9×10−6/°C were obtained at the sintering temperature of 950°C.


2012 ◽  
Vol 476-478 ◽  
pp. 940-943 ◽  
Author(s):  
Zhong Yan ◽  
Jin Liang Huang ◽  
Yong Jun Gu ◽  
Biao Jin ◽  
Ru Yu Wang

ZnNb2O6 ceramics doped with V2O5 were prepared by conventional mixed solid method. The effects of V2O5 addition on the microstructure and the microwave dielectric properties of ZnNb2O6 ceramics were investigated systematically. The sintering temperature of ZnNb2O6 ceramics with 1.0wt.% V2O5 addition can be effectively reduced from 1150°C to 1050°C. The secondary phase ZnV2O6 was observed in sintered samples with V2O5 addition content higher than 1.0wt.%. For 0.3–3wt.%V2O5-doped ZnNb2O6 ceramics, The dielectric constants (εr) of densified samples were higher than that of undoped ZnNb2O6 ceramics. The temperature coefficient of resonant frequency (τf) were shifted toward zero direction with the increase of V2O5 addition, However, the dielectric loss (tanδ=1/Q) increased. The 1.0wt.% V2O5-doped ZnNb2O6 ceramics sintered at 1050°C for 3h have the optimum microwave dielectric properties: εr=28, tanδ=0.0006 and τf=-42.5 ppm/°C.


2003 ◽  
Vol 783 ◽  
Author(s):  
Cheng-Liang Huang ◽  
Yuan-Bin Chen ◽  
Ching-Wen Lo

ABSTRACTThe microwave dielectric properties of (1-x)CaTiO3-xNd(Mg1/2Ti1/2)O3 (0.1≤x≤1.0) have been investigated. The system forms a solid solution throughout the entire compositional range. The dielectric constant decreases from 152 to 27 as x varies from 0.1 to 1.0. In the (1-x)CaTiO3-xNd(Mg1/2Ti1/2)O3 system, the microwave dielectric properties can be effectively controlled by varying the x value. A maximum quality factor Qxf=43000GHz (where f is the resonant frequency) was achieved for samples with x=0.9, although the dielectric properties varied with sintering temperature. The Qxf value of (1-x)CaTiO3-xNd(Mg1/2Ti1/2)O3 almost increased up to 1500°C, after which it decreased. At 1400°C, 0.1CaTiO3-0.9Nd(Mg1/2Ti1/2)O3 ceramics gives a dielectric constant εr of 42, a Qxf value of 35000 (GHz) and a τf value of -10 (ppm/°C).


2014 ◽  
Vol 556-562 ◽  
pp. 318-321
Author(s):  
Gang Xiong

The effects of ZnO-B2O3-Na2O(ZBN) glass on the sinterability and microwave dielectric properties of Ca [(Li1/3Nb2/3)0.92Zr0.08]O3−δ −0.05TiO2 ceramics were investigated . ZBN glass doping can effectively reduce sintering temperatue by 100~150oC. The temperature coefficient of resonator frequency τf increased with an increase of ZBN glass content and sintering temperatue. When ZBN glass of 1.8wt% were added, the optimum microwave dielectric properties: εr=32.8, Qf =13420GHz and τf= − 4.3×10−6/oC were obtained at the sintering temperature of 1000oC.


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