Characterization of Dye-Sensitized Solar Cell with Different Nanoparticle sizes

2011 ◽  
Vol 1322 ◽  
Author(s):  
Aung Htun ◽  
Lakshmi V. Munukutla ◽  
Sailaja Radhakrishnan ◽  
Chih Y. Jen ◽  
Arunachalanadar M. Kannan ◽  
...  
Keyword(s):  
Solar Cell ◽  
Layer Thickness ◽  
Short Circuit ◽  
Short Circuit Current ◽  
Open Circuit ◽  
Nanoparticle Size ◽  
Cell Efficiency ◽  
Dye Sensitized ◽  
20 Nm ◽  
Nanoparticle Sizes

ABSTRACTThe Dye-sensitized Solar Cell (DSSC) has been regarded as the next-generation solar cell because of its simple and low cost fabrication process. The experiments for optimizing the cell efficiency were carried out in this work include varying the TiO2 layer thickness on the working electrode and determining the most favorable nanoparticle size in the TiO2 paste. The TiO2 electrode or working electrode was fabricated using screen printing technique with the Coatema tool with thicknesses ranging from ~20 to 66 μm. It was observed that both open circuit voltage and short circuit current were found to have measurable dependence on the TiO2 layer thickness. The open circuit voltage changed from 0.77 to 0.82 V and correspondingly the short circuit current also varied from ~19 to 23 mA/cm2 depending on the TiO2 layer thickness. Additionally, the cell with 40 μm TiO2 thickness showed 9.06% photo conversion efficiency compared to 6.4% and 8.5% efficiency obtained for the cells with 20 μm and 66 μm TiO2 thicknesses respectively. The second part of the experiment was conducted using three different nanoparticle sizes of 13 nm, 20 nm and 37nm in the TiO2 layer to identify optimum nanoparticle size by maintaining the TiO2 film thickness at 40 μm. The cell with 20 nm size nanoparticle, in combination with 40 μm TiO2 thickness showed 11.2% efficiency that is in par or slightly better than the efficiency value reported for the DSSC in the literature as of now. The work described in this paper showed best possible values for the TiO2 layer thickness and nanoparticle size in the TiO2 for obtaining improved cell efficiency of 11.2%.

Characteristics of Dye-Sensitized Solar Cells Using Dye from Pitaya Fruit

2015 ◽  
Vol 793 ◽  
pp. 450-454 ◽  
Author(s):  
N. Gomesh ◽  
R. Syafinar ◽  
Muhamad Irwanto ◽  
Y.M. Irwan ◽  
M. Fareq ◽  
...  
Keyword(s):  
Solar Cell ◽  
Short Circuit ◽  
Dye Sensitized Solar Cells ◽  
Short Circuit Current ◽  
Liquid Electrolyte ◽  
Open Circuit ◽  
Dye Sensitized Solar Cell ◽  
Photoelectrochemical Performance ◽  
Cell Efficiency ◽  
Dye Sensitized

Dye-sensitized solar cell (DSSC) consists of TiO2 nanoporous coating which acts as a photo electrode, a sensitizer of dye molecules soaked in the TiO2 film, liquid electrolyte and a counter electrode. This paper focuses on the usage of a sensitizer from the Pitaya fruit. Pitaya or commonly known as dragon fruit (Hylocereus polyrhizus) was extracted and used as a sensitizer to fabricate the dye sensitized solar cell (DSSC). The photoelectrochemical performance of Pitaya based solar cell shows an open circuit voltage (VOC) of 237 mV, short circuit current (ISC) of 4.98 mA, fill factor (FF) of 0.51, solar cell efficiency (η) of 0.70 % and has a peak absorbance rate of 2.7 at 550 nm. The photoelectrochemical and UV-Visible light absorbance performance of Pitaya-DSSC shows good potential in future solar cell fabrication.

scholarly journals Efficiency enhancement of natural dye sensitized solar cell by optimizing electrode fabrication parameters

2018 ◽  
Vol 35 (4) ◽  
pp. 816-823 ◽  
Author(s):  
M. Khalid Hossain ◽  
M.F. Pervez ◽  
S. Tayyaba ◽  
M. Jalal Uddin ◽  
A.A. Mortuza ◽  
...  
Keyword(s):  
Solar Cell ◽  
Counter Electrode ◽  
Short Circuit ◽  
Short Circuit Current ◽  
Short Circuit Current Density ◽  
Open Circuit ◽  
Dye Sensitized Solar Cell ◽  
Cell Efficiency ◽  
Dye Sensitized ◽  
Candle Flame

Abstract Efficiency of dye-sensitized solar cell (DSSC) depends on several interrelated factors such as type and concentration of dye, type and thickness of photoelectrode and counter electrode. Optimized combination of these factors leads to a more efficient cell. This paper presents the effect of these parameters on cell efficiency. TiO2 nanoporous thin films of different thicknesses (5 μm to 25 μm) were fabricated on indium doped tin oxide (ITO) coated glass by doctor blading method and characterized by inverted microscope, stylus surface profiler and scanning electron microscope (SEM). Natural organic dye of different concentrations, extracted from turmeric, was prepared with ethanol solvent. Different combinations of dye concentrations and film thicknesses along with different types of carbon catalyst have been investigated by I-V characterization. The result shows that the cell made of a counter electrode catalyst material prepared by candle flame carbon combined with about 15 μm thick photoelectrode and 100 mg/mL dye in ethanol solvent, achieves the highest efficiency of 0.45 %, with open circuit voltage of 566 mV and short circuit current density of 1.02 mA/cm2.

scholarly journals Effect of Chenodeoxycholic Acid as Dye Co-Adsorbent and ZnO Blocking Layer in Improving The Performance of Rose Bengal Dye Based Dye Sensitized Solar Cells

2021 ◽  
Author(s):  
Rajat Biswas ◽  
Suman Chatterjee
Keyword(s):  
Solar Cell ◽  
Chenodeoxycholic Acid ◽  
Short Circuit ◽  
Dye Sensitized Solar Cells ◽  
Short Circuit Current ◽  
Open Circuit ◽  
Blocking Layer ◽  
Cell Efficiency ◽  
Dye Sensitized ◽  
Dye Aggregation

Abstract Effective suppression of dye aggregation on the photoanode surface of dye sensitized solar cell plays a key role in improving the solar cell efficiency. Chenodeoxycholic acid (CDCA) is a very popular anti dye aggregation material used in Dye sensitized solar cells. However, the selection of an improper concentration of CDCA may lead to decreased solar cell efficiency by lowering the open circuit voltage and short circuit current as a consequence of reduced dye loading. The influence of chenodeoxycholic acid (CDCA) as a dye co-adsorbent on the performance of DSSCs fabricated using Rose Bengal dye was studied in this paper. The concentration of the CDCA solution was varied to identify the optimum value for the best device performance. Aside from this, the effect of a very thin and compact ZnO blocking layer was also investigated to reduce the recombination. With photovoltaic parameters such as short circuit current density (Jsc) = 1.98 mA/cm2, open circuit voltage (Voc) = 0.58 V, and fill factor (FF) = 0.43, the traditional cell displayed an overall conversion efficiency of 0.50 %, while the power conversion efficiency was found to be increased to 0.97 % ( Jsc = 2.80 mA/cm2, Voc= 0.64, FF = 0.58 ) when CDCA was added at optimised concentration of 8 mM. Reduced dye aggregation and increased electron injection in the presence of CDCA may be accounted for the DSSC's remarkable improvement in efficiency. Moreover, the combined effect of 8 mM CDCA and the compact ZnO blocking layer dramatically enhanced the efficiency further to 1.23 % (Jsc = 3.09 mA/cm2, Voc= 0.66, FF = 60 ). Electrochemical impedance spectroscopic (EIS) analysis revealed that the addition of CDCA as a co-adsorbent in the dye solution and addition of ZnO blocking layer resulted in significantly improved electron lifetime and reduced electron recombination yielding improved Jsc, Voc and η.

scholarly journals CdTe-Based Thin Film Solar Cells: Past, Present and Future

Energies ◽  
2021 ◽  
Vol 14 (6) ◽  
pp. 1684
Author(s):  
Alessandro Romeo ◽  
Elisa Artegiani
Keyword(s):  
Thin Film ◽  
Solar Cells ◽  
Solar Cell ◽  
Short Circuit ◽  
Short Circuit Current ◽  
Short Circuit Current Density ◽  
Open Circuit ◽  
Early Years ◽  
Solar Cell Efficiency ◽  
Cell Efficiency

CdTe is a very robust and chemically stable material and for this reason its related solar cell thin film photovoltaic technology is now the only thin film technology in the first 10 top producers in the world. CdTe has an optimum band gap for the Schockley-Queisser limit and could deliver very high efficiencies as single junction device of more than 32%, with an open circuit voltage of 1 V and a short circuit current density exceeding 30 mA/cm2. CdTe solar cells were introduced at the beginning of the 70s and they have been studied and implemented particularly in the last 30 years. The strong improvement in efficiency in the last 5 years was obtained by a new redesign of the CdTe solar cell device reaching a single solar cell efficiency of 22.1% and a module efficiency of 19%. In this paper we describe the fabrication process following the history of the solar cell as it was developed in the early years up to the latest development and changes. Moreover the paper also presents future possible alternative absorbers and discusses the only apparently controversial environmental impacts of this fantastic technology.

In Situ Quaternized Gel Electrolyte for Quasi-Solid-State Dye-Sensitized Solar Cell

2011 ◽  
Vol 415-417 ◽  
pp. 1586-1589
Author(s):  
Yu Hua Dai ◽  
Xiao Lei Sun ◽  
Jing Lian Wang ◽  
Ming Shan Yang
Keyword(s):  
Solar Cell ◽  
Fill Factor ◽  
Short Circuit ◽  
Short Circuit Current ◽  
Liquid Electrolyte ◽  
Open Circuit ◽  
Gel Electrolyte ◽  
Dye Sensitized Solar Cell ◽  
Dye Sensitized

A series of copolymers P(VP-HEMA) composed of hydroxyl ethyl methacrylate (HEMA) and 4-vinyl pyridine (VP) were prepared by a solution copolymerization technique. Based on the copolymer P(VP-HEMA) prepared by the content of VP 50%, the amount of AIBN 3% and the optimized liquid electrolyte, a polymer solution electrolyte with concentration of 9.0% was formed. By addition of 1,4-dibromobutane into the solution, the copolymer gel electrolyte with higher conductivity 6.14mS/cm was prepared. Gelation is caused by the quaterisation between the group of pyridine in P(HEMA-VP) and 1,4-dibromobutane. Based on the copolymer gel electrolyte, a dye-sensitized solar cell was fabricated with short-circuit current of 13.62mA/cm2,open circuit voltage of 0.72V, fill factor of 0.5465 and an overall conversion efficiency of 5.24% under irradiation 100mW/cm2(AM1.5).

An Investigation on Dye-Sensitized Solar Cell Performance Influenced by Radiant Intensity and Illuminated Area in Concentrating Photovoltaic System

2014 ◽  
Vol 1070-1072 ◽  
pp. 616-619
Author(s):  
Wen Bo Xiao ◽  
Jin Dai ◽  
Guo Hua Tu ◽  
Hua Ming Wu
Keyword(s):  
Solar Cell ◽  
Open Circuit Voltage ◽  
Short Circuit ◽  
Short Circuit Current ◽  
Open Circuit ◽  
Photovoltaic System ◽  
Dye Sensitized Solar Cell ◽  
Solar Cell Performance ◽  
Radiant Intensity ◽  
Dye Sensitized

The dye-sensitized solar cell performances influenced by radiant intensity and illuminated area in concentrating photovoltaic system are investigated experimentally and discussed theoretically. The results show that, under the same irradiated cells area, the short-circuit current is linearly increasing with the radiant intensity and the open-circuit voltage follows a logarithmic function of the radiant intensity. And, it is turned out that the short-circuit current and open-circuit voltage are obviously enhanced by increasing the illuminated cells surface area at the same radiant intensity. However, that growth trends will decline with an increase of the illuminated area. The reason is more defects involved in the process of increasing illumination area. All results can be interpreted using an equivalent circuit of a single diode model. A good agreement can be observed from the fitting curves. It is of great significance for current photovoltaic research.

scholarly journals The Effect of Annealing Time on TiO2–Based Dye Sensitized Solar Cell: Natural Pigment

2018 ◽  
Vol 6 (6) ◽  
Author(s):  
Hafeez Yusuf Hafeez ◽  
Bala Ismail Adam
Keyword(s):  
Solar Cell ◽  
Annealing Time ◽  
Fill Factor ◽  
Short Circuit ◽  
Short Circuit Current ◽  
Energy Conversion Efficiency ◽  
Short Circuit Current Density ◽  
Open Circuit ◽  
Dye Sensitized Solar Cell ◽  
Dye Sensitized

In this analytical approach we fabricate and characterized a Titanium Dioxide Dye sensitized solar cell using Doctor-Blade Technique. The samples were given annealing treatment at various time of 20, 30 and 40 minutes respectivelyat constant annealing temperature of 450oC. The device under test (DUT) were tested using a Kiethley 2400, source meter under A.M 1.5 (1000W/m2) illumination from a Newport class A solar simulator.The results shows that at the miscellaneous annealing time, the open circuit voltagesVoc= 0.28V, 0.30V and 0.29V, the short circuit current density Jsc=95.5µAcm-2 , 104.1µAcm-2and 105µAcm-2, the fill factor FF= 0.411, 0.448 and 0.525 and the energy conversion efficiency, η = 0.011, 0.014 and 0.016 respectively.With best results of open circuit voltage Voc=0.30, short circuit current density Jsc= 105mAcm-2, fill factor FF= 0.525 and energy conversion efficiency η= 0.016 was achieved.It was observed that the power density, Fill Factor and efficiency increases with increasewith increase in annealing time.

scholarly journals Erythrosine and Rhodamine Dyes as a Solar Cell Concentrator

2019 ◽  
Vol 54 (4) ◽  
Author(s):  
Suhad Hassan Mohsen ◽  
Luma Hafedh Abed Oneizah ◽  
Warood Kream Alaarage
Keyword(s):  
Solar Cell ◽  
Fill Factor ◽  
Organic Dyes ◽  
Short Circuit ◽  
Short Circuit Current ◽  
Photovoltaic Cell ◽  
Open Circuit ◽  
Solar Cell Efficiency ◽  
Cell Efficiency ◽  
Rhodamine Dyes

In this work, a solar and flash center was created by combining two organic dyes, erythrosine and rhodamine, with completely different concentrations. Throughout the spectra of fluorescence (F) and absorbance (A), the quantitative efficiency of the dye mixture was determined. It was manufactured from a panel of epoxy containing a mixture of the two dyes using open-circuit voltage (Voc), short-circuit current (Isc), fill factor (FF), and solar cell efficiency (η). It was found that a 1 mm thickness of the panel works best in increasing the efficiency of the photovoltaic cell.

scholarly journals The Effect of Gel-Electrolyte on Dye Sensitized Solar Cell (DSSC) Prototype based on Nanosized-TiO2 Using Mangosteen Pericarp as Absorber

2017 ◽  
Vol 3 (1) ◽  
pp. 186
Author(s):  
Biaunik Niski Kumila ◽  
Gontjang Prajitno
Keyword(s):  
Solar Cell ◽  
Short Circuit ◽  
Short Circuit Current ◽  
Open Circuit ◽  
Gel Electrolyte ◽  
Dye Sensitized Solar Cell ◽  
Precipitation Method ◽  
Dye Sensitized ◽  
Near Ultraviolet ◽  
Co Precipitation

<p style="text-align: justify;">Dye Sensitized Solar Cell (DSSC) with Fluorine deped Tin Oxide (FTO) substrat and nanosize-TiO2 layer sensitized by “dye” ,mangosteen pericarp extract, was succesfully fabricated. Gel-Electrolyte as electron regenerator was synthesized by adding Polyethylene Glycol (PEG) 1000 to electrolyte solution while nanosize-TiO2 was synthesized by co-precipitation method from TiCl3 solution. The crystal size of TiO2 characterized by X-Ray Diffraction is 10.5 nm in size. The solar absorbance of “dye” mangosteen pericarp was measured using UV-Vis Spectrophotometer and it showed that the dye can absorb photon at Near Ultraviolet (NUV) to yellow visible light. Nanosize-TiO2 based DSSC with gel-electrolyte successfully reached short circuit current up to 30.9 μA, open circuit voltage 398.3 mV and performed the long term stability. ©2017 JNSMR UIN Walisongo. All rights reserved</p>

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