Characteristics of Dye-Sensitized Solar Cells Using Dye from Pitaya Fruit

2015 ◽  
Vol 793 ◽  
pp. 450-454 ◽  
Author(s):  
N. Gomesh ◽  
R. Syafinar ◽  
Muhamad Irwanto ◽  
Y.M. Irwan ◽  
M. Fareq ◽  
...  

Dye-sensitized solar cell (DSSC) consists of TiO2 nanoporous coating which acts as a photo electrode, a sensitizer of dye molecules soaked in the TiO2 film, liquid electrolyte and a counter electrode. This paper focuses on the usage of a sensitizer from the Pitaya fruit. Pitaya or commonly known as dragon fruit (Hylocereus polyrhizus) was extracted and used as a sensitizer to fabricate the dye sensitized solar cell (DSSC). The photoelectrochemical performance of Pitaya based solar cell shows an open circuit voltage (VOC) of 237 mV, short circuit current (ISC) of 4.98 mA, fill factor (FF) of 0.51, solar cell efficiency (η) of 0.70 % and has a peak absorbance rate of 2.7 at 550 nm. The photoelectrochemical and UV-Visible light absorbance performance of Pitaya-DSSC shows good potential in future solar cell fabrication.

2011 ◽  
Vol 415-417 ◽  
pp. 1586-1589
Author(s):  
Yu Hua Dai ◽  
Xiao Lei Sun ◽  
Jing Lian Wang ◽  
Ming Shan Yang

A series of copolymers P(VP-HEMA) composed of hydroxyl ethyl methacrylate (HEMA) and 4-vinyl pyridine (VP) were prepared by a solution copolymerization technique. Based on the copolymer P(VP-HEMA) prepared by the content of VP 50%, the amount of AIBN 3% and the optimized liquid electrolyte, a polymer solution electrolyte with concentration of 9.0% was formed. By addition of 1,4-dibromobutane into the solution, the copolymer gel electrolyte with higher conductivity 6.14mS/cm was prepared. Gelation is caused by the quaterisation between the group of pyridine in P(HEMA-VP) and 1,4-dibromobutane. Based on the copolymer gel electrolyte, a dye-sensitized solar cell was fabricated with short-circuit current of 13.62mA/cm2,open circuit voltage of 0.72V, fill factor of 0.5465 and an overall conversion efficiency of 5.24% under irradiation 100mW/cm2(AM1.5).


2018 ◽  
Vol 35 (4) ◽  
pp. 816-823 ◽  
Author(s):  
M. Khalid Hossain ◽  
M.F. Pervez ◽  
S. Tayyaba ◽  
M. Jalal Uddin ◽  
A.A. Mortuza ◽  
...  

Abstract Efficiency of dye-sensitized solar cell (DSSC) depends on several interrelated factors such as type and concentration of dye, type and thickness of photoelectrode and counter electrode. Optimized combination of these factors leads to a more efficient cell. This paper presents the effect of these parameters on cell efficiency. TiO2 nanoporous thin films of different thicknesses (5 μm to 25 μm) were fabricated on indium doped tin oxide (ITO) coated glass by doctor blading method and characterized by inverted microscope, stylus surface profiler and scanning electron microscope (SEM). Natural organic dye of different concentrations, extracted from turmeric, was prepared with ethanol solvent. Different combinations of dye concentrations and film thicknesses along with different types of carbon catalyst have been investigated by I-V characterization. The result shows that the cell made of a counter electrode catalyst material prepared by candle flame carbon combined with about 15 μm thick photoelectrode and 100 mg/mL dye in ethanol solvent, achieves the highest efficiency of 0.45 %, with open circuit voltage of 566 mV and short circuit current density of 1.02 mA/cm2.


2021 ◽  
Author(s):  
Rajat Biswas ◽  
Suman Chatterjee

Abstract Effective suppression of dye aggregation on the photoanode surface of dye sensitized solar cell plays a key role in improving the solar cell efficiency. Chenodeoxycholic acid (CDCA) is a very popular anti dye aggregation material used in Dye sensitized solar cells. However, the selection of an improper concentration of CDCA may lead to decreased solar cell efficiency by lowering the open circuit voltage and short circuit current as a consequence of reduced dye loading. The influence of chenodeoxycholic acid (CDCA) as a dye co-adsorbent on the performance of DSSCs fabricated using Rose Bengal dye was studied in this paper. The concentration of the CDCA solution was varied to identify the optimum value for the best device performance. Aside from this, the effect of a very thin and compact ZnO blocking layer was also investigated to reduce the recombination. With photovoltaic parameters such as short circuit current density (Jsc) = 1.98 mA/cm2, open circuit voltage (Voc) = 0.58 V, and fill factor (FF) = 0.43, the traditional cell displayed an overall conversion efficiency of 0.50 %, while the power conversion efficiency was found to be increased to 0.97 % ( Jsc = 2.80 mA/cm2, Voc= 0.64, FF = 0.58 ) when CDCA was added at optimised concentration of 8 mM. Reduced dye aggregation and increased electron injection in the presence of CDCA may be accounted for the DSSC's remarkable improvement in efficiency. Moreover, the combined effect of 8 mM CDCA and the compact ZnO blocking layer dramatically enhanced the efficiency further to 1.23 % (Jsc = 3.09 mA/cm2, Voc= 0.66, FF = 60 ). Electrochemical impedance spectroscopic (EIS) analysis revealed that the addition of CDCA as a co-adsorbent in the dye solution and addition of ZnO blocking layer resulted in significantly improved electron lifetime and reduced electron recombination yielding improved Jsc, Voc and η.


Energies ◽  
2020 ◽  
Vol 13 (11) ◽  
pp. 2690
Author(s):  
Dariusz Augustowski ◽  
Paweł Kwaśnicki ◽  
Justyna Dziedzic ◽  
Jakub Rysz

The main efficiency loss is caused by an intensive recombination process at the interface of fluorine-doped tin oxide (FTO) and electrolyte in dye-sensitized solar cells. Electrons from the photoanode can be injected back to the redox electrolyte and, thus, can reduce the short circuit current. To avoid this, the effect of the electron blocking layer (EBL) was studied. An additional thin film of magnetron sputtered TiO2 was deposited directly onto the FTO glass. The obtained EBL was characterized by atomic force microscopy, scanning electron microscopy, optical profilometry, energy dispersive spectroscopy, Raman spectroscopy and UV-VIS-NIR spectrophotometry. The results of the current–voltage characteristics showed that both the short circuit current (Isc) and fill factor (FF) increased. Compared to traditional dye-sensitized solar cell (DSSC) architecture, the power conversion efficiency (η) increased from 4.67% to 6.07% for samples with a 7 × 7 mm2 active area and from 2.62% to 3.06% for those with an area of 7 × 80 mm2.


2019 ◽  
Vol 26 (03) ◽  
pp. 1850164 ◽  
Author(s):  
SWATI S. KULKARNI ◽  
S. S. HUSSAINI ◽  
GAJANAN A. BODKHE ◽  
MAHENDRA D. SHIRSAT

Titanium dioxide (TiO[Formula: see text] nanoparticles have been synthesized by the cost effective Sol–Gel technique. Characteristics of TiO2 nanoparticles were investigated by X-ray diffraction and Fourier Transform Infrared spectroscopy. The Eosin Y dye and dye extracted from Hibiscus tea have been successfully used in fabrication of the dye sensitized solar cell. The photovoltaic performance of the dye sensitized solar cell indicates that the short circuit photo current, open circuit voltage and efficiency of the DSSC using Eosin Y dye is 10 times more compared to the DSSC using the Hibiscus dye.


2012 ◽  
Vol 2012 ◽  
pp. 1-6 ◽  
Author(s):  
Seigo Ito ◽  
Kaoru Takahashi

To improve the durability of dye-sensitized solar cells (DSCs), monolithic DSCs with ionic liquid electrolyte were studied. Deposited by screen printing, a carbon layer was successfully fabricated that did not crack or peel when annealing was employed beforehand. Optimized electrodes exhibited photovoltaic characteristics of 0.608 V open-circuit voltage, 6.90 cm−2 mA short-circuit current, and 0.491 fill factor, yielding 2.06% power conversion efficiency. The monolithic DSC using ionic liquid electrolyte was thermally durable and operated stably for 1000 h at 80°C.


2014 ◽  
Vol 1070-1072 ◽  
pp. 616-619
Author(s):  
Wen Bo Xiao ◽  
Jin Dai ◽  
Guo Hua Tu ◽  
Hua Ming Wu

The dye-sensitized solar cell performances influenced by radiant intensity and illuminated area in concentrating photovoltaic system are investigated experimentally and discussed theoretically. The results show that, under the same irradiated cells area, the short-circuit current is linearly increasing with the radiant intensity and the open-circuit voltage follows a logarithmic function of the radiant intensity. And, it is turned out that the short-circuit current and open-circuit voltage are obviously enhanced by increasing the illuminated cells surface area at the same radiant intensity. However, that growth trends will decline with an increase of the illuminated area. The reason is more defects involved in the process of increasing illumination area. All results can be interpreted using an equivalent circuit of a single diode model. A good agreement can be observed from the fitting curves. It is of great significance for current photovoltaic research.


2014 ◽  
Vol 1008-1009 ◽  
pp. 73-77
Author(s):  
Nair Gomesh ◽  
Syafinar Ramli ◽  
M. Irwanto ◽  
Y. M. Irwan ◽  
M. R. Mamat ◽  
...  

Dye-sensitized solar cell (DSSC) is part of the thin film family that consists of a TiO2 electrode coating which acts as a photo electrode, sensitizer from dye molecules soaked in the TiO2 film, electrolyte layer and a counter electrode. This paper focuses on the usage of a sensitizer from the rose flower and will review some of the research conducted on dye sensitizers from other researcher. Rose flower also known as woody perennial of the genus Rosa, within the family Rosaceae is extracted and were used as sensitizer to fabricate dye sensitized solar cell (DSSC). The photoelectrochemical performance of Rose sensitized solar cell shows parameter of open circuit voltage, VOC,short circuit current, (ISC), fill factor (FF), solar cell efficiency (η), and peak absorbance rate as much as 0.13 V, 57.58 µA, 0.58, 0.85% and 3.5 at 550nm respectively. The photoelectrochemical performance of DSSC and the usage of natural sensitizer from Rose flower dye demonstrate good potential to be applied as a sensitizer yet detail investigations are essential in terms of its applicability for long term application.


2018 ◽  
Vol 6 (6) ◽  
Author(s):  
Hafeez Yusuf Hafeez ◽  
Bala Ismail Adam

In this analytical approach we fabricate and characterized a Titanium Dioxide Dye sensitized solar cell using Doctor-Blade Technique. The samples were given annealing treatment at various time of 20, 30 and 40 minutes respectivelyat constant annealing temperature of 450oC. The device under test (DUT) were tested using a Kiethley 2400, source meter under A.M 1.5 (1000W/m2) illumination from a Newport class A solar simulator.The results shows that at the miscellaneous annealing time, the open circuit voltagesVoc= 0.28V, 0.30V and 0.29V, the short circuit current density Jsc=95.5µAcm-2 , 104.1µAcm-2and 105µAcm-2, the fill factor FF= 0.411, 0.448 and 0.525 and the energy conversion efficiency, η = 0.011, 0.014 and 0.016 respectively.With best results of open circuit voltage Voc=0.30, short circuit current density Jsc= 105mAcm-2, fill factor FF= 0.525 and energy conversion efficiency η= 0.016 was achieved.It was observed that the power density, Fill Factor and efficiency increases with increasewith increase in annealing time.


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