Single-Crystal Thin Films of SrFeO2 and LaNiO2 with Infinite-Layer Structures
Keyword(s):
AbstractInfinite-layer-structure epitaxial thin films of SrFeO2 and LaNiO2 respectively were prepared by low-temperature reduction with CaH2 from brownmillerite SrFeO2.5 and perovskite LaNiO3 epitaxial thin films grown on single-crystal substrates. The reduction process, removing oxygen ions from the perovskite-structure framework and causing rearrangements of oxygen ions, topotactically transforms the initial compounds to the c-axis oriented infinite-layer-structure epitaxial thin films. Consequently, the oxidation state of transition-metal ions in the film changed in wide ranges.
2010 ◽
Vol 46
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pp. 345-348
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2011 ◽
Vol 151
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pp. 943-946
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2012 ◽
Vol 184
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pp. 547-550
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1992 ◽
Vol 196
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pp. 14-16
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