A New Organic Crystal---MHBA for Potential Diode Laser Second-Harmonic Generation

1992 ◽  
Vol 247 ◽  
Author(s):  
Minhua Jiang ◽  
Xutang Tao ◽  
Duorong Yuan ◽  
Nan Zhang ◽  
Zongshu Shao
Keyword(s):  
Crystal Structure ◽  
Optical Properties ◽  
Nonlinear Optical ◽  
Second Harmonic ◽  
Single Crystal Growth ◽  
Organic Crystal ◽  
Unit Cell Parameters ◽  
Monoclinic System ◽  
Cell Parameters ◽  
Linear And Nonlinear

ABSTRACTThis paper reports a potential new organic crystal materials MHBA whose cut-off wavelength is 370nm and powder SHG intensity is 30 times higher than that of Urea. The crystal structure, single crystal growth, linear and nonlinear optical properties of MHBA are reported in detail. MHBA crystal belongs to monoclinic system; space group is P21, and the unit cell parameters are: a=14.057Å, b=7.875Å, c=15.037Å and β=115.45°. The nonlinear susceptibilities are: d11=25.0d36KDP, d12=10d36KDP, d13=33.3d36KDP and d14=8.3d36KDP.

Crystal structure of new phosphates Ca9–xPbxEu(PO4)7 from Rietveld refinement

2015 ◽  
Vol 30 (S1) ◽  
pp. S101-S103 ◽  
Author(s):  
Dina Deyneko ◽  
Sergey Stefanovich ◽  
Bogdan Lazoryak
Keyword(s):  
Crystal Structure ◽  
Solid State ◽  
Harmonic Generation ◽  
Nonlinear Optical ◽  
Second Harmonic ◽  
Rietveld Method ◽  
Polar Space ◽  
Unit Cell Parameters ◽  
Cell Parameters ◽  
Air Atmosphere

New phosphates Ca9–xPbxEu(PO4)7 were obtained by solid state reaction techniques at 1213–1253 K in air atmosphere and were found to be isotypic with whitlockite-type β-Ca3(PO4)2. The unit cell parameters were determinate using Le Bail decomposition. Rietveld method structural refining showed that Eu3+ ions are located statistically with calcium in M1, M2, and M3 sites, whereas Pb2+-ions are preferentially located in the M3. Examination of optical second harmonic generation evidences nonlinear optical activity and confirms polar space group R3c.

scholarly journals Synthesis and Characterization of NLO Material L-Valine L-Valinium Perchlorate Monohydrate for Photonics Applications

2020 ◽  
Vol 12 (3) ◽  
pp. 76
Author(s):  
Paranthaman Vasudevan ◽  
Devaraj Jayaraman
Keyword(s):  
Crystal Structure ◽  
Optical Properties ◽  
Single Crystals ◽  
Nonlinear Optical ◽  
Grown Crystal ◽  
Vickers Microhardness ◽  
Second Harmonic ◽  
Spectroscopic Studies ◽  
Nonlinear Optical Material

L-valine L-valinium perchlorate monohydrate single crystal has been synthesized by slow evaporation technique at room temperature. The crystal structure and space group of the crystal were confirmed by single crystal X-ray diffractometer. Optical behavior of the crystal was analyzed by using UV-visible spectrophotometer. Thermal stability was discussed by using thermo gravimetric analysis. Mechanical strength of the grown crystal was studied using Vickers microhardness tester. Nonlinear optical property was explored to confirm the second harmonic generation efficiency of the grown crystal. These preliminary investigations suggest that the title compound can serve as a potential material for photonics applications. Full Text: PDF ReferencesD. J. Williams, "Nonlinear Optical Properties of Organic and Polymer Materials" (ACS Symposium series 233, American Chemical Society, Washington, DC, 1983). CrossRef K. Bouchouit, Z. Sofiani, B. Derkowska, S. Abed, N. Benali-cherif, M. Bakasse and B. Sahraoui, "Investigation of crystal structure and nonlinear optical properties of 2-methoxyanilinium nitrate", Opt. Commun. 278, 180 (2007), CrossRef K. Bouchouit, H. Bougharraf, B. Derkowska-zielinska, N. Benali-cherif and B. Sahraoui, "Reversible phase transition in semi-organic compound p-Nitroanilinium sulfate detected using second harmonic generation as a tool", Opt.Mater. 48, 215 (2015), CrossRef J. H. Joshi, S. Kalainathan, M. J. Joshi and K. D. Parikh, "Crystal growth, spectroscopic, second and third order nonlinear optical spectroscopic studies of L-phenylalanine doped ammonium dihydrogen phosphate single crystals", Arab. J. Chem. 13, 5018 (2020), CrossRef A. Vijayakumar, A. Ponnuvel and A. Sasikala, "Growth and characterization of α and β form of L-histidine dihydrochloride single crystals", Mater. Today 14, 338 (2019), CrossRef C. Usha, R. Sathakuamri, Lynnette Joseph, D.Sajan, R.Meenakshi, and A.Sinthiya, "Growth and combined experimental and quantum chemical study of glycyl-L-Valine crystal", Heliyon 5, e01574 (2019), CrossRef P. Maadeshwaran and J. Chandrasekaran, "Synthesis, growth and characterization of l-valine cadmium chloride monohydrate—A novel semiorganic nonlinear optical crystal", Optik 122, 1128 (2011) CrossRef S. Pandiyaran, M. Umadevi, R. K. Rajaraman and V. K. Ramakrishnan, "Infrared and Raman spectroscopic studies of l-valine l-valinium perchlorate monohydrate", Spectrochim. Act A Mol. 62, 630 (2005) CrossRef S. Pandiarajan, B. Sridhar and R. K. Rajaram, "L-Valine L-valinium perchlorate monohydrate", Acta Crystallogr. E, 57, 0466 (2001) CrossRef M. Lydia Caroline and S. Vasudevan, "Growth and characterization of l-phenylalanine nitric acid, a new organic nonlinear optical material", Mater. Lett. 63, 41 (2009) CrossRef J. Tauc, R. Grigorovici and A. Vancu, "Optical Properties and Electronic Structure of Amorphous Germanium", Phy. Solid. Stat. 15, 627 (1966), CrossRef J. Tauc, A. Menth and D.L. Wood, "Optical and Magnetic Investigations of the Localized States in Semiconducting Glasses", Phys. Rev. Lett. 25, 749 (1970) CrossRef B. Thirumalaiselvam, R. Kanagadurai, D. Jayaraman and V. Natarajan, "Growth and characterization of 4-methyl benzene sulfonamide single crystals", Opt.Mater. 37, 74 (2014) CrossRef J. Bowman and M. Bevis, "The evaluation of the structure and hardness of processed plastics by the Vickers microhardness test", Colloid Polym. Sci. 255, 954 (1977) CrossRef S. K. Kurtz and T. T. Perry, "A Powder Technique for the Evaluation of Nonlinear Optical Materials", J. Appl. Phy. 39, 3798 (1968) CrossRef M. Prakash, D. Geetha and M. Lydia Caroline, "Crystal growth, structural, optical, spectral and thermal studies of tris(l-phenylalanine)l-phenylalaninium nitrate: A new organic nonlinear optical material", Spectrochim. Act A Mol. 81, 48 (2011) CrossRef

scholarly journals Crystal structure of gluconate 5-dehydrogenase from Lentibacter algarum

2020 ◽  
Vol 76 (5) ◽  
pp. 228-234
Author(s):  
Dengke Tian ◽  
Xueqi Fu ◽  
Wenqiang Cao ◽  
Hong Yuan
Keyword(s):  
Crystal Structure ◽  
Escherichia Coli ◽  
Structural Similarity ◽  
Unit Cell ◽  
Unit Cell Parameters ◽  
Monoclinic System ◽  
Space Group ◽  
Cell Parameters ◽  
High Structural Similarity

Gluconate 5-dehydrogenase (Ga5DH; EC 1.1.1.69) from Lentibacter algarum (LaGa5DH) was recombinantly expressed in Escherichia coli and purified to homogeneity. The protein was crystallized and the crystal structure was solved at 2.1 Å resolution. The crystal belonged to the monoclinic system, with space group P1 and unit-cell parameters a = 55.42, b = 55.48, c = 79.16 Å, α = 100.51, β = 105.66, γ = 97.99°. The structure revealed LaGaDH to be a tetramer, with each subunit consisting of six α-helices and three antiparallel β-hairpins. LaGa5DH has high structural similarity to other Ga5DH proteins, demonstrating that this enzyme is highly conserved.

Synthesis, Crystal Structure, Luminescence, and Nonlinear Optical Properties of 2-[(E)-[[4-[2-(4-Methoxyphenyl)ethynyl]phenyl] imino]methyl]-4- [(E)-phenyldiazenyl]phenol

2020 ◽  
Vol 17 (8) ◽  
pp. 618-623
Author(s):  
Sagar Subhash Mohite ◽  
Aditya Babasaheb Patil-Deshmukh ◽  
Sanjay Shamrao Chavan
Keyword(s):  
Crystal Structure ◽  
Optical Properties ◽  
Nonlinear Optical ◽  
Room Temperature ◽  
Second Harmonic ◽  
Monoclinic Structure ◽  
Single Crystal Diffraction ◽  
X Ray ◽  
Shg Efficiency ◽  
Room Temperature Luminescence

2-((E)-((4-((4-methoxyphenyl)ethynyl)phenyl)imino)methyl-4-((E)phenyldiazenyl)phenol (1) have been synthesized and characterized. X-ray single crystal diffraction study of the compound 1 reveal a monoclinic structure. Room temperature luminescence is observed for 1 in CH2Cl2 solution due to π* → π transition. The SHG efficiency by Kurtz powder technique indicating the compound 1 displayed the second harmonic generation (SHG) property.

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