Uv Absorption Spectra and Photolysis of Some Group II and Group VI Alkyls

1983 ◽  
Vol 29 ◽  
Author(s):  
S. J. C. Irvine ◽  
J. B. Mullin ◽  
D. J. Robbins ◽  
J. L. Glasper

ABSTRACTA preliminary study has been made of the UV photolysis of metal-organic compounds of Hg, Cd and Te which could be used for low-temperature, selective-area deposition of cadmium mercury telluride (CMT). High-resolution UV absorption spectra have been measured for dimethylcadmium (CdMe2), dimethylmercury (HgMe2) and diethyltelluride (TeEt2). Possible modes for photodissociation are discussed in the light of these results. The photodissociation of these alkyls was attempted in a hydrogen stream at atmospheric pressure using a mercury-xenon lamp, deposition being being onto a silica reaction tube. Yields of Cd, Hg and Te were measured under different deposition conditions to determine the dependence on UV intensity, alkyl concentration and flow velocity.

1985 ◽  
Vol 132 (4) ◽  
pp. 968-972 ◽  
Author(s):  
S. J. C. Irvine ◽  
J. B. Mullin ◽  
D. J. Robbins ◽  
J. L. Glasper

Author(s):  
Branislav Milovanović ◽  
Jurica Novak ◽  
Mihajlo Etinski ◽  
Wolfgang Domcke ◽  
Nadja Doslic

Despite many studies, the mechanisms of nonradiative relaxation of uracil in the gas phase and in aqueous solution are still not fully resolved. Here we combine theoretical UV absorption spectroscopy...


1969 ◽  
Vol 23 ◽  
pp. 2127-2135 ◽  
Author(s):  
Bengt Nelander ◽  
G. Hagen ◽  
Seija Vesala ◽  
Tarja Aalto ◽  
Per-Erik Werner ◽  
...  

Weed Science ◽  
1976 ◽  
Vol 24 (1) ◽  
pp. 107-114 ◽  
Author(s):  
V. E. Berkheiser ◽  
J. L. Ahlrichs

Ultraviolet (UV) absorption spectra were recorded of chloramben (3-amino-2,5-dichlorobenzoic acid) and selected relatives in solutions of different pH's. From these spectra, the Broensted acid-base properties of chloramben were deduced. Interpretations of solution spectra were applied to UV absorption spectra of chloramben adsorbed onto Ca-montmorillonite at low water content. Infrared (IR) transmittance spectra were recorded of chloramben and selected derivatives in KBr pellets and band assignments were made. Interpretations of these spectra were also applied to IR spectra of chloramben adsorbed onto Ca-montmorillonite at low water content. Both UV and IR measurements indicated that protonation of the amino group occurs and that the carboxyl group of chloramben is strongly hydrogen-bonded to the hydration water of the interlayer cations.


1983 ◽  
Vol 78 (9) ◽  
pp. 5351-5357 ◽  
Author(s):  
H. Hippler ◽  
J. Troe ◽  
H. J. Wendelken

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