Dry Composite Polymer Electrolytes for Lithium Batteries

1997 ◽  
Vol 496 ◽  
Author(s):  
G. B. Appetecchi ◽  
F. Croce ◽  
G. Dautzenberg ◽  
B. Scrosati
Keyword(s):  
Lithium Batteries ◽  
Polymer Electrolytes ◽  
High Stability ◽  
Metal Electrode ◽  
Unique Property ◽  
Lithium Metal ◽  
Composite Polymer ◽  
Composite Electrolyte ◽  
Composite Polymer Electrolytes

AbstractThe synthesis, characteristics and properties of a PEO-based, dry composite electrolyte are presented and discussed. The major feature of this electrolyte is the high stability towards the lithium metal electrode. This unique property makes the electrolyte quite promising for the development of rechargeable polymer lithium batteries.

scholarly journals Excellent Performances of Composite Polymer Electrolytes with Porous Vinyl-Functionalized SiO2 Nanoparticles for Lithium Metal Batteries

Polymers ◽  
2021 ◽  
Vol 13 (15) ◽  
pp. 2468
Author(s):  
Hui Zhan ◽  
Mengjun Wu ◽  
Rui Wang ◽  
Shuohao Wu ◽  
Hao Li ◽  
...  
Keyword(s):  
Polymer Electrolytes ◽  
Specific Capacity ◽  
Sio2 Nanoparticles ◽  
Inorganic Materials ◽  
Solid Polymer Electrolytes ◽  
Lithium Metal ◽  
Composite Polymer ◽  
Composite Electrolyte ◽  
Composite Polymer Electrolytes ◽  
Lithium Metal Batteries

Composite polymer electrolytes (CPEs) incorporate the advantages of solid polymer electrolytes (SPEs) and inorganic solid electrolytes (ISEs), which have shown huge potential in the application of safe lithium-metal batteries (LMBs). Effectively avoiding the agglomeration of inorganic fillers in the polymer matrix during the organic–inorganic mixing process is very important for the properties of the composite electrolyte. Herein, a partial cross-linked PEO-based CPE was prepared by porous vinyl-functionalized silicon (p-V-SiO2) nanoparticles as fillers and poly (ethylene glycol diacrylate) (PEGDA) as cross-linkers. By combining the mechanical rigidity of ceramic fillers and the flexibility of PEO, the as-made electrolyte membranes had excellent mechanical properties. The big special surface area and pore volume of nanoparticles inhibited PEO recrystallization and promoted the dissolution of lithium salt. Chemical bonding improved the interfacial compatibility between organic and inorganic materials and facilitated the homogenization of lithium-ion flow. As a result, the symmetric Li|CPE|Li cells could operate stably over 450 h without a short circuit. All solid Li|LiFePO4 batteries were constructed with this composite electrolyte and showed excellent rate and cycling performances. The first discharge-specific capacity of the assembled battery was 155.1 mA h g−1, and the capacity retention was 91% after operating for 300 cycles at 0.5 C. These results demonstrated that the chemical grafting of porous inorganic materials and cross-linking polymerization can greatly improve the properties of CPEs.

Composite Polymer Electrolytes with Improved Lithium Metal Electrode Interfacial Properties: I. Elechtrochemical Properties of Dry PEO‐LiX Systems

1998 ◽  
Vol 145 (12) ◽  
pp. 4126-4132 ◽  
Author(s):  
G. B. Appetecchi ◽  
F. Croce ◽  
G. Dautzenberg ◽  
M. Mastragostino ◽  
F. Ronci ◽  
...  
Keyword(s):  
Polymer Electrolytes ◽  
Interfacial Properties ◽  
Metal Electrode ◽  
Lithium Metal ◽  
Composite Polymer ◽  
Composite Polymer Electrolytes

Composite Polymer Electrolytes Based on PVA/PAN for All-Solid-State Lithium Metal Batteries Operated at Room Temperature

2020 ◽  
Vol 3 (11) ◽  
pp. 11024-11035
Author(s):  
Hoai Khang Tran ◽  
Yi-Shiuan Wu ◽  
Wen-Chen Chien ◽  
She-huang Wu ◽  
Rajan Jose ◽  
...  
Keyword(s):  
Solid State ◽  
Polymer Electrolytes ◽  
Room Temperature ◽  
Lithium Metal ◽  
Composite Polymer ◽  
Composite Polymer Electrolytes ◽  
Lithium Metal Batteries
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