Formation Study of Nanocomposite Thin Films of Ferrite Dispersed in a Silica Matrix Prepared by sol-Gel Process

2003 ◽  
Vol 775 ◽  
Author(s):  
Nelcy D. S. Mohallem ◽  
Luciana M. Seara

AbstractMagnetic nanocomposite thin films formed by cobalt ferrite dispersed in silica matrix were prepared by sol-gel process using tetraethylorthosilicate (TEOS) as a precursor of silica, and metallic nitrates as precursors of the ferrite. The films were prepared with 5–50 wt. % ferrite contents and deposited on substrate using the dip-coating process. The films obtained were adherent, transparent, homogeneous and free of microcracks, with thickness between 30 and 500 nm. The films obtained presented crystalline CoFe2O4 phases dispersed in SiO2 amorphous matrix and saturation magnetization of approximately 9 emu/g considering the composite mass and 30 emu/g considering the ferrite mass.

2014 ◽  
Vol 597 ◽  
pp. 165-169
Author(s):  
Jie Hong Lei ◽  
Ri Dong Zhang

The porous sol-gel silica thin films were prepared on silicon substrate by the dip coating process. The surface roughness and microstructure of the film was measured by optical microscopy and AFM .Coating thickness and refractive index were measured by ellipsometry method. Influence of withdrawal speed and concentration of colloid was investigated for the thickness of silica. The relation of the thickness and withdrawal speed was fitted by the linear and power functions, and the results were analyzed and compared. It was found that the films with the same thickness prepared by different concentrations of colloid have different refractive indexes. The experimental results indicated that the thickness and refractive index of the film can be controlled by changing the withdrawal speed and colloid concentration.


2011 ◽  
Vol 1368 ◽  
Author(s):  
Helen R. C. S. Andrade ◽  
Luciana M. Seara ◽  
Nelcy D. S. Mohallem

ABSTRACTNanocomposites formed by ferrimagnetic and ferroelectric materials are multiferroic material in which magnetoelectric coupling occurs via piezoelectricity and magnetostriction phenomena. These nanocomposites have a variety of applications in tunable microwave devices using electric control of spin wave propagation or new magnetic memories in which the magnetic response is controlled by electric field.In this work, transparent and homogeneous thin films of barium titanate interleaved with cobalt ferrite were prepared by sol–gel method using dip-coating process. Films of pure barium titanate and cobalt ferrite were also prepared for comparison. The nanocomposite films were deposited onto clean quartz substrates, where a coating of each material was deposited interleaved, where the cobalt ferrite film formed the last layer. The films were dried in air after each dipping and heated at 900 oC for 1 hour to convert the amorphous films into crystalline ones. The samples were characterized by low angle X-ray diffraction (XRD), scanning electron microscopy (SEM) and atomic force microscopy (AFM) and UV-Vis spectroscopy.


2014 ◽  
Vol 10 (4) ◽  
pp. 869-878 ◽  
Author(s):  
Soaram Kim ◽  
Giwoong Nam ◽  
Hyunsik Yoon ◽  
Hyunggil Park ◽  
Hyonkwang Choi ◽  
...  

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