Amphiphilic Dye for Solid-State Dye-Sensitized Solar Cells

2004 ◽  
Vol 836 ◽  
Author(s):  
Lukas Schmidt-Mende ◽  
Shaik M. Zakeeruddin ◽  
Michael Grätzel

ABSTRACTWe report a solid-state dye-sensitized solar cell with a record efficiency of 4% under simulated sunlight (AM1.5global, 100mW/cm2). This was made possible by using a new amphiphilic dye with hydrophobic spacers in combination with spiro-OMeTAD. We attribute the significant improvement in the device performance to the self-assembly of the dye to form a compact layer on the TiO2 surface and to the hydrophobic chains working as blocking layer between spiro-OMeTAD and TiO2 to reduce the back electron transfer. In addition, we studied the influence of nanoporous TiO2 film thickness on the performance of the device. These results demonstrate the high potential for solid state dye sensitized solar cells to compete with amorphous silicon cells as low cost alternative.

Nanomaterials ◽  
2020 ◽  
Vol 10 (11) ◽  
pp. 2217
Author(s):  
Zhi Zeng ◽  
Dongbo Wang ◽  
Jinzhong Wang ◽  
Shujie Jiao ◽  
Yuewu Huang ◽  
...  

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2009 ◽  
Vol 54 (4) ◽  
pp. 1319-1324 ◽  
Author(s):  
Hua Yu ◽  
Shanqing Zhang ◽  
Huijun Zhao ◽  
Geoffrey Will ◽  
Porun Liu

2008 ◽  
Vol 80 (11) ◽  
pp. 2241-2258 ◽  
Author(s):  
Jihuai Wu ◽  
Zhang Lan ◽  
Sanchun Hao ◽  
Pingjiang Li ◽  
Jianming Lin ◽  
...  

Dye-sensitized solar cells (DSSCs) have aroused intense interest over the past decade owing to their low cost and simple preparation procedures. Much effort has been devoted to the study of electrolytes that enable light-to-electrical power conversion for DSSC applications. This review focuses on recent progress in the field of liquid, solid-state, and quasi-solid-state electrolytes for DSSCs. It is believed that quasi-solid-state electrolytes, especially those utilizing thermosetting gels, are particularly applicable for fabricating high photoelectric performance and long-term stability of DSSCs in practical applications.


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