scholarly journals Evaluation of the low corrosion resistant phase formed during the sigma phase precipitation in duplex stainless steels

1999 ◽  
Vol 2 (4) ◽  
pp. 239-247 ◽  
Author(s):  
Darlene Yuko Kobayashi ◽  
Stephan Wolynec
2018 ◽  
Vol 1 (91) ◽  
pp. 23-30
Author(s):  
R.N. Penha ◽  
L.B. Silva ◽  
C.S.P. Mendonça ◽  
T.C. Moreira ◽  
M.L.N.M. Melo

Purpose: SAF 2205 duplex stainless steels (DSSs) are materials characterized by a favourable combination of the properties of ferritic and austenitic stainless steels. This type of stainless steel presents good weldability, corrosion resistance especially for stress corrosion cracking (SCC). However, this steel presents an unavoidable disadvantage that is its potential microstructural instability. Although duplex stainless steels design idea is to present two main types of microstructure, other phases and carbides or nitrides can precipitate. In the case of DSS SAF 2205, in addition to austenitic and ferritic microstructure, during heat treatment processing, welding or use may occur precipitation of undesirable intermetallic phases such as chi, Widmanstätten austenite, sigma besides carbides and nitrides. The precipitation of s-phase is associated with effects that cause both reduction of toughness and decreases the corrosion resistance on austenitic, ferritic and duplex stainless steels. Design/methodology/approach: This study evaluated the aging treatment effect on hardness, impact toughness and ferrite content of a SAF 2205 duplex stainless steel. Samples were solubilized at 1150°C, quenched in water and aged at 850°C during 1, 5, 10, 30, 60 or 180 minutes. After aging, cooling was to room temperature in air. Findings: Aging time promoted s-phase precipitation and hardness increase. Hardness and ferrite volume measurements, microscopy and the prediction of sigma phase bases the discussion. Impact toughness decreased with time aging and intermetallic phase precipitation. Research limitations/implications: As future work could be performed some corrosion test, vary the cooling rate after aging, and using other techniques to identify phases. Focus the research at lower aging times to try the describe Cr partitioning process to form sigma phase. Practical implications: High aging time should be avoided for SAF 2205 DSS. Originality/value: Usually sigma-phase precipitation on DDS is correlated to welding process. This paper correlates it to aging heat treatment.


1996 ◽  
Vol 45 (2) ◽  
pp. 83-89 ◽  
Author(s):  
Shuji Hashizume ◽  
Kaoru Sato ◽  
Masaharu Honda ◽  
Katsumi Masamura ◽  
Jun-ichi Sakai ◽  
...  

2004 ◽  
Vol 95 (7) ◽  
pp. 631-638 ◽  
Author(s):  
Michael Pohl ◽  
Oliver Storz

2005 ◽  
Vol 502 ◽  
pp. 345-350
Author(s):  
Toshio Kuroda ◽  
Katsuyuki Nakade ◽  
Kenji Ikeuchi

The influence of microstructure concerning sigma phase on hydrogen behavior was investigated by means of internal friction analysis. After hydrogen charging, a sharp significant internal friction peak by hydrogen in austenite of as-received specimen was observed at 245K for a frequency of 1.5Hz. However, the peak height in the specimen precipitated significant sigma phase was substantially lower than in as-received specimen since hydrogen in austenite have a concentration lower by sigma phase precipitation. In addition, the broadening and scattering of the internal friction peak was clearly identified by interaction between hydrogen and sigma phase. It means that the two peaks associated with hydrogen in the both sigma phase and austenite were considered to be overlapped. Consequently, it was clearly confirmed that hydrogen entered in the sigma phase lattice and hydrogen was also trapped at sigma/austenite interfaces.


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