Calcium sulfoaluminate cement (CSA) was used to stabilize a type of marine soft soil in Dalian China. Unconfined compressive strength (UCS) of CSA-stabilized soil was tested and compared to ordinary Portland cement (OPC); meanwhile the influence of amounts of gypsum in CSA and cement contents in stabilized soils on the strength of stabilized soils were investigated. X-ray diffraction (XRD) tests were employed to detect generated hydration products, and scanning electron microscopy (SEM) was conducted to analyze microstructures of CSA-stabilized soils. The results showed that UCS of CSA-stabilized soils at 1, 3, and 28 d firstly increased and then decreased with contents of gypsum increasing from 0 to 40 wt.%, and CSA-stabilized soils exhibited the highest UCS when the content of gypsum equaled 25 wt.%. When the mixing amounts of OPC and CSA were the same, CSA-stabilized soils had a significantly higher early strength (1 and 3 d) than OPC. For CSA-stabilized soil with 0 wt.% gypsum, monosulfate (AFm) was detected as a major hydration product. As for CSA-stabilized soil with certain amounts of gypsum, the intensity of ettringite (Aft) was significantly higher than that in the sample hydrating without gypsum, but a tiny peak of AFm also could be detected in the sample with 15 wt.% gypsum at 28 d. Additionally, the intensity of AFt increased with the contents of gypsum increasing from 0 to 25 wt.%. When contents of gypsum increased from 25 to 40 wt.%, the intensity of AFt tended to decrease slightly, and residual gypsum could be detected in the sample with 40 wt.% gypsum at 28 d. In the microstructure of OPC-stabilized soils, hexagonal plate-shaped calcium hydroxide (CH) constituted skeleton structures, and clusters of hydrated calcium silicates (C-S-H) gel adhered to particles of soils. In the microstructure of CSA-stabilized soils, AFt constituted skeleton structures, and the crystalline sizes of ettringite increased with contents of gypsum increasing; meanwhile, clusters of the aluminum hydroxide (AH3) phase could be observed to adhere to particles of soils and strengthen the interaction.
Effects of Retarding Admixture, Superplasticizer and Supplementary Cementitious Material on the Rheology and Mechanical Properties of High Strength Calcium Sulfoaluminate Cement Paste