scholarly journals A simplified distillation-based sulfur speciation method for sulfidic soil materials

2021 ◽  
Vol 93 (1) ◽  
pp. 19-30
Author(s):  
Krister Dalhem ◽  
◽  
Stefan Mattbäck ◽  
Anton Boman ◽  
Peter Österholm ◽  
...  
Keyword(s):  
Limit Of Detection ◽  
Reaction Times ◽  
Coarse Grained ◽  
Acid Sulfate Soils ◽  
Iron Sulfides ◽  
Acid Sulfate ◽  
Pyrite Content ◽  
Sulfur Speciation ◽  
Sulfate Soils ◽  
Coarse Grained Soil

Speciation of inorganic sulfur species, mainly pyrite and metastable iron sulfides by operationally defined methods, is widely used for risk assessment of acid sulfate soils by quantifying the acidity producing elements, as well as for general characterisation of marine sediments and subaqueous soils. “Traditional” sulfur speciation methods commonly use highly specialised glassware which can be cumbersome for the operator, or, require long reaction times which limit the usability of the method. We present a simplified method which has a sufficiently low limit of detection (0.002%) and quantitation (0.006%) required for the analysis of sulfidic sulfur in acid sulfate soil materials. Commercially available sulfide reagents were used for determining reproducibility and the method was assessed on natural sulfidic soil materials, including fine to coarse grained soil materials as well as sulfide bearing peat, with a large variation of metastable sulfide and pyrite content.

Characteristics of the Acidity in Acid Sulfate Soil Drainage Waters, McLeods Creek, Northeastern NSW, Australia

2006 ◽  
Vol 3 (3) ◽  
pp. 225 ◽  
Author(s):  
Rosalind Green ◽  
T. David Waite ◽  
Michael D. Melville ◽  
Ben C. T. Macdonald
Keyword(s):  
Oxidation Products ◽  
Metal Species ◽  
Acid Sulfate Soils ◽  
Iron Sulfides ◽  
Dissolved Metals ◽  
Species Determination ◽  
Acid Sulfate ◽  
Direct Titration ◽  
Sulfate Soils ◽  
Drainage Waters

Environmental Context. Acid sulfate soils are found in many low-lying coastal areas, but they can also be encountered in inland areas of Australia and other parts of the world. These soils typically contain iron sulfides, primarily pyrite (FeS2) and mackinawite (FeS), and the products that result from oxidation of these iron minerals. Acidic and metal-rich waters can be produced when the pyrite in soil is oxidized by natural means or accelerated when the soil is drained, which typically occurs when it is developed for agriculture or urban use. In general, acid sulfate soils become a problem when oxidation products are transported from the soil profile into nearby streams and estuaries, which can severely affect the ecology, biodiversity, economic development, and the aesthetics of adjacent waterways. The key contributors to acidity in drainage waters from the site examined are Al3+, AlSO4– and, under particular circumstances, Mn2+ and Fe2+, but the principal species contributing to acidity are strongly time variant and would be expected to vary from site to site. Abstract. Catchments that contain acid sulfate soils can discharge large quantities of acid and dissolved metals into waterways. At McLeods Creek in far northern NSW, Australia, the acidity from the hydrolysis of dissolved metal species, particularly aluminium and iron, contributes to greater than 70% of the total acidity. Therefore, a poor relationship exists between both calculated and titrated acidity and pH because of the dominant influence of these hydrolyzable metal species. Determination of the so-called ‘cold acidity’ by direct titration with NaOH yields results that are difficult to replicate because of the buffering effects of suspended solids, carbon dioxide ingassing, and/or MnII and FeII oxidation in the sample as the titration end-point is approached. Samples that are pre-treated with sulfuric acid and hydrogen peroxide produce results (of ‘hot acidity’) that can be easily replicated and are similar to calculated acidities based on elemental analysis and speciation calculations. The cold acidity values for titrations of 105 water samples from the chosen field site are often higher than hot acidity values as a result of the loss of carbonate acidity during pre-treatment of samples for hot acidity analysis.

PEUBAH KUALITAS AIR YANG MEMPENGARUHI PERTUMBUHAN RUMPUT LAUT (Gracilaria verrucosa) DI TAMBAK TANAH SULFAT MASAM KECAMATAN ANGKONA KABUPATEN LUWU TIMUR PROVINSI SULAWESI SELATAN

2009 ◽  
Vol 4 (1) ◽  
pp. 125
Author(s):  
Akhmad Mustafa ◽  
Rachmansyah Rachmansyah ◽  
Dody Dharmawan Trijuno ◽  
Ruslaini Ruslaini
Keyword(s):  
Water Quality ◽  
Growth Rate ◽  
Ammonium Phosphate ◽  
Gracilaria Verrucosa ◽  
Acid Sulfate Soils ◽  
Acid Sulfate Soil ◽  
Acid Sulfate ◽  
Independent Variables ◽  
Water Quality Variables ◽  
Sulfate Soils

Rumput laut (Gracilaria verrucosa) telah dibudidayakan di tambak tanah sulfat masam dengan kualitas dan kuantitas produksi yang relatif tinggi. Oleh karena itu, dilakukan penelitian yang bertujuan untuk mengetahui peubah kualitas air yang mempengaruhi laju pertumbuhan rumput laut di tambak tanah sulfat masam Kecamatan Angkona Kabupaten Luwu Timur Provinsi Sulawesi Selatan. Pemeliharaan rumput laut dilakukan di 30 petak tambak  terpilih selama 6 minggu. Bibit rumput laut dengan bobot 100 g basah ditebar dalam hapa berukuran 1,0 m x 1,0 m x 1,2 m. Peubah tidak bebas yang diamati adalah laju pertumbuhan relatif, sedangkan peubah bebas adalah peubah kualitas air yang meliputi: intensitas cahaya, salinitas, suhu, pH, karbondioksida, nitrat, amonium, fosfat, dan besi. Analisis regresi berganda digunakan untuk menentukan peubah bebas yang dapat digunakan untuk memprediksi peubah tidak bebas. Hasil penelitian menunjukkan bahwa laju pertumbuhan relatif rumput laut di tambak tanah sulfat masam berkisar antara 1,52% dan 3,63%/hari dengan rata-rata 2,88% ± 0,56%/hari. Di antara 9 peubah kualitas air yang diamati ternyata hanya 5 peubah kualitas air yaitu: nitrat, salinitas, amonium, besi, dan fosfat yang mempengaruhi pertumbuhan rumput laut secara nyata. Untuk meningkatkan pertumbuhan rumput laut di tambak tanah sulfat masam Kecamatan Angkona Kabupaten Luwu Timur dapat dilakukan dengan pemberian pupuk yang mengandung nitrogen untuk meningkatkan kandungan amonium dan nitrat serta pemberian pupuk yang mengandung fosfor untuk meningkatkan kandungan fosfat sampai pada nilai tertentu, melakukan remediasi untuk menurunkan kandungan besi serta memelihara rumput laut pada salinitas air yang lebih tinggi, tetapi tidak melebihi 30 ppt.Seaweed (Gracilaria verrucosa) has been cultivated in acid sulfate soil-affected ponds with relatively high quality and quantity of seaweed production. A research has been conducted to study water quality variables that influence the growth of seaweed in acid sulfate soil-affected ponds of Angkona Sub-district East Luwu Regency South Sulawesi Province. Cultivation of seaweed was done for six weeks in 30 selected brackishwater ponds. Seeds of seaweed with weight of 100 g were stocked in hapa sized 1.0 m x 1.0 m x 1.2 m. Dependent variable that was observed was specific growth rate, whereas independent variables were water quality variables including light intensity, salinity, temperature, pH, carbondioxide, nitrate, ammonium, phosphate, and iron. Analyses of multiple regressions were used to determine the independent variables which could be used to predict the dependent variable. Research result indicated that relative growth rate of seaweed in acid sulfate soils-affected brackishwater ponds ranged from 1.52% to 3.63%/day with 2.88% ± 0.56%/day in average. Among nine observed water quality variables, only five variables namely: nitrate, salinity, ammonium, phosphate and iron influence significantly on the growth of seaweed in acid sulfate soils-affected brackishwater ponds. The growth of seaweed in acid sulfate soils-affected brackishwater ponds of Angkona District East Luwu Regency, can be improved by using nitrogen-based fertilizers to increase ammonium and nitrate contents and also fertilizers which contain phosphorus to improve phosphate content to a certain level. Pond remediation to decrease iron content and also rearing seaweed at higher salinity (but less than 30 ppt) can also be alternatives to increase the growth of seaweed.

scholarly journals Bacillus Cyclic Lipopeptides Iturin and Fengycin Control Rice Blast Caused by Pyricularia oryzae in Potting and Acid Sulfate Soils by Direct Antagonism and Induced Systemic Resistance

2021 ◽  
Vol 9 (7) ◽  
pp. 1441
Author(s):  
Van Bach Lam ◽  
Thibault Meyer ◽  
Anthony Arguelles Arias ◽  
Marc Ongena ◽  
Feyisara Eyiwumi Oni ◽  
...  
Keyword(s):  
Rice Blast ◽  
Induced Systemic Resistance ◽  
Pyricularia Oryzae ◽  
Blast Disease ◽  
Systemic Resistance ◽  
Acid Sulfate Soils ◽  
Acid Sulfate ◽  
Wide Range ◽  
Bacillus Spp ◽  
Sulfate Soils

Rice monoculture in acid sulfate soils (ASSs) is affected by a wide range of abiotic and biotic constraints, including rice blast caused by Pyricularia oryzae. To progress towards a more sustainable agriculture, our research aimed to screen the biocontrol potential of indigenous Bacillus spp. against blast disease by triggering induced systemic resistance (ISR) via root application and direct antagonism. Strains belonging to the B. altitudinis and B. velezensis group could protect rice against blast disease by ISR. UPLC–MS and marker gene replacement methods were used to detect cyclic lipopeptide (CLiP) production and construct CLiPs deficient mutants of B. velezensis, respectively. Here we show that the CLiPs fengycin and iturin are both needed to elicit ISR against rice blast in potting soil and ASS conditions. The CLiPs surfactin, iturin and fengycin completely suppressed P. oryzae spore germination resulting in disease severity reduction when co-applied on rice leaves. In vitro microscopic assays revealed that iturin and fengycin inhibited the mycelial growth of the fungus P. oryzae, while surfactin had no effect. The capacity of indigenous Bacillus spp. to reduce rice blast by direct and indirect antagonism in ASS conditions provides an opportunity to explore their usage for rice blast control in the field.

CARACTÉRISTIQUES DES SOLS SULFATÉS ACIDES DE LA SÉRIE DE L'ANSE EN MILIEU ESTUARIEN (QUÉBEC)

1988 ◽  
Vol 68 (3) ◽  
pp. 577-592
Author(s):  
C. R. DE KIMPE ◽  
M. R. LAVERDIERE ◽  
R. W. BARIL
Keyword(s):  
Key Words ◽  
Lower Limit ◽  
Marine Sediments ◽  
Acid Sulfate Soils ◽  
Acid Sulfate ◽  
Organic C ◽  
South Shore ◽  
Sulfate Soils ◽  
Sulfate Leaching ◽  
St Lawrence River

Acid sulfate soils were sampled according to the transect method in four bays along the south shore of the St. Lawrence river to determine their properties in their area of distribution. In each bay, six profiles of cultivated soils were sampled along a transect perpendicular to the river. One non-cultivated profile was also sampled at l'Isle-Verte. The lower limit of the B horizons, between 79 and 89 cm, suggested a homogeneous development of these soils across the area. Most profiles contained jarosite in the lower Bg and, sometimes, in the C horizons; this mineral was absent in the upper part of the profiles of soils that had been limed prior to cultivation. Total S content increased with depth, but only a few horizons had a content > 0.75% presumably because of sulfate leaching once the soils were drained. Organic C content in the de l'Anse soils decreased less rapidly with depth than in other gleysolic soils, because vegetation grew while sediments were being deposited. Key words: Acid sulfate soils, total S, recent marine sediments, jarosite

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