Carbon Dioxide Reforming of Methane over Zeolite-containing Catalysts

Reforming of methane by carbon dioxide (dry reforming of methane) has been studied over the series of the 5% Со-М/Al2O3+ zeolite catalysts. The effect of zeolite (type, module, and amount) added to support composition on performance of the Со-М/Al2O3 catalyst in dry reforming has been examined. It has been shown that syngas is a main product of dry reforming over the zeolite-containing catalysts. Also, some amount (up to 3%) of acetic acid is produced. The yield of syngas and acetic acid depends on nature and amount of zeolite and process conditions.

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Effect of a second metal (Co, Cu, Mn or Zr) on nickel catalysts derived from hydrotalcites for the carbon dioxide reforming of methane

RSC Advances ◽

10.1039/c6ra12335j ◽

2016 ◽

Vol 6 (74) ◽

pp. 70537-70546 ◽

Cited By ~ 16

Author(s):

Xiaopeng Yu ◽

Fubao Zhang ◽

Wei Chu

Keyword(s):

Carbon Dioxide ◽

Nickel Catalysts ◽

Dry Reforming ◽

Dry Reforming Of Methane ◽

Ni Catalyst ◽

Carbon Dioxide Reforming ◽

Enhanced Stability

NiCo and NiCu catalysts exhibited enhanced stability compared with a Ni catalyst for the dry reforming of methane. On the contrary, NiMn and NiZr catalysts decreased the reforming stability.

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Iron-Nickel Alloys for Carbon Dioxide Activation by Chemical Looping Dry Reforming of Methane

Energy Technology ◽

10.1002/ente.201500539 ◽

2016 ◽

Vol 4 (10) ◽

pp. 1147-1157 ◽

Cited By ~ 19

Author(s):

Amey More ◽

Saurabh Bhavsar ◽

Götz Veser

Keyword(s):

Carbon Dioxide ◽

Nickel Alloys ◽

Dry Reforming ◽

Dry Reforming Of Methane ◽

Chemical Looping ◽

Iron Nickel ◽

Carbon Dioxide Activation ◽

Iron Nickel Alloys

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Dry Reforming of Methane in DBD Plasma over Ni‐Based Catalysts: Influence of Process Conditions and Support on Performance and Durability

Energy Technology ◽

10.1002/ente.201801008 ◽

2019 ◽

Vol 7 (4) ◽

pp. 1801008 ◽

Cited By ~ 10

Author(s):

Debjyoti Ray ◽

Devadutta Nepak ◽

Sagar Janampelli ◽

Partha Goshal ◽

Ch. Subrahmanyam

Keyword(s):

Dry Reforming ◽

Dry Reforming Of Methane ◽

Process Conditions ◽

Dbd Plasma

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Efficient dry reforming of methane with carbon dioxide reaction on Ni@Y2O3 nanofibers anti-carbon deposition catalyst prepared by electrospinning-hydrothermal method

International Journal of Hydrogen Energy ◽

10.1016/j.ijhydene.2020.08.202 ◽

2020 ◽

Vol 45 (56) ◽

pp. 31494-31506

Author(s):

Yongshuai Xie ◽

Fengqiong Xie ◽

Lin Wang ◽

Ying Peng ◽

Dehua Ma ◽

...

Keyword(s):

Carbon Dioxide ◽

Hydrothermal Method ◽

Carbon Deposition ◽

Dry Reforming ◽

Dry Reforming Of Methane ◽

Carbon Dioxide Reaction

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Enhancing effects on the catalytic performance during the preparation of nickel supported lanthanum–alumina catalyst for the catalytic carbon dioxide dry reforming of methane

Reaction Kinetics Mechanisms and Catalysis ◽

10.1007/s11144-012-0484-7 ◽

2012 ◽

Vol 108 (1) ◽

pp. 161-171 ◽

Cited By ~ 4

Author(s):

Sang-Hoon Song ◽

Jung Eun Park ◽

Tae-Sun Chang ◽

Jeong-Kwon Suh

Keyword(s):

Carbon Dioxide ◽

Catalytic Performance ◽

Dry Reforming ◽

Dry Reforming Of Methane ◽

Alumina Catalyst

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Dry Reforming of Methane with Carbon Dioxide Using Pulsed DC Arc Plasma at Atmospheric Pressure

Plasma Chemistry and Plasma Processing ◽

10.1007/s11090-010-9217-8 ◽

2010 ◽

Vol 30 (2) ◽

pp. 257-266 ◽

Cited By ~ 35

Author(s):

B. H. Yan ◽

Q. Wang ◽

Y. Jin ◽

Y. Cheng

Keyword(s):

Carbon Dioxide ◽

Atmospheric Pressure ◽

Dry Reforming ◽

Dry Reforming Of Methane ◽

Arc Plasma ◽

Pulsed Dc ◽

Dc Arc

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Syngas production plus reducing carbon dioxide emission using dry reforming of methane: utilizing low-cost Ni-based catalysts

Oil & Gas Science and Technology – Revue d’IFP Energies nouvelles ◽

10.2516/ogst/2020016 ◽

2020 ◽

Vol 75 ◽

pp. 22 ◽

Cited By ~ 1

Author(s):

Saeid Abbasi ◽

Mohsen Abbasi ◽

Firouz Tabkhi ◽

Benyamin Akhlaghi

Keyword(s):

Carbon Dioxide ◽

Methane Conversion ◽

Low Cost ◽

Carbon Dioxide Emission ◽

Dry Reforming ◽

Dry Reforming Of Methane ◽

Hydrogen Yield ◽

Heterogeneous Model ◽

Syngas Production ◽

Steam Reformers

Applicability of using Dry Reforming of Methane (DRM) using low-cost Ni-based catalysts instead of Conventional Steam Reformers (CSR) to producing syngas simultaneously with reducing the emission of carbon dioxide was studied. In order to achieving this goal, a multi-tubular recuperative thermally coupled reactor which consists of two-concentric-tubes has been designed (Thermally Coupled Tri- and Dry Reformer [TCTDR]). By employing parameters of an industrial scale CSR, two proposed configuration (DRM with fired-furnace and Tri-Reforming of Methane (TRM) instead of fired-furnace (TCTDR)) was simulated. A mathematical heterogeneous model was used to simulate proposed reactors and analyses were carried out based on methane conversion, hydrogen yield and molar flow rate of syngas for each reactor. The results displayed methane conversion of DRM with fired-furnace was 35.29% and 31.44% for Ni–K/CeO2–Al2O3 and Ni/La2O3 catalysts, respectively, in comparison to 26.5% in CSR. Methane conversion in TCTDR reached to 16.98% by Ni/La2O3 catalyst and 88.05% by NiO–Mg/Ce–ZrO2/Al2O3 catalyst in TRM side. Also, it was 15.88% using Ni–K/CeO2–Al2O3 catalyst in the DRM side and 88.36% using NiO–Mg/Ce–ZrO2/Al2O3 catalyst in TRM side of TCTDR. Finally, the effect of different amounts of supplying energy on the performance of DRM with fired-furnace was studied, and positive results in reducing the energy consumption were observed.

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