scholarly journals The return of the dispersed metal waste into production

2019 ◽  
pp. 45-48
Author(s):  
S. L Rovin ◽  
A. S. Kalinichenko ◽  
L. E. Rovin
Keyword(s):  
Chemical Composition ◽  
Liquid Phase ◽  
Mill Scale ◽  
Metal Waste ◽  
Organic Impurities ◽  
Processing Wastes ◽  
Cast Alloys ◽  
Preliminary Preparation ◽  
Solid Liquid ◽  
Phase Process

The article presents an alternative method of recycling of dispersed metal waste, based on a continuous solid-liquid-phase process, implemented in rotary tilting furnaces (RTF). The new proposed method of recycling allows processing wastes with almost any composition and state from metal to oxide and multicomponent wastes (shavings, fine scrap, mill scale, aspiration dust, sludge, etc.). The wastes can be even contaminated with moisture, oil, and organic impurities. The method developed does not require preliminary preparation of the initial materials (cleaning, homogenization, pelletizing, etc.). The finished products are ingots (pigs) for subsequent processing aiming the particular chemical composition or cast alloys of certain brend.

Multi-walled Carbon Nanotubes Reinforced into Hollow Fiber by Chitosan Sol-gel for Solid/Liquid Phase Microextraction of NSAIDs from Urine Prior to HPLC-DAD Analysis

2019 ◽  
Vol 20 (5) ◽  
pp. 390-400 ◽  
Author(s):  
Nabil N. AL-Hashimi ◽  
Amjad H. El-Sheikh ◽  
Rania F. Qawariq ◽  
Majed H. Shtaiwi ◽  
Rowan AlEjielat
Keyword(s):  
Carbon Nanotubes ◽  
Liquid Phase ◽  
Hollow Fiber ◽  
Sol Gel ◽  
Liquid Phase Microextraction ◽  
Extraction Device ◽  
Multi Walled Carbon Nanotubes ◽  
Solid Liquid ◽  
Walled Carbon Nanotubes

Background: The efficient analytical method for the analysis of nonsteroidal antiinflammatory drugs (NSAIDs) in a biological fluid is important for determining the toxicological aspects of such long-term used therapies. Methods: In the present work, multi-walled carbon nanotubes reinforced into a hollow fiber by chitosan sol-gel assisted-solid/ liquid phase microextraction (MWCNTs-HF-CA-SPME) method followed by the high-performance liquid chromatography-diode array detection (HPLC–DAD) was developed for the determination of three NSAIDs, ketoprofen, diclofenac, and ibuprofen in human urine samples. MWCNTs with various dimensions were characterized by various analytical techniques. The extraction device was prepared by immobilizing the MWCNTs in the pores of 2.5 cm microtube via chitosan sol-gel assisted technology while the lumen of the microtube was filled with few microliters of 1-octanol with two ends sealed. The extraction device was operated by direct immersion in the sample solution. Results: The main factors influencing the extraction efficiency of the selected NSAIDs have been examined. The method showed good linearity R2 ≥ 0.997 with RSDs from 1.1 to 12.3%. The limits of detection (LODs) were 2.633, 2.035 and 2.386 µg L-1, for ketoprofen, diclofenac, and ibuprofen, respectively. The developed method demonstrated a satisfactory result for the determination of selected drugs in patient urine samples and comparable results against reference methods. Conclusion: The method is simple, sensitive and can be considered as an alternative for clinical laboratory analysis of selected drugs.

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