Treatment of industrial wastewaters with ozone/hydrogen peroxide

1995 ◽  
Vol 32 (7) ◽  
pp. 127-134 ◽  
Author(s):  
H. Gulyas ◽  
R. von Bismarck ◽  
L. Hemmerling
Keyword(s):  
Hydrogen Peroxide ◽  
Humic Acid ◽  
Soil Remediation ◽  
Paper Mill ◽  
Chemical Oxidation ◽  
Paper Mill Effluent ◽  
Industrial Wastewaters ◽  
Laboratory Scale Reactor ◽  
Paper Mill Wastewater ◽  
Organic Wastewater

Treatment with ozone and ozone/hydrogen peroxide was tested in a laboratory scale reactor for removal of organics from four different industrial wastewaters: wastewaters of a paper-mill and of a biotechnical pharmaceutical process as well as two process waters from soil remediation by supercritical water extraction. Moreover, an aqueous solution of triethyleneglycoldimethylether and humic acid which was a model for a biologically treated oil reclaiming wastewater was also oxidized. The aim of the oxidation of the pharmaceutical wastewater was the removal of the preservative 1.1.1-trichloro-2-methyl-2-propanol (TCMP). Although TCMP could easily be removed from pure aqueous solutions by treatment with ozone/hydrogen peroxide, the oxidation of the wastewater failed to be effective in TCMP degradation because of competitive ozonation of other organic solutes in the wastewater. The ozonation of the paper-mill wastewater and of the soil remediation process waters decreased COD and TOC to some extent. The presence of organic wastewater solutes which contain C-C double bonds (ligninsulfonic acid in the treated paper-mill effluent and humic acid in the oil reclaiming model wastewater) were shown to yield hydrogen peroxide by the reaction with ozone. Therefore, these wastewaters are efficiently ozonated even without addition of hydrogen peroxide. Chemical Oxidation of paper-mill wastewater and of wastewaters resulting from soil remediation did not improve biological degradability of organic wastewater constituents.

The role of chemical oxidation in combined chemical-physical and biological processes: experiences of industrial wastewater treatment

2001 ◽  
Vol 44 (5) ◽  
pp. 109-116 ◽  
Author(s):  
G. Bertanza ◽  
C. Collivignarelli ◽  
R. Pedrazzani
Keyword(s):  
Hydrogen Peroxide ◽  
Unsaturated Polyester ◽  
Chemical Oxidation ◽  
Process Conditions ◽  
Biological Processes ◽  
Industrial Wastewaters ◽  
First Case ◽  
Textile Factory ◽  
Cost Determination

In this work, some experiences are described concerning the application of chemical oxidation in the treatment of industrial wastewaters in combination with other chemical-physical and/or biological processes. In the first case, two different wastewaters from saturated and unsaturated polyester resin production were considered. In a second case, optimal process conditions were assessed for the treatment of a wastewater deriving from polystyrene production. A third experience dealt with a comparison among different processes (flocculation, Fenton process, ozonisation, oxidation by means of ozone and hydrogen peroxide, oxidation by means of hydrogen peroxide and UV radiation), for the pretreatment of two industrial wastewaters (the first one being produced in a textile factory, the second one coming from detergent manufacturing). The evaluation of different processes was carried out by means of laboratory scale tests, considering treatment efficiency (organic substance removal, changes in wastewater biodegradability) and parameters (chemicals and energy consumption, sludge production) which play an important role in cost determination.

scholarly journals Purification of pulp and paper mill effluent through Typha and Canna using constructed wetlands technology

2011 ◽  
Vol 1 (4) ◽  
pp. 237-242 ◽  
Author(s):  
Neetu Rani ◽  
R. C. Maheshwari ◽  
Vivek Kumar ◽  
V. K. Vijay
Keyword(s):  
Wastewater Treatment ◽  
Constructed Wetlands ◽  
Constructed Wetland ◽  
Oxygen Demand ◽  
Paper Mill ◽  
Pulp And Paper ◽  
Pulp And Paper Mill ◽  
Wastewater Treatment Process ◽  
Paper Mill Effluent ◽  
Paper Mill Wastewater

The use of constructed wetlands (CW) to treat domestic as well as industrial wastewater is rapidly emerging as a viable alternative in India. Constructed wetland systems offer several potential advantages as a wastewater treatment process. These advantages include simple operation and maintenance and lower construction and operating costs. The study evaluated the effectiveness of the subsurface flow constructed wetland for pulp and paper mill wastewater treatment and also the effectiveness of plant species. A pilot scale study was conducted to examine the feasibility of a CW system for treatment of pulp and paper mill wastewater during summers as well as winters at different hydraulic retention time (HRT) such as 1.5 days, 3.5 days and 6.5 days. Wetland beds were prepared with easily available plants such as Typha angustifolia and Canna indica. Specific performance objectives were to decrease biochemical oxygen demand (BOD), chemical oxygen demand (COD), total solids (TS) and color. Comparison of mean inlet and outlet concentrations showed that the CW system could effectively reduce the output of TS (87.6 ± 1.1%), COD (86.6 ± 2.0%), BOD5 (80.01 ± 0.1%), color (89.4 ± 0.6%) during summer and TS (72.15 ± 0.71%), COD (70.94 ± 2.3%), BOD5 (72.07 ± 2.2%) and color (74.90 ± 0.47%) during winter at 3.5 days HRT.

Application of a Pilot-Scale Pulsed Electrocoagulation system to OCC-Based Paper Mill Effluent

TAPPI Journal ◽  
2009 ◽  
Vol 8 (3) ◽  
pp. 14-20 ◽  
Author(s):  
YUAN-SHING PERNG ◽  
EUGENE I-CHEN WANG ◽  
SHIH-TSUNG YU ◽  
AN-YI CHANG
Keyword(s):  
Water Quality ◽  
Quality Indicators ◽  
Paper Mill ◽  
Pilot Scale ◽  
Operating Conditions ◽  
Optimal Dosage ◽  
Water Quality Indicators ◽  
Paper Mill Effluent ◽  
Treated Effluent ◽  
True Color

Trends toward closure of white water recirculation loops in papermaking often lead to a need for system modifications. We conducted a pilot-scale study using pulsed electrocoagulation technology to treat the effluent of an old corrugated containerboard (OCC)-based paper mill in order to evaluate its treatment performance. The operating variables were a current density of 0–240 A/m2, a hydraulic retention time (HRT) of 8–16 min, and a coagulant (anionic polyacrylamide) dosage of 0–22 mg/L. Water quality indicators investigated were electrical con-ductivity, suspended solids (SS), chemical oxygen demand (COD), and true color. The results were encouraging. Under the operating conditions without coagulant addition, the highest removals for conductivity, SS, COD, and true color were 39.8%, 85.7%, 70.5%, and 97.1%, respectively (with an HRT of 16 min). The use of a coagulant enhanced the removal of both conductivity and COD. With an optimal dosage of 20 mg/L and a shortened HRT of 10 min, the highest removal achieved for the four water quality indicators were 37.7%, 88.7%, 74.2%, and 91.7%, respectively. The water qualities thus attained should be adequate to allow reuse of a substantial portion of the treated effluent as process water makeup in papermaking.

CHEMICAL OXIDATION OF TREATED TEXTILE EFFLUENT BY HYDROGEN PEROXIDE AND FENTON PROCESS

2010 ◽  
Vol 9 (3) ◽  
pp. 351-360 ◽  
Author(s):  
Abdelnaser Omran ◽  
Hamidi Abdul Aziz ◽  
Marniyanti Mamat Noor
Keyword(s):  
Hydrogen Peroxide ◽  
Chemical Oxidation ◽  
Textile Effluent ◽  
Fenton Process

TREATABILITY OF 2,4-D PRODUCTION WASTEWATERS

1994 ◽  
Vol 30 (3) ◽  
pp. 73-78 ◽  
Author(s):  
O. Tünay ◽  
S. Erden ◽  
D. Orhon ◽  
I. Kabdasli
Keyword(s):  
Hydrogen Peroxide ◽  
Activated Sludge ◽  
Partial Oxidation ◽  
Chloride Concentration ◽  
Chemical Oxidation ◽  
Cod Removal ◽  
Optimum Conditions ◽  
Organic Loading ◽  
Activated Sludge System ◽  
Biological Treatability

This study evaluates the characterization and treatability of 2,4-D production wastewaters. Wastewaters contain 20000-40000 mg/l COD, 17000-30000 mg/l chloride and pH is around 1.0. Chemical oxidation with hydrogen peroxide provided almost complete COD removal. The optimum conditions are 3:1 H2O2/COD oxidant dosage, 3000 mg/l Fe3+ as catalyst and pH 3. Partial oxidation at 0.5:1 H2O2//COD ratio is also effective providing 67% COD removal. A batch activated sludge system is used for biological treatability. Dilution is needed to maintain a tolerable chloride concentration which increases through COD removal. pH also increased during COD removal. 85% COD removal is obtained for the 50% dilution at an organic loading of 0.3 day‒1 on a COD basis. Completely and partially oxidized wastewaters are also treated in the activated sludge down to 30 mg/l BOD5.

Utilization of a small soda pulp and paper mill effluent for rice field irrigation

1997 ◽  
Vol 35 (2-3) ◽  
pp. 205-212 ◽  
Author(s):  
H. T. Adisesha ◽  
S. Purwati ◽  
P. R. Panggabean ◽  
S. E. Sarief
Keyword(s):  
Soil Analysis ◽  
Paper Mill ◽  
Exchange Capacity ◽  
Pulp And Paper ◽  
Rice Fields ◽  
Chemical Recovery ◽  
Pulp And Paper Mill ◽  
Paper Mill Effluent ◽  
Soda Pulp ◽  
Paddy Crop

Padalarang pulp and paper mill, a soda pulp and paper mill without chemical recovery, located near Bandung, Indonesia, discharges untreated effluent mixed with domestic waste water into surrounding rice fields. For more than 60 years, paddy has been harvested 3 times a year. An in-depth study to characterize the effluent, the soil and the biomass production was conducted to define the evidence. A field study using four experimental plots indicated that soil irrigated with effluent had a higher concentration of potassium, calcium, sodium ions and greater cation exchange capacity than near-by soil. Analysis of well water showed that the effluent had no effect on the ground water. A reduction of suspended solids and BOD occurred in the effluent while flowing through rice fields. The yields of paddy demonstrated significant positive effect of effluent either in dry or in rainy season, while zeolites as soil amendment did not give significant effect to the already high paddy crop yield.

Sign in / Sign up

Export Citation Format

Share Document