Solid Phase Regeneration of Carbonyl Compounds by Oxidative Cleavage of Carbon-Nitrogen Double Bonds with Molecular Oxygen at Room Temperature

2006 ◽  
Vol 3 (2) ◽  
pp. 121-122 ◽  
Author(s):  
Mohammed Hashemi ◽  
Maryam Akhbari ◽  
Zahed Karimi-Jaberi
Keyword(s):  
Molecular Oxygen ◽  
Carbonyl Compounds ◽  
Room Temperature ◽  
Solid Phase ◽  
Oxidative Cleavage ◽  
Double Bonds

scholarly journals Deoximation of Ketoximes to Ketones with Ammonium Chlorochromate/Montmorillonite K10 in Dichloromethane

2009 ◽  
Vol 6 (1) ◽  
pp. 156-160 ◽  
Author(s):  
Ji-Tai Li ◽  
Xian-Tao Meng
Keyword(s):  
Efficient Method ◽  
Carbonyl Compounds ◽  
Room Temperature ◽  
Oxidative Cleavage ◽  
Montmorillonite K10

A convenient, mild and efficient method for oxidative cleavage of ketoximes to their parent carbonyl compounds with ammonium chlorochromate (ACC) / montmorillonite K10 in dichloromethane at room temperature is described

2, 4-Ionene Supported Permanganate: A Novel, Efficient and Selective Solid Phase Oxidizing Agent for Oxidation of Organic Compounds

2011 ◽  
Vol 14 (2) ◽  
Author(s):  
Moslem Mansour Lakouraj ◽  
Sayed Maysam Hossaini ◽  
Vahid Hasantabar ◽  
Masoomeh Soleimani
Keyword(s):  
Aqueous Solution ◽  
Organic Compounds ◽  
Carbonyl Compounds ◽  
Room Temperature ◽  
Solid Phase ◽  
Oxidizing Agent ◽  
Solvent Free Conditions ◽  
Oxidation Of Organic Compounds ◽  
Different Types ◽  
Hydroxyl Compounds

Abstract2, 4-ionene supported permanganate is easily prepared by treatment of 2, 4-ionene with an aqueous solution of potassium permanganate. This reagent could be used as a stable, mild and efficient oxidizing agent to produce carbonyl compounds from hydroxyl compounds or arenes, and disulfides from thiols in either heterogonous or solvent free conditions. In addition, aromatization of different types of 2-arylimidazolines and 2-alkylimidazolines to corresponding imidazoles was achieved in good yields in acetonitrile at room temperature.

Radical Mediated Aerobic Oxidation of Substituted Styrenes and Stilbenes

2021 ◽  
Author(s):  
Hasil Aman ◽  
Wei-hua Chiu Chiu ◽  
Pin-Heng Liu ◽  
Gary Jing Chuang
Keyword(s):  
Molecular Oxygen ◽  
Carbonyl Compounds ◽  
Aerobic Oxidation ◽  
Oxidative Cleavage ◽  
Moderate Yield

A 2,2-azobis(isobutyronitrile) (AIBN) catalyzed oxidative cleavage of alkenes with molecular oxygen as the oxidant has been described. Carbonyl compounds and oxiranes were obtained as products in moderate yield under mild...

Efficient and selective copper-catalyzed organic solvent-free and biphasic oxidation of aromatic gem-disubstituted alkenes to carbonyl compounds by tert-butyl hydroperoxide at room temperature

2014 ◽  
Vol 16 (6) ◽  
pp. 3013-3017 ◽  
Author(s):  
Md. Munkir Hossain ◽  
Wei-Kai Huang ◽  
Hung-Jie Chen ◽  
Pei-Han Wang ◽  
Shin-Guang Shyu
Keyword(s):  
Organic Solvent ◽  
Carbonyl Compounds ◽  
Room Temperature ◽  
Oxidative Cleavage ◽  
Solvent Free ◽  
Butyl Hydroperoxide ◽  
Tert Butyl ◽  
Tert Butyl Hydroperoxide

Biphasic Cu(ii) catalyzed selective oxidative cleavage of aromatic gem-disubstituted alkenes to carbonyl compounds using tert-butyl hydroperoxide at room temperature.

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