scholarly journals The Temperature and Pressure Dependencies of Propagation Characteris-tics for Premixed Laminar Ethanol-Air Flames

2012 ◽  
Vol 6 (1) ◽  
pp. 55-64 ◽  
Author(s):  
S. Y. Liao ◽  
D. L. Zhong ◽  
C. Yang ◽  
X. B. Pan ◽  
C. Yuan ◽  
...  

Laminar burning velocity is strongly dependent on mixture characteristics, e.g. initial temperature, pressure and equivalence ratio. In this work, spherically expanding laminar premixed flames, freely propagating from a spark ignition source in initially quiescent ethanol-air mixtures, have been imaged and then the laminar burning velocities were obtained at initial temperatures of 358 K to 500K, pressure of 0.1 to 0.2 MPa and equivalence ratio of 0.7 to 1.4. The measured re-sults and literature data on ethanol laminar burning velocities were accumulated, to analyze the effects of initial tempera-ture and pressure on the propagation characteristics of laminar ethanol-air flames. A correlation in the form of ul=ulo(Tu/Tu0)αT (Pu/Pu0)βP , and validated over much wide temperature, pressure and equivalence ratio ranges. The global activation temperatures were determined in terms of the laminar burning mass flux for ethanol-air flames. And the Zel’dovich numbers were estimated as well. The dependencies of global activation temperature and Zel’dovich number on initial mixture pressure, temperature and equivalence ratio were explored. Additionally, an alterna-tive correlation of laminar burning velocities, from the view of theoretical arguments, was proposed on the basis of the de-termined ethanol-air laminar mass burning flux. Good agreements were obtained in its comparison with the literature data.

Fuel ◽  
2022 ◽  
Vol 310 ◽  
pp. 122149
Author(s):  
Ryuhei Kanoshima ◽  
Akihiro Hayakawa ◽  
Takahiro Kudo ◽  
Ekenechukwu C. Okafor ◽  
Sophie Colson ◽  
...  

Fuel ◽  
2022 ◽  
Vol 309 ◽  
pp. 122081
Author(s):  
Yu Liu ◽  
Wu Gu ◽  
Jinduo Wang ◽  
Hongan Ma ◽  
Nanhang Dong ◽  
...  

Author(s):  
Sebastian Verhelst ◽  
Roger Sierens

During the development of a quasi-dimensional simulation programme for the combustion of hydrogen in spark-ignition engines, the lack of a suitable laminar flame speed formula for hydrogen/air mixtures became apparent. A literature survey shows that none of the existing correlations covers the entire temperature, pressure and mixture composition range as encountered in spark-ignition engines. Moreover, there is ambiguity concerning the pressure dependence of the laminar burning velocity of hydrogen/air mixtures. Finally, no data exists on the influence of residual gases. This paper looks at several reaction mechanisms found in the literature for the kinetics of hydrogen/oxygen mixtures, after which one is selected that corresponds best with available experimental data. An extensive set of simulations with a one-dimensional chemical kinetics code is performed to calculate the laminar flame speed of hydrogen/air mixtures, in a wide range of mixture compositions and initial pressures and temperatures. The use of a chemical kinetics code permits the calculation of any desired set of conditions and enables the estimation of interactions, e.g. between pressure and temperature effects. Finally, a laminar burning velocity correlation is presented, valid for air-to-fuel equivalence ratios λ between 1 and 3 (fuel-to-air equivalence ratio 0.33 < φ < 1), initial pressures between 1 bar and 16 bar, initial temperatures between 300 K and 800 K and residual gas fractions up to 30 vol%. These conditions are sufficient to cover the entire operating range of hydrogen fuelled spark-ignition engines.


2018 ◽  
Vol 17 (2) ◽  
pp. 03
Author(s):  
L. Pizzuti ◽  
C. A. Martins ◽  
L. R. Santos

This paper presents a very detailed description of a new cylindrical constant volume combustion chamber designed for laminar burning velocity determination of gaseous mixtures at ambient temperature and initial pressure up to 6 bar. The experimental setup, the experimental procedure and the determination of the range of flame radius for laminar burning determination are all described in details. The laminar burning velocity of twelve synthetic biogas mixtures has been studied. Initial pressure varying between 1 and 5 bar, equivalence ratios, f, between 0.7 and 1.1 and percentage dilution, with a mixture of CO2 and N2, between 35 and 55% have been considered. Five experiments were run for each mixture providing a maximum percentage standard deviation of 8.11%. However, for two third of the mixtures this value is lower than 3.55%. A comparison with simulation using PREMIX for both GRI-Mech 3.0 and San Diego mechanisms has provided closer agreement for mixtures with equivalence ratio closer to stoichiometry whereas for f = 0.7 the deviation is larger than 15% for all pressures. Mixtures with lower equivalence ratio, higher dilution percentage and higher initial pressure presents the lower values of laminar burning velocity.


Author(s):  
B. B. Ale ◽  
I. Wierzba

The flammability limits of hydrogen and methane in air were determined experimentally at elevated initial mixture temperatures up to 350°C at atmospheric pressure for upward flame propagation in a conventional steel test tube apparatus. Additionally the extent to which a prolonged exposure (i.e., residence time) of the mixture to elevated temperatures before spark ignition and, consequently, the existence of pre-ignition reactions that may influence the value of the lean and rich flammability limits was also investigated. It was shown that the flammability limits for methane widened approximately linearly with an increase in the initial mixture temperature over the whole range of temperatures tested. These limits were not affected by the length of the residence time before spark ignition. Different behaviour was observed for flammability limits of hydrogen. They were also widened with an increase in the initial temperature but only up to 200°C. In this initial temperature range the limits were not affected by the length of the residence time. However, at initial temperature exceeding 200°C the flammability limits, especially, the rich limits narrowed with an increase in the temperature and were significantly affected by the residence time before spark ignition. The results of detailed chemical kinetic simulation showed that the gas phase reactions of hydrogen oxidation could not be responsible for the substantial drop in the value of the rich limit. It was therefore, suggested that this drop in the value of the rich limit with the increase in the residence time was caused by the relatively low temperature catalytic reactions on the stainless steel surface of the flame tube. Simple method for calculating the hydrogen conversion to water was proposed. The results of calculations are in fair agreement with the experimental evidence.


Author(s):  
Sebastian Verhelst ◽  
Roger Sierens ◽  
Stefaan Verstraeten

Hydrogen is an attractive alternative energy carrier, which could make harmful emissions, global warming and the insecurity concerning oil supply a thing of the past. Hydrogen internal combustion engines can be introduced relatively easily, from a technological as well as from an economic point of view. This paper discusses the development of a model for the combustion of hydrogen in spark ignition engines, which has lead to a simulation program that can assist the optimization of these engines. The importance of a laminar burning velocity correlation taking stretch and instability effects into account is shown. The effects are particularly strong for the highly diffusive hydrogen molecule. In this paper, a laminar burning velocity correlation published previously by two of the authors is combined with a number of turbulent burning velocity models in a quasi-dimensional two-zone combustion model framework. After calibration of the combustion model for a reference condition, simulation results are compared with experimental cylinder pressure data recorded on a single cylinder hydrogen engine. Correspondence between simulation and measurement is shown for varying equivalence ratio, ignition timing and compression ratio. All models performed well for varying ignition timings and compression ratios; the real test proved to be the ability of the models to predict the effects of a varying equivalence ratio, this lead to a clear distinction in the models.


Fuel ◽  
2020 ◽  
Vol 280 ◽  
pp. 118587
Author(s):  
J.L.S. Fagundez ◽  
R.L. Sari ◽  
A. Garcia ◽  
F.M. Pereira ◽  
M.E.S. Martins ◽  
...  

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