scholarly journals Studies of the Influence of Temperature on the Photocatalytic Activity of Tungsten Oxide

2022 ◽  
Author(s):  
N. Derbasova

Abstract. The results of photocatalytic activity of tungsten oxide in visible light are analyzed. It was shown that tungsten oxide has photocatalytic activity under the action of visible light in the photodegradation of the dye methylene blue. It was determined that the concentration of 15 mg/L provides the highest rate of photodecomposition of methylene blue. The optimum temperature for the process was determined. The process of methylene blue decomposition is most effective at 25 °С.

RSC Advances ◽  
2020 ◽  
Vol 10 (39) ◽  
pp. 23024-23037 ◽  
Author(s):  
Fengxia Zhang ◽  
Wenjing Li ◽  
Tianyi Jiang ◽  
Xuemei Li ◽  
Yuanyuan Shao ◽  
...  

Three novel visible-light-driven composite photocatalysts were synthesized by hydrothermal method. The effects of introducing PDIs with different structures into TiO2 were evaluated by assaying the photodegradation rate of methylene blue.


2013 ◽  
Vol 69 (1) ◽  
pp. 113-119 ◽  
Author(s):  
Sakthivel Pitchaimuthu ◽  
Ponnusamy Velusamy

An attempt has been made to enhance the photocatalytic activity of CeO2 for visible light assisted decoloration of methylene blue (MB) dye in aqueous solutions by β-cyclodextrin (β-CD). The inclusion complexation patterns between host and guest (i.e., β-CD and MB) have been confirmed with UV–visible spectral data. The interaction between CeO2 and β-CD has also been characterized by field emission scanning electron microscopy analysis. The photocatalytic activity of the catalyst under visible light was investigated by measuring the photodegradation of MB in aqueous solution. The effects of key operational parameters such as initial dye concentration, initial pH, CeO2 concentration as well as illumination time on the decolorization extents were investigated. Among the processing parameters, the pH of the reaction solution played an important role in tuning the photocatalytic activity of CeO2. The maximum photodecoloration rate was achieved at basic pH (pH 11). Under the optimum operational conditions, approximately 99.6% dye removal was achieved within 120 min. The observed results indicate that the decolorization of the MB followed a pseudo-first order kinetics.


2011 ◽  
Vol 335-336 ◽  
pp. 1385-1390 ◽  
Author(s):  
Shuo Wiei Zhao ◽  
Hui Xu ◽  
Hua Ming Li ◽  
Yuan Guo Xu

In order to improve the photocatalytic activity, Co was successfully loaded into Ag3VO4 by using impregnation process. The samples were characterized by X-ray diffraction (XRD), scanning electron microscope (SEM), energy-dispersive X-ray spectroscopy (EDS) and diffuse reflectance spectroscopy (DRS). The XRD and SEM–EDS analyses revealed that Co ion was dispersed on Ag3VO4. The DRS results indicated that the absorption edge of the Co–Ag3VO4 catalyst shifted to longer wavelength. The enhanced photocatalytic activity of Co–Ag3VO4 for Methylene Blue(MB) dye degradation under visible light irradiation was due to its wider absorption edge and higher separation rate of photo-generated electron and holes. In the experimental conditions, it is demonstrated that the MB was effectively degraded by more than 95% within 40 min when the Co–Ag3VO4 catalyst was calcined at 300°C with 1 wt.% Co content.


RSC Advances ◽  
2016 ◽  
Vol 6 (60) ◽  
pp. 54709-54717 ◽  
Author(s):  
Aasim Shahzad ◽  
Taekyung Yu ◽  
Woo-Sik Kim

Ag/AgBr hybrid nanostructures were prepared by reducing AgBr nanoparticles synthesized by reaction of Ag+ with Br−. The Ag/AgBr hybrid nanostructures exhibited enhanced photocatalytic activity and recyclability for decomposing methylene blue (MB).


2017 ◽  
Vol 28 (2) ◽  
pp. 85-103 ◽  
Author(s):  
Hajar Atiqah Mohd Azmy ◽  
◽  
Nor Amirah Razuki ◽  
Azia Wahida Aziz ◽  
Nurul Syamimi Abdul Satar ◽  
...  

2021 ◽  
Vol 7 (2) ◽  
pp. 129-141
Author(s):  
Adawiah Adawiah ◽  
Muhammad Derry Luthfi Yudhi ◽  
Agustino Zulys

The yttrium based metal-organic framework (MOF) Y-PTC was synthesized by the solvothermal method using perylene as the linker and yttrium as metal ion. This study aims to assess the photocatalytic activity of yttrium-perylenetetracarboxylate (Y-PTC) metal-organic framework (MOF) toward methylene blue and methyl orange under visible light irradiation. The results of the FTIR analysis showed that Y-PTC MOF had a different structure and composition from its precursor (Na4PTC). The Y-PTC MOF has a bandgap energy value of 2.20 eV with a surface area of 47.7487 m2/g. The SEM-EDS analysis showed an elemental composition of yttrium, carbon, and oxygen, were 6.9%, 72.1% and 20.7%, respectively. Furthermore, Y-PTC MOF was able to adsorb dyes at the optimum by 78.10% and 35.57% toward methylene blue (MB) and methyl orange (MO) at the dispersion period of 60 mins. Y-PTC MOF exhibited photocatalytic activity towards the degradation of methylene blue and methyl orange under visible light irradiation. The addition of H2O2 inhibited Y-PTC photocatalytic activity towards MO degradation from 50.89% to 26.38%. In contrast to MO, the addition of H2O2 had a positive effect on MB, which increased the degradation from 87.56% to 91.65%. Therefore, Y-PTC MOF possessed the potential of a photocatalyst material in dyes degradation under visible light irradiation.


2018 ◽  
Vol 42 (13) ◽  
pp. 11109-11116 ◽  
Author(s):  
R. Salimi ◽  
A. A. Sabbagh Alvani ◽  
N. Naseri ◽  
S. F. Du ◽  
D. Poelman

A new plasmonic Ag hybridized CuWO4/WO3 heterostructured nanocomposite was successfully synthesized via a ligand-assisted sol gel method and the photocatalytic activity was evaluated by photo-degradation of methylene blue (MB) under visible light irradiation.


RSC Advances ◽  
2014 ◽  
Vol 4 (55) ◽  
pp. 28978-28986 ◽  
Author(s):  
Huigang Wang ◽  
Dongmei Zhou ◽  
Shaosong Shen ◽  
Junmin Wan ◽  
Xuming Zheng ◽  
...  

Copper(ii)tetra(4-carboxyphenyl) porphyrin were chemically sensitized on TiO2, its electronic relaxation dynamics and the visible-light induced catalytic mechanism are discussed.


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