scholarly journals Влияние мультиплетных уровней Sm-=SUP=-3+-=/SUP=- и Eu-=SUP=-3+-=/SUP=- на теплоемкость мультиферроика BiFeO-=SUB=-3-=/SUB=-

2021 ◽  
Vol 63 (6) ◽  
pp. 763
Author(s):  
Р.Г. Митаров ◽  
С.Н. Каллаев ◽  
З.М. Омаров ◽  
О.М. Назарова ◽  
Л.А. Резниченко
Keyword(s):  
Thermal Conductivity ◽  
Heat Capacity ◽  
Rare Earth ◽  
Specific Heat ◽  
Temperature Dependence ◽  
Bismuth Ferrite ◽  
Rare Earth Ions ◽  
Phonon Thermal Conductivity ◽  
Additional Heat ◽  
Schottky Effect

The temperature dependence of the heat capacity of the multiferroics BiFeO3, Bi0.90Sm0.10FeO3, and Bi0.90Eu0.10FeO3 has been studied. It was found that the substitution of europium and samarium ions for bismuth ions in bismuth ferrite leads to the appearance of an additional heat capacity component due to transitions of 4f - electrons of rare earth ions to higher levels of the multiplet. A connection is established between the decrease in phonon thermal conductivity and the Schottky effect for the specific heat.

scholarly journals Рассеяние фононов на парамагнитных ионах европия и самария в феррите висмута

2020 ◽  
Vol 62 (7) ◽  
pp. 1137
Author(s):  
Р.Г. Митаров ◽  
С.Н. Каллаев ◽  
А.М. Бакмаев ◽  
С.А. Резниченко ◽  
А.Т. Темиров
Keyword(s):  
Thermal Conductivity ◽  
Rare Earth ◽  
Thermal Diffusivity ◽  
Temperature Dependence ◽  
Wide Temperature Range ◽  
Bismuth Ferrite ◽  
Resonance Scattering ◽  
Phonon Thermal Conductivity ◽  
Temperature Range ◽  
The Rare Earth

The temperature dependence of the thermal diffusivity and thermal conductivity of the multiferroics BiFeO3, Bi0.90Sm0.10FeO3 and Bi0.90Еu0.10FeO3 is studied. It was found that the substitution of bismuth ions by the rare-earth europium and samarium ions in bismuth ferrite leads to a decrease in phonon thermal conductivity in a wide temperature range. It was established that the decrease in the thermal conductivity of bismuth ferrite is due to resonance scattering of phonons at paramagnetic levels of europium and samarium ions.

scholarly journals Эффект Шоттки в Bi-=SUB=-0.95-=/SUB=-Sm-=SUB=-0.05-=/SUB=-FeO-=SUB=-3-=/SUB=-

2019 ◽  
Vol 61 (8) ◽  
pp. 1557
Author(s):  
Р.Г. Митаров ◽  
С.Н. Каллаев ◽  
З.М. Омаров ◽  
Л.А. Резниченко
Keyword(s):  
Specific Heat ◽  
Temperature Dependence ◽  
Bismuth Ferrite ◽  
Multiplet Structure ◽  
Temperature Range ◽  
Schottky Effect

AbstractThe temperature dependence of the specific heat of the Bi_0.95Sm_0.05FeO_3 multiferroic has been studied in the temperature range 130–780 K. The substitution of samarium ions for bismuth ions in the bismuth ferrite is found to lead to the appearance of additional specific heat component that is due to the manifestation of the Schottky effect for three-level states and multiplet structure of 4 f electrons of samarium ions.

Automatic Measurement of the Dependence on Pressure and Temperature of the Mass Density of Drilling Fluids

2021 ◽  
Author(s):  
Eric Cayeux
Keyword(s):  
Thermal Conductivity ◽  
Heat Capacity ◽  
Specific Heat ◽  
Temperature Dependence ◽  
Speed Of Sound ◽  
Drilling Fluid ◽  
Mass Density ◽  
Adiabatic Compressibility ◽  
Drilling Fluids ◽  
Pvt Behavior

Abstract Drilling fluids are subjected to large variations of pressure and temperature while they are circulated in a well. This span of pressures and temperatures is so large that the mass density of the drilling mud differs from one depth to another. For a precise estimation of the hydrostatic and hydrodynamic pressures, it is therefore important to have a good estimation of the pressure and temperature dependence of the mass density of drilling fluids. Usually, the mass density of drilling fluids is manually measured with a mud balance. The pressure and temperature dependence of the mass density of the fluid, i.e. its PVT behavior, is then estimated based on the PVT behavior of its components and their relative proportions. However, variations in the composition of the fluid mix and uncertainties on the PVT behavior of each components, may lead to inaccuracies. To circumvent these limitations, an apparatus that measures directly and automatically the PVT behavior of the drilling fluid contained in a pit has been designed. The setup measures both the mass density and the speed of sound in the fluid at specific conditions of pressure and temperature. From the speed of sound in the liquid mix, it is possible to estimate the adiabatic compressibility. The device also utilizes a heat exchanger from which the thermal conductivity and specific heat capacity of the drilling fluid can be estimated. Combining the specific heat capacity, thermal conductivity and the adiabatic compressibility, the isothermal compressibility can be calculated. By combining measurements made at different conditions of pressure and temperature, a PVT model of the drilling fluid is estimated. By providing automatically, and on a continuous basis, the actual PVT behavior of drilling fluids, drilling automation systems can gain in precision and at the same time, their configuration can be simplified, therefore making them more accessible to any drilling operation.

scholarly journals Influence of alkaline modification on selected properties of banana fiber paperbricks

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Abayomi A. Akinwande ◽  
Adeolu A. Adediran ◽  
Oluwatosin A. Balogun ◽  
Oluwaseyi S. Olusoju ◽  
Olanrewaju S. Adesina
Keyword(s):  
Thermal Conductivity ◽  
Heat Capacity ◽  
Specific Heat ◽  
Specific Heat Capacity ◽  
Moisture Absorption ◽  
Water Volume ◽  
Banana Fiber ◽  
Fiber Loading ◽  
Banana Fibers ◽  
Alkaline Modification

AbstractIn a bid to develop paper bricks as alternative masonry units, unmodified banana fibers (UMBF) and alkaline (1 Molar aqueous sodium hydroxide) modified banana fibers (AMBF), fine sand, and ordinary Portland cement were blended with waste paper pulp. The fibers were introduced in varying proportions of 0, 0.5, 1.0 1.5, 2.0, and 2.5 wt% (by weight of the pulp) and curing was done for 28 and 56 days. Properties such as water and moisture absorption, compressive, flexural, and splitting tensile strengths, thermal conductivity, and specific heat capacity were appraised. The outcome of the examinations carried out revealed that water absorption rose with fiber loading while AMBF reinforced samples absorbed lesser water volume than UMBF reinforced samples; a feat occasioned by alkaline treatment of banana fiber. Moisture absorption increased with paper bricks doped with UMBF, while in the case of AMBF-paper bricks, property value was noted to depreciate with increment in AMBF proportion. Fiber loading resulted in improvement of compressive, flexural, and splitting tensile strengths and it was noted that AMBF reinforced samples performed better. The result of the thermal test showed that incorporation of UMBF led to depreciation in thermal conductivity while AMBF infusion in the bricks initiated increment in value. Opposite behaviour was observed for specific heat capacity as UMBF enhanced heat capacity while AMBF led to depreciation. Experimental trend analysis carried out indicates that curing length and alkaline modification of fiber were effective in maximizing the properties of paperbricks for masonry construction.

The Key Factors of Low-Frequency Electric Heating Assisted Depressurization Method in the Exploiting of Methane Hydrate Sediments

2021 ◽  
Author(s):  
Ermeng Zhao ◽  
Jian Hou ◽  
Yunkai Ji ◽  
Lu Liu ◽  
Yongge Liu ◽  
...  
Keyword(s):  
Thermal Conductivity ◽  
Heat Capacity ◽  
Specific Heat ◽  
Specific Heat Capacity ◽  
Low Frequency ◽  
Electric Heating ◽  
Gas Production ◽  
Hydrate Decomposition ◽  
Hydrate Saturation ◽  
Production Behavior

Abstract Natural gas hydrate is widely distributed in the permafrost and marine deposits, and is regarded as an energy resource with great potential. The low-frequency electric heating assisted depressurization (LF-EHAD) has been proven to be an efficient method for exploiting hydrate sediments, which involves complex multi-physics processes, i.e. current conduction, multiphase flow, chemical reaction and heat transfer. The physical properties vary greatly in different hydrate sediments, which may profoundly affect the hydrate decomposition in the LF-EHAD process. In order to evaluate the influence of hydrate-bearing sediment properties on the gas production behavior and energy utilization efficiency of the LF-EHAD method, a geological model was first established based on the data of hydrate sediments in the Shenhu Area. Then, the influence of permeability, porosity, thermal conductivity, specific heat capacity, hydrate saturation and hydrate-bearing layer (HBL) thickness on gas production behavior is comprehensively analyzed by numerical simulation method. Finally, the energy efficiency ratio under different sediment properties is compared. Results indicate that higher gas production is obtained in the high-permeability hydrate sediments during depressurization. However, after the electric heating is implemented, the gas production first increases and then tends to be insensitive as the permeability decreases. With the increasing of porosity, the gas production during depressurization decreases due to the low effective permeability; while in the electric heating stage, this effect is reversed. High thermal conductivity is beneficial to enhance the heat conduction, thus promoting the hydrate decomposition. During depressurization, the gas production is enhanced with the increase of specific heat capacity. However, more heat is consumed to increase the reservoir temperature during electric heating, thereby reducing the gas production. High hydrate saturation is not conducive to depressurization because of the low effective permeability. After electric heating, the gas production increases significantly. High HBL thickness results in a higher gas production during depressurization, while in the electric heating stage, the gas production first increases and then remains unchanged with the increase of thickness, due to the limited heat supply. The comparison results of energy efficiency suggest that electric heating is more advantageous for hydrate sediments with low permeability, high porosity, high thermal conductivity, low specific heat capacity, high hydrate saturation and high HBL thickness. The findings in this work can provide a useful reference for evaluating the application of the LF-EHAD method in gas hydrate sediments.

Determination of the Thermal Properties of a PCB by Coupled Numerical and Experimental Approach

2020 ◽  
Author(s):  
Yener Usul ◽  
Mustafa Özçatalbaş
Keyword(s):  
Thermal Conductivity ◽  
Heat Capacity ◽  
Thermal Properties ◽  
Numerical Analysis ◽  
Specific Heat ◽  
Specific Heat Capacity ◽  
Thermal Analyses ◽  
Analysis Model ◽  
Linear Temperature ◽  
Coefficient Of Thermal Conductivity

Abstract Increasing demand for usage of electronics intensely in narrow enclosures necessitates accurate thermal analyses to be performed. Conduction based FEM (Finite Element Method) is a common and practical way to examine the thermal behavior of an electronic system. First step to perform a numerical analysis for any system is to set up the correct analysis model. In this paper, a method for obtaining the coefficient of thermal conductivity and specific heat capacity of a PCB which has generally a complex composite layup structure composed of conductive layers, and dielectric layers. In the study, above mentioned properties are obtained performing a simple nondestructive experiment and a numerical analysis. In the method, a small portion of PCB is sandwiched from one side at certain pressure by jaws. A couple of linear temperature profiles are applied to the jaws successively. Unknown values are tuned in the analysis model until the results of FEM analysis and experiment match. The values for the coefficient of thermal conductivity and specific heat capacity which the experiment and numerical analysis results match can be said to be the actual values. From this point on, the PCB whose thermal properties are determined can be analyzed numerically for any desired geometry and boundary condition.

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