scholarly journals Фотоуправляемые обратимые изменения электронных и колебательных спектров фотохромного диарилэтена в различных наноструктурированных системах

2022 ◽  
Vol 130 (3) ◽  
pp. 433
Author(s):  
Г.Т. Василюк ◽  
П.В. Карпач ◽  
С.Д. Гоголева ◽  
А.О. Айт ◽  
В.А. Барачевский ◽  
...  
Keyword(s):  
Solid Phase ◽  
High Capacity ◽  
Molecular Switches ◽  
Colloidal Nanoparticles ◽  
Theoretical Studies ◽  
Nanostructured Systems ◽  
Electronic And Vibrational Spectra ◽  
Photoinduced Changes ◽  
Experimental And Theoretical Studies ◽  
Colloidal Metal

An analysis of the results of complex experimental and theoretical studies of photoinduced changes in the spectral properties of photochromic diarylethene in various nanostructured systems is presented. The properties of diarylethene were studied in solutions in the presence of colloidal metal and semiconductor nanoparticles, as well as in the form of solid-phase composite nanostructured core-shell systems based on colloidal nanoparticles with a shell of diarylethene molecules (including in a polymer matrix). A photoinduced reversible change in the electronic and vibrational spectra of diarylethene in various studied matrices was found. The results can be used to create optoelectronic photo-switchable elements for ultra-high-capacity memory devices, photo-controlled molecular switches and sensors.

Experimental and theoretical studies of photoinduced reactions in the solid phase of the interstellar medium

2020 ◽  
Vol 89 (4) ◽  
pp. 430-448 ◽  
Author(s):  
M S Murga ◽  
D S Wiebe ◽  
A I Vasyunin ◽  
V N Varakin ◽  
A V Stolyarov
Keyword(s):  
Interstellar Medium ◽  
Solid Phase ◽  
Theoretical Studies ◽  
Photoinduced Reactions ◽  
Experimental And Theoretical Studies

The Stabilizing Effect of Pre-Equilibria: A Trifluoromethyl Complex as CF2 Reservoir in Catalytic Olefin Difluorocarbenation

2020 ◽  
Author(s):  
Thomas Louis-Goff ◽  
Huu Vinh Trinh ◽  
Eileen Chen ◽  
Arnold L. Rheingold ◽  
Christian Ehm ◽  
...  
Keyword(s):  
High Selectivity ◽  
Side Reactions ◽  
Theoretical Studies ◽  
Attractive Feature ◽  
Catalyst Recovery ◽  
Wide Range ◽  
Stabilizing Effect ◽  
Experimental And Theoretical Studies

A new, efficient, catalytic difluorocarbenation of olefins to give 1,1-difluorocyclopropanes is presented. The catalyst, an organobismuth complex, uses TMSCF<sub>3</sub> as a stoichiometric difluorocarbene source. We demonstrate both the viability and robustness of this reaction over a wide range of alkenes and alkynes, including electron-poor alkenes, to generate the corresponding 1,1-difluorocyclopropanes and 1,1-difluorocyclopropenes. Ease of catalyst recovery from the reaction mixture is another attractive feature of this method. In depth experimental and theoretical studies showed that the key difluorocarbene-generating step proceeds through a bismuth non-redox synchronous mechanism generating a highly reactive free CF<sub>2</sub> in an endergonic pre-equilibrium. It is the reversibility when generating the difluorocarbene that accounts for the high selectivity, while minimizing CF<sub>2</sub>-recombination side-reactions.

Strong coupling: resonant effects

2017 ◽  
Author(s):  
Alexey V. Kavokin ◽  
Jeremy J. Baumberg ◽  
Guillaume Malpuech ◽  
Fabrice P. Laussy
Keyword(s):  
Strong Coupling ◽  
Experimental Studies ◽  
Strong Coupling Regime ◽  
Theoretical Studies ◽  
Stimulated Scattering ◽  
Quantum Theories ◽  
Pump Probe ◽  
Exciton Polaritons ◽  
Linear Optical Properties ◽  
Experimental And Theoretical Studies

This chapter presents experimental studies performed on planar semiconductor microcavities in the strong-coupling regime. The first section reviews linear experiments performed in the 1990s that evidence the linear optical properties of cavity exciton-polaritons. The chapter is then focused on experimental and theoretical studies of resonantly excited microcavity emission. We mainly describe experimental configuations in which stimulated scattering was observed due to formation of a dynamical condensate of polaritons. Pump-probe and cw experiments are described in addition. Dressing of the polariton dispersion and bistability of the polariton system due to inter-condensate interactions are discussed. The semiclassical and the quantum theories of these effects are presented and their results analysed. The potential for realization of devices is also discussed.

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