scholarly journals Framework structure materials in photovoltaics based on perovskites 3D

2022 ◽  
Vol 5 (2) ◽  
Author(s):  
E.M. Keita ◽  
B. Mbow ◽  
C. Sene

The inorganic and hybrid organic / inorganic perovskites based on lead halide and derived materials (alloys) having the formula ABX3 are emerging as a new and innovative family of absorber materials for the conversion of solar energy into electricity in photovoltaic systems. Thanks to their composition, perovskites and derivatives have exceptional optical, electrical and structural properties with high absorption of light in the visible solar spectrum and good mobility of charge carriers generated by photons facilitating the extraction of electric current. Due to these important properties, perovskite solar cells combine a high efficiency of conversion of light into electricity with great ease of preparation and synthesis at very low costs via simple deposition techniques. In this article we review the structural and optoelectronic properties of perovskites 3D exhibiting photovoltaic properties, we are also interested in the operating principle of perovskite-based solar cells, charge transport materials and associated architectures. Simple fabrication techniques and issues with stability and hysteresis are also discussed.

Nanomaterials ◽  
2020 ◽  
Vol 10 (9) ◽  
pp. 1676
Author(s):  
Md. Shahiduzzaman ◽  
Daiki Kuwahara ◽  
Masahiro Nakano ◽  
Makoto Karakawa ◽  
Kohshin Takahashi ◽  
...  

The most frequently used n-type electron transport layer (ETL) in high-efficiency perovskite solar cells (PSCs) is based on titanium oxide (TiO2) films, involving a high-temperature sintering (>450 °C) process. In this work, a dense, uniform, and pinhole-free compact titanium dioxide (TiOx) film was prepared via a facile chemical bath deposition process at a low temperature (80 °C), and was applied as a high-quality ETL for efficient planar PSCs. We tested and compared as-deposited substrates sintered at low temperatures (< 150 °C) and high temperatures (> 450 °C), as well as their corresponding photovoltaic properties. PSCs with a high-temperature treated TiO2 compact layer (CL) exhibited power conversion efficiencies (PCEs) as high as 15.50%, which was close to those of PSCs with low-temperature treated TiOx (14.51%). This indicates that low-temperature treated TiOx can be a potential ETL candidate for planar PSCs. In summary, this work reports on the fabrication of low-temperature processed PSCs, and can be of interest for the design and fabrication of future low-cost and flexible solar modules.


Author(s):  
Arunkumar Prabhakaran Shyma ◽  
Andrews Nirmala Grace ◽  
Vimala Raghavan ◽  
George Jacob ◽  
Raja Sellappan

: Perovskite-based photovoltaic technology has gained significant attention owing to its tunable electrical and optical properties. Among them, lead-based perovskites are considered as the most efficient one that delivers maximum power conversion efficiency with ample stability. In the current scenario, the perovskite-based solar cells (PSCs) can be classified into two main categories, i.e., highly efficient lead-containing and underperforming lead-free based. Even though lead-based PSCs delivers high efficiency, it loses the charm in the context of lead toxicity. The toxicity issue related to lead stands as a barrier to the commercialization of lead-based PSCs. To date, various materials have been prepared and implemented as an alternative to lead in the absorber layer. Tin (Sn) based perovskites are explored as an alternative absorber material owing to its photovoltaic properties that are comparable to lead. Tin-based perovskites exhibit some drawbacks, such as rapid crystallization, lack of oxidation stability, etc. Many research group has addressed the problems regarding tinbased perovskites and modified its structural and morphological aspects through compositional engineering as well as functional additives and managed to obtain an efficiency of around 10 %. In this review, we portray the state of the art developments of tin-based PSCs and its future perspectives.


2021 ◽  
Vol 889 (1) ◽  
pp. 012057
Author(s):  
Rinku Kumari ◽  
Karan Singh Vinayak ◽  
Deepak Kumar

Abstract Extended efficiency of solar cells to ensemble more solar energy as well as its optimum conversion and utilization is believed to be a major challenge in current times. The spectral mismatch between the distribution of energy in the solar spectrum incidence and the semiconducting material band gap is a major restriction in the performance of solar cells. The conversion of wavelength of the sun is a necessary requisite to reduce spectral disruption. Of late, the solar cell converters are presumed as up-converted components and products derived from down conversion. Materials like NaCsWO3, NaYF4, and NaYF4: Yb, Er are synthesized and used to overcome the problem like deficiency of up-conversion luminescence (UCL) materials and device structures. The intensity of UCL can be enhanced by a significant time when the amount of NaCsWO3 is 2.8 m mol per cent. UCL material is considered as one of the best approaches to obtain high-efficiency perovskite solar cells (PSCs). In order to overcome these difficulties, not only were these effective up-conversion nano-particles (UPCNPs) doped into the hole layer but the perovskite foil was also modified in PSCs. The highest power conversion (PCE) performance reached 18.89%. Enhanced UCLs allow for UCNPs to extend the recognition spectrum of near PSCs. The objective of this comprehensive and focused review is to highlight the different synthesis techniques used in up-conversion nano-materials, for solar cell applications along with a theoretical perspective in this regard.


2017 ◽  
Vol 4 (10) ◽  
pp. 170942 ◽  
Author(s):  
Pengyu Su ◽  
Wuyou Fu ◽  
Huizhen Yao ◽  
Li Liu ◽  
Dong Ding ◽  
...  

In this paper, we fabricated a TiO 2 homogeneous hybrid structure for application in perovskite solar cells (PSCs) under ambient conditions. Under the standard air mass 1.5 global (AM 1.5G) illumination, PSCs based on homogeneous hybrid structure present a maximum power conversion efficiency of 5.39% which is higher than that of pure TiO 2 nanosheets. The enhanced properties can be explained by the better contact of TiO 2 nanosheets/nanoparticles with CH 3 NH 3 PbI 3 and fewer pinholes in electron transport materials. The advent of such unique structure opens up new avenues for the future development of high-efficiency photovoltaic cells.


Nano Energy ◽  
2021 ◽  
Vol 82 ◽  
pp. 105712
Author(s):  
Sisi Wang ◽  
Zhipeng Zhang ◽  
Zikang Tang ◽  
Chenliang Su ◽  
Wei Huang ◽  
...  

2021 ◽  
pp. 2001466
Author(s):  
Yali Chen ◽  
Xuejiao Zuo ◽  
Yiyang He ◽  
Fang Qian ◽  
Shengnan Zuo ◽  
...  

2021 ◽  
Vol 13 (1) ◽  
Author(s):  
Tianhao Wu ◽  
Zhenzhen Qin ◽  
Yanbo Wang ◽  
Yongzhen Wu ◽  
Wei Chen ◽  
...  

AbstractPerovskite solar cells (PSCs) emerging as a promising photovoltaic technology with high efficiency and low manufacturing cost have attracted the attention from all over the world. Both the efficiency and stability of PSCs have increased steadily in recent years, and the research on reducing lead leakage and developing eco-friendly lead-free perovskites pushes forward the commercialization of PSCs step by step. This review summarizes the main progress of PSCs in 2020 and 2021 from the aspects of efficiency, stability, perovskite-based tandem devices, and lead-free PSCs. Moreover, a brief discussion on the development of PSC modules and its challenges toward practical application is provided.


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