Insights into tropical cloud chemistry in Réunion (Indian Ocean): results from the BIO-MAÏDO campaign

We present here the results obtained during an intensive field campaign conducted in the framework of the French “BIO-MAÏDO” (Bio-physico-chemistry of tropical clouds at Maïdo (Réunion Island): processes and impacts on secondary organic aerosols' formation) project. This study integrates an exhaustive chemical and microphysical characterization of cloud water obtained in March–April 2019 in Réunion (Indian Ocean). Fourteen cloud samples have been collected along the slope of this mountainous island. Comprehensive chemical characterization of these samples is performed, including inorganic ions, metals, oxidants, and organic matter (organic acids, sugars, amino acids, carbonyls, and low-solubility volatile organic compounds, VOCs). Cloud water presents high molecular complexity with elevated water-soluble organic matter content partly modulated by microphysical cloud properties. As expected, our findings show the presence of compounds of marine origin in cloud water samples (e.g. chloride, sodium) demonstrating ocean–cloud exchanges. Indeed, Na+ and Cl− dominate the inorganic composition contributing to 30 % and 27 %, respectively, to the average total ion content. The strong correlations between these species (r2 = 0.87, p value: < 0.0001) suggest similar air mass origins. However, the average molar Cl-/Na+ ratio (0.85) is lower than the sea-salt one, reflecting a chloride depletion possibly associated with strong acids such as HNO3 and H2SO4. Additionally, the non-sea-salt fraction of sulfate varies between 38 % and 91 %, indicating the presence of other sources. Also, the presence of amino acids and for the first time in cloud waters of sugars clearly indicates that biological activities contribute to the cloud water chemical composition. A significant variability between events is observed in the dissolved organic content (25.5 ± 18.4 mg C L−1), with levels reaching up to 62 mg C L−1. This variability was not similar for all the measured compounds, suggesting the presence of dissimilar emission sources or production mechanisms. For that, a statistical analysis is performed based on back-trajectory calculations using the CAT (Computing Atmospheric Trajectory Tool) model associated with the land cover registry. These investigations reveal that air mass origins and microphysical variables do not fully explain the variability observed in cloud chemical composition, highlighting the complexity of emission sources, multiphasic transfer, and chemical processing in clouds. Even though a minor contribution of VOCs (oxygenated and low-solubility VOCs) to the total dissolved organic carbon (DOC) (0.62 % and 0.06 %, respectively) has been observed, significant levels of biogenic VOC (20 to 180 nmol L−1) were detected in the aqueous phase, indicating the cloud-terrestrial vegetation exchange. Cloud scavenging of VOCs is assessed by measurements obtained in both the gas and aqueous phases and deduced experimental gas-/aqueous-phase partitioning was compared with Henry's law equilibrium to evaluate potential supersaturation or unsaturation conditions. The evaluation reveals the supersaturation of low-solubility VOCs from both natural and anthropogenic sources. Our results depict even higher supersaturation of terpenoids, evidencing a deviation from thermodynamically expected partitioning in the aqueous-phase chemistry in this highly impacted tropical area.

Large-Scale Background and the Role of Quasi-Biweekly Moisture Transport in the Extreme Yangtze River Rainfall in Summer 2020

A severe flooding hit southern China along the Yangtze River in summer 2020. The floods were induced by heavy rains, and the associated dynamic and thermodynamic conditions are investigated using daily gridded rainfall data of China and NCEP-NCAR reanalysis. It is found that the summer rainfall over the Yangtze River Basin (YRB) experienced pronounced subseasonal variation in 2020, dominated by a quasi-biweekly oscillation (QBWO) mode. The southwestward-moving anomalous QBWO circulation was essentially the fluctuation of cold air mass related to the tropospheric polar vortex or trough-ridge activities over the mid-high latitude Eurasian in boreal summer. The large-scale southwestward-transport of cold air mass from mid-high latitudes and the northeastward-transport of warm and moist air by the strong anomalous anticyclone over the western North Pacific provided important circulation support for the heavy rainfall in the YRB. The quasi-biweekly anomalies of potential and divergent component of vertically integrated water vapor flux played a major role in maintaining the moisture during summer 2020. The diagnosis of moisture budget shows that the enhanced moisture associated with the quasi-biweekly fluctuation rainfall was primarily attributed to the moisture convergence. The convergence of QBWO specific humidity by the background mean flow and convergence of mean specific humidity by QBWO flow played dominant roles in contributing to the positive moisture tendency. In combination with an adiabatic ascent induced by the warm temperature advection, the boundary layer moisture convergence strengthens the upward transport of moisture from lower troposphere. The vertical moisture transport associated with boundary layer convergence was of critical importance in causing low-level tropospheric moistening, whereas the horizontal advection of moisture showed a negative effect during the anomalous quasi-biweekly summer rainfall in 2020.

First evidence of microplastics in Antarctic snow

In recent years, airborne microplastics have been identified in a range of remote environments. However, data throughout the Southern Hemisphere, in particular Antarctica, are largely absent to date. We collected snow samples from 19 sites across the Ross Island region of Antarctica. Suspected microplastic particles were isolated and their composition confirmed using micro-Fourier transform infrared spectroscopy (μFTIR).We identified microplastics in all Antarctic snow samples at an average concentration of 29 particles L−1, with fibres the most common morphotype and polyethylene terephthalate (PET) the most common polymer. To investigate sources, backward air mass trajectories were run from the time of sampling. These indicate potential long-range transportation of up to 6000 kilometers, assuming a residence time of 6.5 days. Local sources were also identified as potential inputs into the environment, as the polymers identified were consistent with those used in clothing and equipment from nearby research stations. This study adds to the growing body of literature regarding microplastics as a ubiquitous airborne pollutant, and establishes their presence in Antarctica.

The unusually long cold spell and the snowstorm Filomena in Spain in January 2021

In early January 2021, Spain was affected by two extreme events – an unusually long cold spell and a heavy snowfall event associated with extratropical cyclone Filomena. For example, up to 50 cm of snow fell in Madrid and the surrounding areas in 4 days. Already during 9 days prior to the snowfall event, anomalously cold temperatures at 850 hPa and night frosts prevailed over large parts of Spain. During this period, anomalously cold and dry air was transported towards Spain from central Europe and even from the Barents Sea. The storm Filomena, which was responsible for major parts of the snowfall event, developed from a precursor low-pressure system over the central North Atlantic. Filomena intensified due to interaction with an upper-level potential vorticity (PV) trough, which was the result of anticyclonic wave breaking over Europe. In turn, this wave breaking was related to an intense surface anticyclone and upper-level ridge, whose formation was strongly influenced by a warm conveyor belt outflow of a cyclone off the coast of Newfoundland. The most intense snowfall occurred on 09 January and was associated with a sharp air mass boundary with an equivalent potential temperature difference at 850 hPa across Spain exceeding 20 K. Overall, the combination of pre-existing cold surface temperatures, the optimal position of the air mass boundary, and the dynamical forcing for ascent induced by Filomena and its associated upper-level trough were all essential – and in parts physically independent – ingredients for this extreme snowfall event to occur.

Influence of air masses on microphone vibration sensitivity

A study is presented of the primary design parameters that influence the vibration sensitivity of a microphone. The sensitivity to vibration is generally determined by the mass of the pressure-sensing diaphragm along with the mass of air that moves with it. The sound-sensing performance is improved as the pressure-sensing diaphragm is made thinner, but for a thin enough diaphragm, the moving air mass is not negligible relative to that of the diaphragm itself. In the present study, we develop a simple duct-acoustic model to account for the effect of the co-vibrating air. It is shown that an idealized massless, thin microphone diaphragm will still produce unwanted vibration signal due to acceleration of the air masses within the microphone. For a small microphone, the predicted pressure related acceleration sensitivity is found to be a simple function of the mass per unit area of the air inside of the microphone package. The acceleration sensitivity predicted using a finite element model of a one micrometer thick clamped flexible silicon diaphragm agrees with that predicted by the simple duct model. Measured and predicted acceleration sensitivities are compared for several MEMS and sub-miniature electret microphones of different back volume lengths . It is found that the primary design parameter determining vibration sensitivity for these microphones is the effective length of the column of air inside the microphone’s packaging. Microphones that have longer air-filled volumes had greater pressure related acceleration sensitivity.

Measurement report: Characterization and source apportionment of coarse particulate matter in Hong Kong: Insights into the constituents of unidentified mass and source origins in a coastal city in southern China

Coarse particulate matter (i.e., PM with aerodynamic diameter between 2.5 and 10 micrometers or PMcoarse) has been increasingly recognized of its importance in PM10 regulation because of its growing proportion in PM10 and the accumulative evidence for its adverse health impact. In this work, we present comprehensive PMcoarse speciation results obtained through a one-year long (January 2020–February 2021) joint PM10 and PM2.5 chemical speciation study in Hong Kong, a coastal and highly urbanized city in southern China. The annual average concentration of PMcoarse is 14.9 ± 8.6 μg m–3 (±standard deviation), accounting for 45 % of PM10 (32.9 ± 18.5 μg m–3). The measured chemical components explain ~75 % of the PMcoarse mass. The unexplained part is contributed by unmeasured geological components and residue liquid water content, supported by analyses by positive matrix factorization (PMF) and the thermodynamic equilibrium model ISORROPIA II. The PMcoarse mass is apportioned to four sources resolved by PMF, namely soil dust, copper-rich dust, fresh sea salt, and an aged sea salt factor containing secondary inorganic aerosols (mostly nitrate). Back-trajectory cluster analysis reveals significant variations in source contributions with the air mass origin. Under the influence of marine air mass, PMcoarse is the lowest (average = 8.0 μg m–3) and sea salt is the largest contributor (47 %), followed by the two dust factors (38 % in total). When the site receives air mass from the northern continental region, PMcoarse increased substantially to 21.2 μg m–3, with the two dust factors contributing 90 % of the aerosol mass. The potential dust source areas are mapped using the Concentration-Weighted Trajectory technique, showing either the Greater Bay Area or the greater part of southern China as the origin of fugitive dust emissions leading to elevated ambient PMcoarse loadings in Hong Kong. This study, first of this kind in our region, provides highly relevant guidance to other locations with similar monitoring needs. Additionally, the study findings point to the needs for further research on the sources, transport, aerosol processes, and health effects of PMcoarse.

Karstic Groundwater Origin and Recharge Process in Zagros Region: Insights From Stable Isotopes (δ18O and Δ2H) Approach

Zagros is an important region with high quality and quantity karstic water resources in the Middle East. This region provides a dominant part of potable and agricultural water needs for its inhabitants as well as agricultural water needs for nearby regions. Therefore, studying karstic water resources in Zagros by accurate methods such as stable isotopes techniques is very important. In this investigation, hydrological characteristics of groundwater resources including groundwater origin, recharge rate and recharge elevation have been studied using stable isotopes (18O and 2H). The results show that stable isotopes signatures in groundwater resources show notable variations across Zagros and groundwater resource mainly plot on south and west Zagros meteoric water lines. In addition, recharge elevation and recharge rate in groundwater resources also show significant variations in Zagros. Finally, the stable isotopes signatures in precipitation and groundwater has been used to study the role of each dominant air mass (contribution percentage of precipitation events originate from each air mass) in groundwater resources recharge using Simmr package in R language. Overall, groundwater resources in Zagros is recharged by precipitation events originate from various air masses and they have various recharge rates and recharge elevations.

Measurement report: New particle formation characteristics at an urban and a mountain station in northern China

Atmospheric new particle formation (NPF) events have attracted increasing attention for their contribution to the global aerosol number budget and therefore their effects on climate, air quality and human health. NPF events are regarded as a regional phenomenon, occurring over a large area. Most observations of NPF events in Beijing and its vicinity were conducted in populated areas, whereas observations of NPF events on mountaintops with low anthropogenic emissions are still rare in China. The spatial variation of NPF event intensity has not been investigated in detail by incorporating both urban areas and mountain measurements in Beijing. Here, we provide NPF event characteristics in summer 2018 and 2019 at urban Beijing and a comparison of NPF event characteristics – NPF event frequency, formation rate and growth rate – by comparing an urban Beijing site and a background mountain site separated by ∼80 km from 14 June to 14 July 2019, as well as giving insights into the connection between both locations. During parallel measurements at urban Beijing and mountain background areas, although the median condensation sink during the first 2 h of the common NPF events was around 0.01 s−1 at both sites, there were notable differences in formation rates between the two locations (median of 5.42 cm−3 s−1 at the urban site and 1.13 cm−3 s−1 at the mountain site during the first 2 h of common NPF events). In addition, the growth rates in the 7–15 nm range for common NPF events at the urban site (median of 7.6 nm h−1) were slightly higher than those at the mountain site (median of 6.5 nm h−1). To understand whether the observed events were connected, we compared air mass trajectories as well as meteorological conditions at both stations. Favorable conditions for the occurrence of regional NPF events were largely affected by air mass transport. Overall, our results demonstrate a clear inhomogeneity of regional NPF within a distance of ∼100 km, possibly due to the discretely distributed emission sources.

Exploring the inorganic composition of the Asian Tropopause Aerosol Layer using medium-duration balloon flights

Satellite observations have revealed an enhanced aerosol layer near the tropopause over Asia during the summer monsoon, called the Asian Tropopause Aerosol Layer (ATAL). In this work, aerosol particles in the ATAL were collected with a balloon-borne impactor near the tropopause region over India, using extended duration balloon flights, in summer 2017 and winter 2018. Their chemical composition was further investigated by quantitative analysis using offline ion chromatography. Nitrate (NO3−) and nitrite (NO2−) were found to be the dominant ions in the collected aerosols with values ranging between 87–343 ng/m3 STP during the summer campaign. In contrast, sulfate (SO42−) levels were found above the detection limit (> 10 ng/m3 STP) only in winter. In addition, we determined the origin of the air masses sampled during the flights through analysis of back trajectories along with convective influence. The results obtained therein were put into a context of large-scale transport and aerosol distribution with GEOS-Chem chemical transport model simulations. The first flight of summer 2017 which sampled air mass within the Asian monsoon anticyclone (AMA), influenced by convection over Western China, was associated with particle size radius (0.05–2 μm). In contrast, the second flight sampled air mass at the edge of the AMA associated with larger particle size radius (> 2 μm) with higher nitrite concentration. The sampled air masses in winter 2018 were likely affected by smoke from the Pacific Northwest fire event in Canada, which occurred 7 months prior to our campaign, leading to concentration enhancements of SO42− and Ca2+. Overall, our results suggest that nitrogen-containing particles represent a large fraction of aerosols populating the ATAL, in agreement with the results from aircraft measurements during the StratoClim campaign. Furthermore, GEOS-Chem model simulations suggest that lightning NOx emissions had a significant impact on the production of nitrate aerosols sampled during the summer 2017.